IP Library › Granted Patent US 12,005,726
Granted Patent B2
US 12,005,726 · App. 17/903,257 · Granted Jun 11, 2024

Ink jet recording method and ink jet recording apparatus

Inventors: Eiichi Nakata (Kanagawa, JP); Eriko Yoshino (Kanagawa, JP); Ryo Tsujii (Tokyo, JP); Yoshitaka Torisaka (Tokyo, JP); Masanori Yoshida (Chiba, JP)
Assignee: Canon Kabushiki Kaisha
B41M7/009C09D11/104C09D11/106C09D11/322B41J11/00216B41M5/0011B41M5/50B41M5/52C09D11/12
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Quick Facts
Patent No.
US 12,005,726
App. No.
17/903,257
Granted
Jun 11, 2024
Kind
B2
Abstract

The ink jet recording method includes ejecting an aqueous ink from a recording head to apply the aqueous ink to a recording medium, to thereby record an image. The ink jet recording method includes: ejecting the aqueous ink heated to a temperature T H (° C.) from the recording head to apply the aqueous ink to the recording medium; and heating the recording medium having the aqueous ink applied thereto to a temperature T F (° C.), the aqueous ink containing a pigment and a polyester resin particle, a glass transition temperature T G (° C.) of the polyester resin particle, the temperature T H (° C.) and the temperature T F (° C.) satisfying relationships of the following expressions (1) to (3). T G (° C.)> T H (° C.)  (1) T F (° C.)≥ T H (° C.)+10° C.  (2) T F (° C.)≥ T G (° C.)−10° C.  (3)

Claims (44)

1. An ink jet recording method including ejecting an aqueous ink from a recording head of an ink jet system through action of thermal energy to apply the aqueous ink to a recording medium, to thereby record an image,

the ink jet recording method comprising:

ejecting the aqueous ink heated to a temperature T H (° C.) from the recording head to apply the aqueous ink to the recording medium; and

heating the recording medium having the aqueous ink applied thereto to a temperature T F (° C.),

the aqueous ink containing a pigment and a polyester resin particle,

the polyester resin particle having a ratio of a weight average molecular weight to a number average molecular weight of 6.0 or less,

a glass transition temperature T G (° C.) of the polyester resin particle, the temperature T H (° C.) and the temperature T F (° C.) satisfying relationships of the following expressions (1) to (3),

a heat quantity ((W·h)/g) to be applied to the aqueous ink applied to the recording medium being 2 (W·h)/g or more,

the recording medium having a water absorption amount of 10 mL/m 2 or less in a Bristow method from start of contact to 30 msec 1/2 .

T G (° C.)> T H (° C.)  (1)

T F (° C.)≥ T H (° C.)+10° C.  (2)

T F (° C.)≥ T G (° C.)−10° C.  (3)

2. The ink jet recording method according to claim 1 ,

wherein the temperature T H (° C.) is 40° C. or more, and

wherein the temperature T F (° C.) is 90° C. or less.

3. The ink jet recording method according to claim 1 ,

wherein the aqueous ink further contains a first water-soluble organic solvent having a boiling point of from 120° C. or more to 220° C. or less, and

wherein the first water-soluble organic solvent has a largest content by mass) among all water-soluble organic solvents in the aqueous ink.

4. The ink jet recording method according to claim 3 ,

wherein a difference between an SP value of the first water-soluble organic solvent and an SP value of the polyester resin particle is 4.0 or less, and

wherein the content (% by mass) of the first water-soluble organic solvent in the aqueous ink is from 1.0 times or more to 4.0 times or less in terms of mass ratio with respect to a content (% by mass) of the polyester resin particle.

5. The ink jet recording method according to claim 1 ,

wherein the aqueous ink further contains a second water-soluble organic solvent having a boiling point of from more than 220° C. to 310° C. or less, and

wherein a difference between an SP value of the second water-soluble organic solvent and an SP value of the polyester resin particle is 4.0 or less.

6. The ink jet recording method according to claim 1 ,

wherein the pigment is dispersed in the aqueous ink through action of an anionic group, and

wherein an anionic group amount (μmol/g) of the pigment is 6.0 times or more in terms of ratio with respect to an anionic group amount (μmol/g) of the polyester resin particle.

7. The ink jet recording method according to claim 1 , wherein the weight average molecular weight of the polyester resin particle is from 30,000 or more to 70,000 or less.

8. The ink jet recording method according to claim 1 , wherein a content (% by mass) of the polyester resin particle in the aqueous ink is 1.5 times or more in terms of mass ratio with respect to a content (% by mass) of the pigment.

9. The ink jet recording method according to claim 1 ,

wherein the aqueous ink further contains a wax particle formed of at least one kind of wax selected from the group consisting of: a Fischer-Tropsch wax; a polyolefin wax; and an α-olefin/maleic anhydride copolymer, and

wherein a content (% by mass) of the polyester resin particle in the aqueous ink is from 2.0 times or more to 30.0 times or less in terms of mass ratio with respect to a content (% by mass) of the wax particle.

10. An ink jet recording apparatus to be used in an ink jet recording method including ejecting an aqueous ink from a recording head of an ink jet system through action of thermal energy to apply the aqueous ink to a recording medium, to thereby record an image,

the ink jet recording apparatus comprising:

a mechanism configured to heat the aqueous ink to be ejected from the recording head and applied to the recording medium to a temperature T H (° C.); and

a mechanism configured to heat the recording medium having the aqueous ink applied thereto to a temperature T F (° C.),

the aqueous ink containing a pigment and a polyester resin particle,

the polyester resin particle having a ratio of a weight average molecular weight to a number average molecular weight of 6.0 or less,

a glass transition temperature T G (° C.) of the polyester resin particle, the temperature T H (° C.) and the temperature T F (° C.) satisfying relationships of the following expressions (1) to (3),

a heat quantity (W·h)/g) to be applied to the aqueous ink applied to the recording medium being 2 (W·h)/g or more,

the recording medium having a water absorption amount of 10 mL/m 2 or less in a Bristow method from start of contact to 30 msec 1/2 .

T G (° C.)> T H (° C.)  (1)

T F (° C.)≥ T H (° C.)+10° C.  (2)

T F (° C.)≥ T G (° C.)−10° C.  (3)

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2022
From: NAKATA, EIICHI; YOSHINO, ERIKO; TSUJII, RYO; TORISAKA, YOSHITAKA; YOSHIDA, MASANORI
To: CANON KABUSHIKI KAISHA
Reel/Frame 061341/0973 →
Priority Claims (3)
JP 2021-147158 · Sep 9, 2021 · national
JP 2021-147159 · Sep 9, 2021 · national
JP 2022-127993 · Aug 10, 2022 · national
Continuity (1)
Related Publication 20230077739A1 · Mar 16, 2023
Cited By (2)
US 12,643,326 US 12,734,814