Wires of superelastic nickel-titanium alloy and methods of forming the same
A nickel-titanium alloy with an average grain size of between 0.2 and 10 microns and a recoverable strain of greater than 9% is disclosed herein, in which the alloy is formed using a method which involves applying a shape set heat treatment to the nickel-titanium alloy. The heat treatment includes applying heat at a temperature between 225° C. and 350° C. for a period of time between 20 and 240 minutes.
1. A nickel-titanium alloy having an average grain size between 0.2 and 10 microns, a recoverable strain of greater than 9% in length, and an upper plateau stress (UPS) of less than 400 MPa, wherein the UPS is measured in response to applying the recoverable strain to the wire, and the nickel-titanium alloy undergoes a residual elongation of less than 0.5% in response to applying the recoverable strain.
2. The nickel-titanium alloy of claim 1 , wherein the nickel-titanium alloy has an upper plateau length of greater than 7%.
3. The nickel-titanium alloy of claim 1 , wherein the nickel-titanium alloy has a lower plateau stress (LPS) of less than 250 MPa, wherein the LPS is measured in response to applying the recoverable strain to the wire.
4. The nickel-titanium alloy of claim 1 , wherein the nickel-titanium alloy has an elongation at fracture of greater than 15% in length.
5. The nickel-titanium alloy of claim 1 , further formed into an implantable medical device.
6. A nickel-titanium alloy formed using a method comprising:
providing the nickel-titanium alloy with an average grain size between 0.2 and 10 microns; and
applying a shape set heat treatment to the nickel-titanium alloy to form the nickel-titanium alloy with a recoverable strain of greater than 9% in length and an upper plateau stress (UPS) of less than 400 MPa, wherein the UPS is measured in response to applying the recoverable strain to the wire, the heat treatment includes applying heat at a temperature between 225° C. and 350° C. for a period of time between 20 and 240 minutes, wherein the nickel-titanium alloy undergoes a residual elongation of less than 0.5% in response to applying the recoverable strain.
7. The nickel-titanium alloy of claim 6 , wherein the nickel-titanium alloy has an upper plateau length of greater than 6%.
8. The nickel-titanium alloy of claim 6 , wherein the nickel-titanium alloy has a lower plateau stress of less than 250 M Pa.
9. The nickel-titanium alloy of claim 6 , wherein the nickel-titanium alloy has an elongation at fracture of greater than 15% in length.
10. The nickel-titanium alloy of claim 6 , further formed into an implantable medical device.
11. A method of forming a nickel-titanium alloy, comprising:
providing the nickel-titanium alloy in a cold worked state of between 35% and 46%;
applying a partial annealing heat treatment of between 550° C. and 700° C. temperature for up to 60 minutes; and
applying a heat treatment to the nickel-titanium alloy to cause the nickel-titanium alloy to have a recoverable strain of greater than 9% in length and an upper plateau stress (UPS) of less than 400 M Pa, wherein the UPS is measured in response to applying the recoverable strain to the wire, the heat treatment includes applying heat of between 225° C. and 350° C. temperature for a period of time between 20 and 240 minutes.
12. The method of claim 11 , wherein the nickel-titanium alloy has an upper plateau length of greater than 6%.
13. The method of claim 11 , wherein the nickel-titanium alloy has a lower plateau stress of less than 250 M Pa.
14. The method of claim 11 , wherein the nickel-titanium alloy has an elongation at fracture of greater than 15% in length.
15. The method of claim 11 , further comprising forming the nickel-titanium alloy into an implantable medical device.