High performance magnets
Permanent magnet materials are provided. The permanent magnet materials are cerium based materials including zirconium and iron in combination with cobalt. The permanent magnet materials may have the formula Ce 2 ZrFe 15−x Co x wherein 6≤x≤15. In some embodiments, the permanent magnet materials have the formula Ce 2+y Zr 1−y Fe (15−x)(2−z)/2) Co x Cu ((15−x)z/2) wherein 6≤x≤15, 0≤y≤0.4, and z=0 or 1. In other embodiments, the permanent magnet materials have the formula Ce 2 Zr x (Fe 1−y Co y ) 17−2x , where 0<x≤1 and 0.4≤y≤1. Permanent magnets including the permanent magnet materials are also provided.
1. A permanent magnet material comprising a compound having the formula Ce 2 ZrFe 15−x Co x wherein 6≤x≤14 in the formula, the permanent magnet material having a magnetic anisotropy greater than 2 MJ/m 3 .
2. The permanent magnet material of claim 1 , wherein x=9.
3. The permanent magnet material of claim 1 , wherein Ce is in a trivalent (Ce 3+ ) state.
4. The permanent magnet material of claim 1 , wherein the material has a total magnetization of greater than 21μ B per formula unit.
5. The permanent magnet material of claim 1 , wherein the material has an energy of formation (E for ) less than −80.0 meV/atom.
6. The permanent magnet material of claim 1 , wherein the material has a maximum energy product (BH max ) of greater than 30 MGOe.
7. A permanent magnet comprising the permanent magnet material of claim 1 .
8. The permanent magnet of claim 7 , wherein the permanent magnet further comprises one or more of Hf, Ti, Ni, and inadvertent impurities.
9. A permanent magnet material comprising:
a compound having the formula Ce 2 ZrFe 15−x Co x wherein 6≤x≤14 in the formula, the permanent magnet material having a magnetic anisotropy greater than 2 MJ/m 3 , and wherein one or more of Hf, Ti, and W is partially substituted for Zr.
10. A permanent magnet material comprising:
TiC in an amount in the range of between 0 and 4% by weight; and
the balance a compound having the formula Ce 2 ZrFe 15−x Co x wherein 6≤x≤14 in the formula;
wherein the permanent magnet material has a magnetic anisotropy greater than 2 MJ/m 3 .
11. A permanent magnet material comprising a compound having the formula Ce 2+y Zr 1−y Fe (15−x)(2−z)/2 Co x Cu ((15−x)z/2) wherein x=9, y=0.4, and z=1.
12. A permanent magnet comprising the permanent magnet material of claim 11 .
13. The permanent magnet of claim 12 , wherein the permanent magnet further comprises one or more of Hf, Ti, Ni, and inadvertent impurities.