Electro-optic element with additive
An electro-optic element having enhanced durability by the addition of an additive. The additive may enhance the durability of the electro-optic element by reducing or eliminating the effects of water on species with the electro-optic element, such as the electrolyte. Specifically, the additive may operate to reduce or eliminate the formation and/or accumulation of hydrogen fluoride within the electro-optic element by interaction of the electrolyte with water or alcohol molecules. In some embodiments, the additive may be an organosilicon species, such as (3-cyanopropyl) dimethylfluorosilane.
1. A device comprising:
a first substrate having a first surface and a second surface;
a second substrate having a third surface and a fourth surface, the second substrate disposed in a spaced apart relationship relative the first substrate;
a first electrode associated with the second surface;
a second electrode associated with the third surface;
an electrolyte species disposed between the first and second electrodes;
an additive formed of (3-cyanopropyl) dimethylfluorosilane disposed between the first and second electrodes, the additive inhibiting at least one of the production and the accumulation of hydrogen fluoride or fluoride ions by interaction of the electrolyte with water; and
an electro-optic medium disposed between the first and second electrodes, the electro-optic medium operable between substantially activated and substantially un-activated states corresponding to variable transmissivity based, at least in part, on exposure to an electrical potential.
2. The device according to claim 1 , wherein the electrolyte species comprises a hydrolyzed fluoride containing anion.
3. The device according to claim 2 , wherein the anion is tetrafluoroborate.
4. The device according to claim 2 , wherein the anion is hexafluorophosphate.
5. The device according to claim 1 , wherein the electro-optic medium is electrochromic.
6. The device according to claim 1 , wherein the electro-optic medium is disposed in one or more layers associated with the at least one of the first and second electrodes.
7. The device according to claim 1 , wherein the electro-optic medium is in solution.
8. The device according to claim 7 , wherein the additive is a solvent of the electro-optic medium.
9. The device according to claim 1 , wherein one or more component of the electro-optic medium is also a component of the electrolyte species.
10. The device according to claim 1 , wherein the additive is a solvent of the electrolyte species.
11. A sunroof comprising the device of claim 1 .
12. A rearview mirror assembly comprising the device of claim 1 .
13. A window comprising the device of claim 1 .
14. An electro-optic element comprising:
a first substrate being substantially transparent and having a first surface and a second surface;
a second substrate being substantially transparent and having a third surface and a fourth surface, the second substrate disposed in a spaced apart relationship relative the first substrate;
a first electrode associated with the second surface;
a second electrode associated with the third surface;
an electrolyte species disposed between the first and second electrodes;
an additive formed of (3-cyanopropyl) dimethylfluorosilane disposed between the first and second electrodes, the additive inhibiting at least one of the production and the accumulation of hydrogen fluoride or fluoride ions by interaction of the electrolyte with water; and
an electro-optic medium disposed between the first and second electrodes, the electro-optic medium having variable transmissivity based, at least in part, on exposure to an electrical potential.
15. A sunroof comprising the electro-optic element of claim 14 .
16. An electro-optic element comprising:
a first substrate being substantially transparent and having a first surface and a second surface;
a second substrate being substantially reflective and having a third surface and a fourth surface, the second substrate disposed in a spaced apart relationship relative the first substrate;
a first electrode associated with the second surface;
a second electrode associated with the third surface;
an electrolyte species disposed between the first and second electrodes;
an additive formed of (3-cyanopropyl) dimethylfluorosilane disposed between the first and second electrodes, the additive inhibiting at least one of the production and the accumulation of hydrogen fluoride or fluoride ions by interaction of the electrolyte with water; and
an electro-optic medium disposed between the first and second electrodes, the electro-optic medium having variable transmissivity based, at least in part, on exposure to an electrical potential.
17. A rearview mirror assembly comprising the electro-optic element of claim 16 .