Phase-transition solid electrolyte material and all solid secondary battery including the same
An all-solid secondary battery includes: a cathode layer including a cathode active material; an anode layer; and a solid electrolyte layer disposed between the cathode layer and the anode layer, wherein at least one of the cathode layer, the anode layer, or the solid electrolyte layer includes a phase-transition solid electrolyte material, wherein upon heating, the phase-transition solid electrolyte material undergoes a phase transition from a first phase to a second phase, and the second phase has an ionic conductivity less than the ionic conductivity of the first phase.
1. A phase-transition solid electrolyte material comprising: a sulfide material represented by Formula (4)
d ( e LiBr-(1- e )LiCl)-(1- d )Li 3 PS 4 (4)
wherein, in Formula (4)
0.1≤d≤0.7, and
0≤e≤1;
the phase-transition solid electrolyte material further comprising at least one sulfide material represented by Formula (1), wherein the at least one sulfide material represented by Formula (1) is distinct from the sulfide material represented by Formula (4):
b LiX-(1- b )( c Li 2 S-(1- c )P 2 S 5 ) (1)
wherein, in Formula (1),
0.1≤b≤0.7,
0.6≤c≤0.9,
and X is at least one of Cl, Br, or I.
2. The phase-transition solid electrolyte material of claim 1 , wherein,
in Formula (1),
0.2≤b≤0.67, and
0.7≤c≤0.8.