IP Library Granted Patent US 12,037,557
Granted Patent B2
US 12,037,557 · App. 18/107,535 · Granted Jul 16, 2024

Solid thermochemical fuel apparatus

Inventors: James F. Klausner (Haslett, MI); Joerg Petrasch (East Lansing, MI); Kelvin Randhir (East Lansing, MI); Nima Rahmatian (East Lansing, MI)
Assignee: Board of Trustees of Michigan State University
C10L5/28C10L9/06C10L9/08C10L2200/0213C10L2200/0236C10L2200/0254C10L2290/06
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Quick Facts
Patent No.
US 12,037,557
App. No.
18/107,535
Granted
Jul 16, 2024
Kind
B2
Abstract

A method of charging and/or discharging energy in reusable fuel workpieces or particles includes a solar furnace with counter-flowing workpieces and gas, to exchange heat therebetween, with the exiting gas and workpieces being at about ambient temperature. A further aspect employs a production plant including a reduction reactor configured to use excess electrical energy generated by renewable power generators to charge and/or discharge solid-state thermochemical fuel. Another aspect includes a fuel flow control valve using air pulses. An oxygen-deprived and reusable fuel, such as magnesium manganese oxide, or magnesium iron oxide, is also provided. In another aspect, an apparatus for producing a solid-state fuel includes a reduction reactor including a reactor chamber configured to receive concentrated solar energy, and a reactor tube having a recuperation zone, a reduction zone, and a quenching zone, wherein the reduction zone passes through the reactor chamber. A discharged solid-state fuel is configured to be fed down the reactor tube and a low-oxygen gas is configured to flow up the reactor tube.

Claims (59)

1. A method of using energy, the method comprising:

(a) downwardly feeding particles from a hopper to an upper heat-exchange area of a reactor, the particles being at least one of: magnesium manganese oxide, magnesium iron oxide, or magnesioferrite;

(b) downwardly feeding the particles from the upper heat-exchange area to a furnace;

(c) downwardly feeding the particles from the furnace to a lower heat-exchange area;

(d) flowing gas into the lower heat-exchange area, the gas being oxygen-depleted when in the lower heat-exchange area;

(e) upwardly flowing the gas from the lower heat-exchange area to the furnace;

(f) upwardly flowing the gas from the furnace to the upper heat-exchange area;

(g) pre-heating the particles with the gas as the gas flows through the particles in the upper heat-exchange area;

(h) transferring oxygen from the particles to the gas as the gas flows through the particles in the furnace; and

(i) cooling the particles with the gas as the gas flows through the particles in the lower heat-exchanging area.

2. The method of claim 1 , further comprising converting the particles into oxygen-depleted fuel when the particles and gas are heated in the furnace which is a solar furnace, as they continuously move through at least one substantially vertically elongated and ceramic feeding tube located within the solar furnace, and the particles and the gas having counter-flowing directions.

3. The method of claim 2 , further comprising:

(a) moving the oxygen-depleted fuel from an entrance to a recuperation area;

(b) moving the oxygen-depleted fuel from the recuperation area to an oxidation area, whereat the oxygen-depleted fuel receives oxygen and is converted back to the particles including a pre-reduced amount of the oxygen;

(c) moving the particles from the oxidation area to a quenching area;

(d) moving the particles from the quenching area to an exit;

(e) flowing a second gas or steam into the quenching area;

(f) flowing the second gas or the steam from the quenching area to the oxidation area during the moving of the particles from the oxidation area to the quenching area;

(g) flowing the second gas or the steam from the oxidation area to the recuperation area during the moving of the oxygen-depleted fuel from the recuperation area to the oxidation area; and

(h) pre-heating the oxygen-depleted fuel with the second gas or the steam, when the oxygen-depleted fuel and the second gas or the steam are in the recuperation area.

4. The method of claim 3 , further comprising splitting the steam within at least one of the oxidation area and the recuperation area to produce substantially pure hydrogen.

5. The method of claim 1 , further comprising exhausting oxygen-enriched gas from the upper heat-exchange area at substantially room temperature.

6. The method of claim 5 , further comprising receiving the particles from the lower heat-exchange area at substantially room temperature.

7. The method of claim 1 , further comprising storing the particles, which are oxygen-depleted, at substantially room temperature for more than two months without a loss of its energy content, and reusing the particles multiple times after the energy is removed therefrom as the oxygen-depleted particles are moved through subsequent generators.

8. The method of claim 1 , further comprising:

(a) supplying a substantially constant flow of the gas to a constant gas inlet coupled to the lower heat-exchange area;

(b) supplying a pulsating flow of the gas to an entryway a bottom of the lower heat-exchange area and the constant gas inlet; and

(c) the pulsating flow of the gas acting as a non-mechanical valve to control the flow of the particles downwardly moving through at least one of the zones.

9. The method of claim 1 , wherein the energy is concentrated solar energy entering the furnace.

10. The method of claim 1 , further comprising sending electricity from a renewable power generator to a heating element inside the furnace.

11. A method of using energy, the method comprising:

(a) downwardly feeding particles from a hopper to an upper heat-exchange area of a reactor, the particles comprising at least one of: magnesium manganese oxide, magnesium iron oxide, or magnesioferrite;

(b) downwardly feeding the particles from the upper heat-exchange area to a solar furnace;

(c) downwardly feeding the particles from the solar furnace to a lower heat-exchange area;

(d) flowing gas into the lower heat-exchange area, the gas being oxygen-depleted when in the lower heat-exchange area;

(e) upwardly flowing the gas from the lower heat-exchange area to the solar furnace;

(f) upwardly flowing the gas from the solar furnace to the upper heat-exchange area;

(g) pre-heating the particles with the gas as the gas flows through the particles in the upper heat-exchange area;

(h) transferring oxygen from the particles to the gas as the gas flows through the particles in the solar furnace; and

(i) cooling the particles with the gas as the gas flows through the particles in the lower heat-exchanging area;

(j) exhausting oxygen-enriched gas from the upper heat-exchange area at substantially room temperature;

(k) receiving the particles from the lower heat-exchange area at substantially room temperature; and

(l) converting the particles into oxygen-depleted fuel when the particles and the gas are heated in the solar furnace.

12. The method of claim 11 , further comprising moving the particles and the gas in counter-flowing directions.

13. The method of claim 11 , further comprising:

moving the oxygen-depleted fuel from an entrance to a recuperation area;

moving the oxygen-depleted fuel from the recuperation area to an oxidation area, whereat the oxygen-depleted fuel receives oxygen and is converted back to the particles including a pre-reduced amount of the oxygen;

moving the particles from the oxidation area to a quenching area;

moving the particles from the quenching area to an exit;

flowing a second gas or steam into the quenching area;

flowing the second gas or the steam from the quenching area to the oxidation area during the moving of the particles from the oxidation area to the quenching area;

flowing the second gas or the steam from the oxidation area to the recuperation area during the moving of the oxygen-depleted fuel from the recuperation area to the oxidation area; and

pre-heating the oxygen-depleted fuel with the second gas or the steam, when the oxygen-depleted fuel and the second gas or the steam are in the recuperation area.

14. The method of claim 11 , further comprising splitting steam within at least one of an oxidation area and a recuperation area to produce substantially pure hydrogen.

15. The method of claim 11 , further comprising storing the oxygen-depleted fuel at substantially room temperature for more than two months without a loss of its energy content, and reusing the particles multiple times after the energy is removed therefrom as the oxygen-depleted fuel is moved through subsequent generators.

16. The method of claim 11 , further comprising:

supplying a pulsating flow of the gas to an entryway a bottom of the lower heat-exchange area and the constant gas inlet; and

the pulsating flow of the gas acting as a non-mechanical valve to control the flow of the particles downwardly moving through at least one of the zones.

17. The method of claim 11 , further comprising sending electricity from a renewable power generator to a heating element inside the solar furnace.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 22, 2023
From: KLAUSNER, JAMES F.; PETRASCH, JOERG; RANDHIR, KELVIN; RAHMATIAN, NIMA
To: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY
Reel/Frame 063711/0700 →
Continuity (4)
Continuation PCTUS2021044651 · Aug 5, 2021
Provisional Application 63144120 · Feb 1, 2021
Provisional Application 63064256 · Aug 11, 2020
Related Publication 20230183590A1 · Jun 15, 2023