Laminate including layer of ethylene-α-olefin-nonconjugated polyene copolymer composition, and application thereof
The present invention has an object of providing a laminate which is composed of a layer containing a melt shapable fluororesin and a layer of an ethylene-α-olefin-nonconjugated polyene copolymer composition, and is excellent in adhesiveness, and the present invention relates to a laminate including: a layer including an ethylene-α-olefin-nonconjugated polyene copolymer composition, and a layer comprising a melt shapable fluororesin; wherein the ethylene-α-olefin-nonconjugated polyene copolymer composition includes 100 parts by mass of an ethylene-α-olefin-nonconjugated polyene copolymer (A), 1.0 to 6.0 parts by mass of at least one compound (C) selected from the group consisting of 1,8-diazabicyclo(5.4.0)undecene-7 salts, 1,5-diazabicyclo(4.3.0)nonene-5 salts, 1,8-diazabicyclo(5.4.0)undecene-7 and 1,5-diazabicyclo(4.3.0)nonene-5, and 3 to 20 parts by mass of magnesium oxide.
1. A laminate comprising: a layer comprising an ethylene-α-olefin-nonconjugated polyene copolymer composition, and a layer comprising a melt shapable fluororesin; wherein the ethylene-α-olefin-nonconjugated polyene copolymer composition comprises
100 parts by mass of an ethylene-α-olefin-nonconjugated polyene copolymer (A),
1.0 to 6.0 parts by mass of at least one compound (C) selected from the group consisting of 1,8-diazabicyclo(5.4.0)undecene-7 salts, 1,5-diazabicyclo(4.3.0)nonene-5 salts, 1,8-diazabicyclo(5.4.0)undecene-7 and 1,5-diazabicyclo(4.3.0)nonene-5,
3 to 20 parts by mass of magnesium oxide, and
25 to 200 parts by mass of a mineral oil-based softener (B) selected from naphthenic process oils and aromatic process oil; and
wherein the ethylene-α-olefin-nonconjugated polyene copolymer composition further comprises a crosslinking agent, the crosslinking agent being a sulfur-based compound.
2. The laminate according to claim 1 , wherein the compound (C) is a 1,8-diazabicyclo(5.4.0)undecene-7 salt and/or a 1,5-diazabicyclo(4.3.0)nonene-5 salt and is contained in an amount of 1.5 to 6.0 parts by mass, and the laminate further comprises 0.1 to 10 parts by mass of a dialkylcarbamic acid metal salt, with respect to 100 parts by mass of the ethylene-α-olefin-nonconjugated polyene copolymer (A).
3. The laminate according to claim 2 , wherein the dialkylcarbamic acid metal salt is a copper salt of dimethyldithiocarbamic acid or a zinc salt of dibutyldithiocarbamic acid.
4. The laminate according to claim 1 , wherein the ethylene-α-olefin-nonconjugated polyene copolymer composition further comprises
up to 100 parts by mass of a basic silica,
with respect to 100 parts by mass of the ethylene-α-olefin-nonconjugated polyene copolymer (A).
5. The laminate according to claim 1 , wherein the melt shapable fluororesin is at least one selected from the group consisting of polychlorotrifluoroethylene, chlorotrifluoroethylene-based copolymers and tetrafluoroethylene/hexafluoropropylene/vinylidene fluoride copolymers.
6. The laminate according to claim 1 , wherein a layer comprising the ethylene-α-olefin-nonconjugated polyene copolymer composition is laminated on each of both sides of a layer comprising the melt shapable fluororesin.
7. The laminate according to claim 1 , wherein a layer comprising the melt shapable fluororesin is laminated on each of both sides of a layer comprising the ethylene-α-olefin-nonconjugated polyene copolymer composition.
8. A laminate, obtained by vulcanizing a laminate according to claim 1 , wherein both the layers are vulcanizedly adhered.
9. A fuel line tube or hose comprising a laminate according to claim 1 .
10. A product comprising a laminate according to claim 1 .
11. The laminate according to claim 1 , wherein the total amount of the ethylene-α-olefin-nonconjugated polyene copolymer composition is 216.7 parts by mass or more, with respect to 100 parts by mass of the ethylene-α-olefin-nonconjugated polyene copolymer (A).