Microcapsule compositions prepared from polysaccharides
Disclosed are microcapsule compositions having microcapsules suspended in an aqueous phase. Each of the microcapsules has a single core-shell structure and contains a microcapsule core and a microcapsule wall encapsulating the microcapsule core. The microcapsule compositions include a pectin. Also disclosed are preparation methods and use of the microcapsule compositions in consumer products.
1. A microcapsule composition comprising microcapsules that contain a microcapsule core and a microcapsule wall encapsulating the microcapsule core, wherein
the microcapsule core contains an active material, and
the microcapsule wall is a covalently bonded polymeric network comprising
(i) a pectin;
(ii) a polyisocyanate; and
(iii) a tannic acid;
wherein the pectin and the polyisocyanate are covalently bonded, and the polyisocyanate and the tannic acid are also covalently bonded.
2. The microcapsule composition of claim 1 , wherein the tannic acid is present at a level of 0.1% to 5% by weight of the microcapsule composition.
3. A method of preparing the microcapsule composition of claim 1 , comprising the steps of:
(a) preparing an oil-in-water emulsion comprising the active material, the pectin, and the polyisocyanate;
(b) adding the tannic acid to the oil-in-water emulsion; and
(c) applying conditions sufficient to induce formation of a covalently bonded polymeric network comprising the pectin, polyisocyanate and tannic acid, thereby forming the microcapsule composition,
wherein the pectin and the polyisocyanate are covalently bonded, and the polyisocyanate and the tannic acid are also covalently bonded.
4. The microcapsule composition of claim 1 further comprising a capsule formation aid.
5. The microcapsule composition of claim 1 , wherein the active material contains a fragrance, flavor, cosmetic active, malodor counteractant, or a combination thereof.
6. The microcapsule composition of claim 1 , wherein the polyisocyanate is selected from the group consisting of a polyisocyanurate of toluene diisocyanate, a trimethylol propane-adduct of toluene diisocyanate, a trimethylol propane-adduct of xylylene diisocyanate, a biuret of hexamethylene diisocyanate, and combinations thereof.
7. The microcapsule composition of claim 1 , wherein the microcapsules are present at a level of 10% to 50% by weight of the mierocapsule composition.
8. The microcapsule composition of claim 1 , wherein the pectin has a molecular weight of 200 Da to 2,000,000 Da.
9. The microcapsule composition of claim 1 , wherein the pectin has a molecular weight of 10,000 Da to 500,000 Da.
10. The microcapsule composition of claim 1 , wherein the pectin has molecular weight of 30,000 Da to 200,000 Da.
11. A consumer product comprising the microcapsule composition of claim 1 .