Recycled oil and rubber modified for asphalt and method of use
A asphalt binder modifier or a stand-alone asphalt binder and the method of making the asphalt binder or binder modifier are disclosed. The asphalt modifier or binder consisting of treated re-refined engine oil bottoms/VTB's treated by injecting air into re-refining engine oil bottoms/VTB's at temperatures between 150° F. and 550° F. The re-refined engine oil can be processed with ground tire rubber. The binder modifier was blended with various paving and roofing asphalts to form performance-enhanced modified asphalt binders used in paving, roofing, and industrial products.
1. A modifier for asphalt comprising re-refined engine oil, ground tire rubber and at least one plastomer and/or at least one elastomer, wherein the re-refined engine oil and ground tire rubber are oxidized by heating the re-refined engine oil and ground tire rubber to a temperature of about 150° F. to about 550° F. or to 50° F. below the flash point of the re-refined engine oil and injecting air into the re-refined engine oil and ground tire rubber while mixing, wherein after oxidation the modifier has a softening point of at least 150° F. and penetration values that vary by 75 decimillimeters or less when measured at about 39° F. and about 115° F.
2. The modifier of claim 1 , wherein the modifier is oxidized prior to the addition of the at least one plastomer and/or at least one elastomer.
3. The modifier of claim 1 , wherein the at least one plastomer and/or at least one elastomer is added prior to oxidation of the re-refined engine oil and ground tire rubber.
4. The modifier of claim 2 , wherein the at least one elastomer is selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-butadiene rubber, styrene-butadiene polymer, styrene-ethylene-butadiene-styrene, reactive polymers, ter-polymers, natural rubbers or combinations thereof.
5. The modifier of claim 3 , wherein the at least one elastomer is selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-butadiene rubber, styrene-butadiene polymer, styrene-ethylene-butadiene-styrene, reactive polymers, ter-polymers, natural rubbers or combinations thereof.
6. The asphalt modifier of claim 2 , wherein the at least one plastomer is selected from the group consisting of polyethylene, ethylene-vinyl-acetate, APO, amorphous polyolefin, or APP, or a combination thereof.
7. The asphalt modifier of claim 3 , wherein the at least one plastomer is selected from the group consisting of polyethylene, ethylene-vinyl-acetate, APO, amorphous polyolefin, or APP, or a combination thereof.
8. The asphalt modifier of claim 3 , wherein the at least one plastomer is polyethylene.
9. An asphalt modifier emulsion comprising re-refined engine oil, ground tire rubber, and water, wherein the re-refined engine oil and ground tire rubber are oxidized by heating the re-refined engine oil and ground tire rubber to a temperature of about 150° F. to about 550° F. or to 50° F. below the flash point of the re-refined engine oil and injecting air into the re-refined engine oil and ground tire rubber while mixing, wherein after oxidation the modifier has a softening point of at least 150° F. and penetration values that vary by 75 decimillimeters or less when measured at about 39° F. and about 115° F.
10. The asphalt modifier emulsion of claim 9 , further comprising at least one elastomer and/or at least one plastomer.
11. A The asphalt modifier emulsion of claim 10 , wherein the at least one elastomer is selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-butadiene rubber, styrene-butadiene polymer, styrene-ethylene-butadiene-styrene, reactive polymers, ter-polymers, natural rubbers or combinations thereof.
12. The asphalt modifier of claim 10 , wherein the at least one plastomer is selected from the group consisting of polyethylene, ethylene-vinyl-acetate, APO, amorphous polyolefin, or APP, or a combination thereof.
13. The asphalt modifier of claim 12 , wherein the at least one plastomer is polyethylene.
14. The asphalt modifier of claim 12 , wherein the re-refined engine oil and ground tire rubber are oxidized by heating the re-refined engine oil and ground tire rubber to a temperature of about 150° F. to about 550° F. or to 50° F. below the flash point of the re-refined engine oil and injecting air combined with inert gas into the re-refined engine oil and ground tire rubber while mixing.
15. The asphalt modifier of claim 14 , wherein the inert gas is nitrogen.
16. A modifier for asphalt comprising re-refined engine oil, ground tire rubber and at least one wax, wherein the re-refined engine oil and ground tire rubber are oxidized by heating the re-refined engine oil and ground tire rubber to a temperature of about 150° F. to about 550° F. or to 50° F. below the flash point of the re-refined engine oil and injecting air into the re-refined engine oil and ground tire rubber while mixing, wherein after oxidation the modifier has a softening point of at least 150° F. and penetration values that vary by 75 decimillimeters or less when measured at about 39° F. and about 115° F.
17. A modifier for asphalt comprising re-refined engine oil, ground tire rubber and at least one polymer, wherein the re-refined engine oil and ground tire rubber are oxidized by heating the re-refined engine oil and ground tire rubber to a temperature of about 150° F. to about 550° F. or to 50° F. below the flash point of the re-refined engine oil and injecting air into the re-refined engine oil and ground tire rubber while mixing, wherein after oxidation the modifier has a softening point of at least 150° F. and penetration values that vary by 75 decimillimeters or less when measured at about 39° F. and about 115° F.
18. The modifier of claim 17 , wherein the at least one polymer includes at least one recycled polymer.