Quantum dot light emitting diode, manufacturing method thereof and display panel with electron contribution layer for injecting free electrons to light emitting layer
The present disclosure provides a quantum dot light emitting diode, including: a first electrode, a second electrode, a quantum dot light emitting layer between the first electrode and the second electrode, at least one electron transport layer between the quantum dot light emitting layer and the first electrode, and an electron contribution layer between the electron transport layer of the at least one electron transport layer closest to the first electrode and the quantum dot light emitting layer; a material of the electron contribution layer includes a metal material. The embodiment of the present disclosure also provides a method for manufacturing the quantum dot light emitting diode and a display panel.
1. A quantum dot light emitting diode, comprising: a first electrode, a second electrode, a quantum dot light emitting layer between the first electrode and the second electrode, at least one electron transport layer between the quantum dot light emitting layer and the first electrode, and an electron contribution layer between an electron transport layer of the at least one electron transport layer closest to the first electrode and the quantum dot light emitting layer;
wherein a material of the electron contribution layer comprises a metal material, and the electron contribution layer is configured to inject free electrons on a surface of the electron contribution layer into the quantum dot light emitting layer under action of an electric field between the first electrode and the second electrode.
2. The quantum dot light emitting diode of claim 1 , wherein a work function of the metal material is less than 4 eV.
3. The quantum dot light emitting diode of claim 2 , wherein the metal material comprises: at least one of magnesium, lithium and cesium.
4. The quantum dot light emitting diode of claim 1 , wherein a thickness of the electron contribution layer is in a range of 1 nm to 100 nm.
5. The quantum dot light emitting diode of claim 1 , wherein the at least one electron transport layer comprises one electron transport layer, and
the electron contribution layer is between the electron transport layer and the quantum dot light emitting layer.
6. The quantum dot light emitting diode of claim 1 , wherein the at least one electron transport layer comprises a plurality of electron transport layers, and
the electron contribution layer is between any two adjacent electron transport layers in the plurality of electron transport layers.
7. The quantum dot light emitting diode of claim 1 , wherein a material of the quantum dot light emitting layer comprises: at least one of indium phosphide quantum dots or indium phosphide derived quantum dots having a core-shell structure, blue light cadmium-containing quantum dots, GaP/ZnSe, CsPbBr 3 /ZnS; and
a material of the electron transport layer comprises: at least one of zinc oxide, magnesium zinc oxide, aluminum zinc oxide and magnesium aluminum zinc oxide.
8. The quantum dot light emitting diode of claim 1 , further comprising a hole transport layer and a hole injection layer;
wherein the hole transport layer is between the second electrode and the quantum dot light emitting layer, and the hole injection layer is between the second electrode and the hole transport layer.
9. A display panel, comprising: the quantum dot light emitting diode of claim 1 .