Flexible tube for endoscope, endoscopic medical device, and resin composition for covering flexible tube substrate for endoscope
A flexible tube for an endoscope has a flexible tube substrate that is flexible and tubular and a resin layer (A) covering the flexible tube substrate. The resin layer (A) includes a thermoplastic resin (a) including at least one of a polyamide resin, a polyurethane resin, a polyester resin, a polystyrene resin, or an acrylic resin and having a tensile strength at 10% elongation of 10 MPa or more and a hindered amine compound (b) having a molecular weight of 500 or more. Also provided are an endoscopic medical device including the flexible tube for an endoscope and a resin composition suitable for forming the resin layer of the flexible tube for an endoscope.
1. A flexible tube for an endoscope, comprising:
a flexible tube substrate that is flexible and tubular; and
a resin layer (A) covering the flexible tube substrate,
wherein the resin layer (A) includes a thermoplastic resin (a) including at least one of a polyamide resin, a polyurethane resin, a polyester resin, a polystyrene resin, or an acrylic resin and having a tensile strength at 10% elongation of 10 MPa or more and a hindered amine compound (b) having a molecular weight of 500 or more.
2. The flexible tube for an endoscope according to claim 1 , wherein the thermoplastic resin (a) has a tensile strength at 10% elongation of 10 MPa to 50 MPa.
3. The flexible tube for an endoscope according to claim 1 , wherein the polyamide resin includes at least one of polyamide 1010, polyamide 1012, polyamide 11, polyamide 12, a polyamide elastomer, or an amorphous polyamide.
4. The flexible tube for an endoscope according to claim 3 , wherein the polyamide resin includes at least one of polyamide 11, polyamide 12, or a polyamide elastomer.
5. The flexible tube for an endoscope according to claim 1 , wherein the polyurethane resin has an aliphatic diisocyanate-derived component.
6. The flexible tube for an endoscope according to claim 1 , wherein the polyurethane resin has a poly(alkyleneoxy) structure in which the alkylene has 6 or more carbon atoms.
7. The flexible tube for an endoscope according to claim 1 , wherein the polyester resin has a polybutylene naphthalate structure.
8. The flexible tube for an endoscope according to claim 1 , wherein the acrylic resin has two or more acrylic acid ester components, each acrylic acid ester component forming a block structure.
9. The flexible tube for an endoscope according to claim 1 , wherein the hindered amine compound (b) has a molecular weight of 1,000 or more.
10. The flexible tube for an endoscope according to claim 1 , wherein the hindered amine compound (b) includes at least one of an N—R type hindered amine compound or an N—OR type hindered amine compound.
11. The flexible tube for an endoscope according to claim 1 , wherein an amount of the hindered amine compound (b) is 0.2% to 8% by mass based on 100% by mass of all components forming the resin layer (A).
12. The flexible tube for an endoscope according to claim 1 , wherein the resin layer (A) includes an antioxidant (c).
13. The flexible tube for an endoscope according to claim 12 , wherein the antioxidant (c) includes at least one of a phosphite-based antioxidant or a thioether-based antioxidant.
14. The flexible tube for an endoscope according to claim 12 , wherein an amount of the antioxidant (c) in the resin layer (A) is 0.15% to 4% by mass.
15. An endoscopic medical device comprising the flexible tube for an endoscope according to claim 1 .