Dialkyl tin oxide composition and process for producing 2-dimethylaminoethyl (meth)acrylate
The invention relates to a new dialkyl tin oxide catalyst composition and its use for the synthesis of amino alkyl (meth)acrylates by transesterification from an alkyl (meth)acrylates and an amino alcohol, and especially 2-dimethylaminoethyl (meth)acrylate. The invention also relates to polymers made with quaternized amino alkyl (meth)acrylates and use of said polymers in water treatment, sludge dewatering, papermaking process, agriculture, cosmetic and detergency composition, textile process, oil and gas recovery process such as enhanced oil recovery, fracturing, mining operation such as tailings treatment.
1. A dialkyl tin oxide composition comprising:
about 85% by weight of dibutyl tin oxide, wherein the dibutyl tin oxide has a particle-average diameter of about 300 microns, as measured before being added to the dialkyl tin oxide composition; and
about 15% by weight of a mixture that is
about half by weight methyl acrylate; and
about half by weight dimethylaminoethanol;
the percentages by weight of dibutyl tin oxide and mixture being relative to the weight of the dialkyl tin oxide composition.
2. The dialkyl tin oxide composition according to claim 1 , wherein the composition is a suspension in which 70% to 95% by weight of dibutyl tin oxide is solubilized, and 5% to 30% by weight of dibutyl tin oxide is in the form of particles suspended in the composition, the percentages by weight being relative to the weight of dibutyl tin oxide in the dialkyl tin oxide composition.
3. A process for the production of aminoalkyl (meth)acrylate, said process comprising performing a transesterification reaction to form the aminoalkyl (meth)acrylate from an alkyl (meth)acrylates and an amino alcohol, said process comprising using a dialkyl tin oxide composition according to claim 1 as a catalyst of the transesterification reaction.
4. The process according to claim 3 , wherein the process comprises the following steps:
in a reactor, adding at least one amino alcohol, at least one alkyl(meth) acrylate and at least one solvent with a weight ratio of 2-15:2-40:1-5;
in the same reactor, adding a dialkyl tin oxide composition according to claim 1 , with a weight ratio amino alcohol to the dialkyl tin oxide composition ranging from 10:1 to 100:1 to obtain a suspension;
increasing the temperature of the resulting suspension from 40° C. to 70° ° C., for a period of time from 30 minutes to 500 minutes, for recovering aminoalkyl (meth)acrylate; and
obtaining aminoalkyl (meth)acrylate.
5. The process according to claim 4 , further comprising a step of purifying the aminoalkyl (meth)acrylate.