IP Library Granted Patent US 12,054,796
Granted Patent B2
US 12,054,796 · App. 17/255,186 · Granted Aug 6, 2024

Method for producing steel

Inventors: Toshiaki Mizoguchi (Tokyo, JP); Jun Takekawa (Tokyo, JP); Shintaro Oga (Tokyo, JP); Hidenori Kurimoto (Tokyo, JP)
Assignee: NIPPON STEEL CORPORATION
C21C7/06C22C38/002C22C38/005C22C38/02C22C38/04C22C38/06C22C38/42C22C38/44C22C38/46C22C38/48C22C38/50C22C38/54
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Quick Facts
Patent No.
US 12,054,796
App. No.
17/255,186
Granted
Aug 6, 2024
Kind
B2
Abstract

A method for producing steel includes: (a) a step of adding the first group of alloys to molten steel having an amount of dissolved oxygen of 0.0050 mass % or more; (b) a step of, after the step of (a), adding deoxidizer to the molten steel for deoxidation; (c) a step of, after the step of (b), adding the second group of alloys to the deoxidized molten steel; and (d) a step of, after the step of (c), adding REM to the molten steel, wherein amounts of oxygen O b introduced from the first group of alloys (mass %) and amounts of oxygen O a introduced from the second group of alloys (mass %) satisfy [O a ≤0.00100], [O b +O a ≥0.00150], and [O b /O a ≥2.0], and satisfy a formula [0.05≤REM/T.O≤0.5] after the step of (d).

Claims (81)

1. A method for producing steel, comprising:

adding a first group of alloys to molten steel, wherein the molten steel has an amount of dissolved oxygen of 0.0050 mass % or more;

after the adding the first group of alloys, adding deoxidizer to the molten steel for deoxidation;

after the adding the deoxidizer, adding a second group of alloys, which includes certain amounts of oxygen, to the deoxidized molten steel; and

after the adding the second group of alloys, adding REM to the molten steel, wherein

amounts of oxygen introduced from the first group of alloys and amounts of oxygen introduced from the second group of alloys satisfy formulas (i) to (iii), and

after the adding REM, the ratio between REM and T.O satisfies formula (iv):

O a ≤0.00100  (i)

O b +O a ≥0.00150  (ii)

O b /O a ≥2.0  (iii)

0.05≤ REM/T.O≤ 0.5  (iv)

where symbols in the formulas are defined as follows:

O b : the amounts of oxygen introduced from the first group of alloys, in mass %;

O a : the amounts of oxygen introduced from the second group of alloys, in mass %;

REM: content of REM, in mass %;

T.O: total content of oxygen, in mass %.

2. The method for producing steel according to claim 1 , wherein the first group of alloys and the second group of alloys are selected from the group consisting of manganese metal, titanium metal, copper metal, nickel metal, FeMn, FeP, FeTi, FeS, FeSi, FeCr, FeMo, FeB, and FeNb.

3. The method for producing steel according to claim 1 , wherein a chemical composition of the steel consists of, in mass %:

C: 0.0005 to 1.5%;

Si: 0.005 to 1.2%;

Mn: 0.05 to 3.0%;

P: 0.001 to 0.2%;

S: 0.0001 to 0.05%;

T.Al: 0.005 to 1.5%;

Cu: 0 to 1.5%;

Ni: 0 to 10.0%;

Cr: 0 to 10.0%;

Mo: 0 to 1.5%;

Nb: 0 to 0.1%;

V: 0 to 0.3%;

Ti: 0 to 0.25%;

B: 0 to 0.005%;

REM: 0.00001 to 0.0020%; and

T.O: 0.0005 to 0.0050%,

with the balance being Fe and impurities

where T.Al in the defined as total content of Al.

4. The method for producing steel according to claim 3 , wherein the chemical composition of the steel contains one or more elements selected from, in mass %:

Cu: 0.1 to 1.5%;

Ni: 0.1 to 10.0%;

Cr: 0.1 to 10.0%;

Mo: 0.05 to 1.5%;

Nb: 0.005 to 0.1%;

V: 0.005 to 0.3%;

Ti: 0.001 to 0.25%; and

B: 0.0005 to 0.005%.

5. The method for producing steel according to claim 1 , wherein in the steel, a maximum diameter of alumina clusters is 100 μm or less.

6. The method for producing steel according to claim 5 , wherein in the steel, numbers of alumina clusters having diameters of 20 μm or more are 2.0 clusters/kg or less.

7. The method for producing steel according to claim 2 , wherein a chemical composition of the steel consists of, in mass %:

C: 0.0005 to 1.5%;

Si: 0.005 to 1.2%;

Mn: 0.05 to 3.0%;

P: 0.001 to 0.2%;

S: 0.0001 to 0.05%;

T.Al: 0.005 to 1.5%;

Cu: 0 to 1.5%;

Ni: 0 to 10.0%;

Cr: 0 to 10.0%;

Mo: 0 to 1.5%;

Nb: 0 to 0.1%;

V: 0 to 0.3%;

Ti: 0 to 0.25%;

B: 0 to 0.005%;

REM: 0.00001 to 0.0020%; and

T.O: 0.0005 to 0.0050%,

with the balance being Fe and impurities

where T.Al in the above is defined as total content of Al.

8. The method for producing steel according to claim 7 , wherein the chemical composition of the steel contains one or more elements selected from, in mass %:

Cu: 0.1 to 1.5%;

Ni: 0.1 to 10.0%;

Cr: 0.1 to 10.0%;

Mo: 0.05 to 1.5%;

Nb: 0.005 to 0.1%;

V: 0.005 to 0.3%;

Ti: 0.001 to 0.25%; and

B: 0.0005 to 0.005%.

9. The method for producing steel according to claim 2 , wherein in the steel, a maximum diameter of alumina clusters is 100 μm or less.

10. The method for producing steel according to claim 3 , wherein in the steel, a maximum diameter of alumina clusters is 100 μm or less.

11. The method for producing steel according to claim 4 , wherein in the steel, a maximum diameter of alumina clusters is 100 μm or less.

12. The method for producing steel according to claim 9 , wherein in the steel, numbers of alumina clusters having diameters of 20 μm or more are 2.0 clusters/kg or less.

13. The method for producing steel according to claim 10 , wherein in the steel, numbers of alumina clusters having diameters of 20 μm or more are 2.0 clusters/kg or less.

14. The method for producing steel according to claim 11 , wherein in the steel, numbers of alumina clusters having diameters of 20 μm or more are 2.0 clusters/kg or less.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2020
From: MIZOGUCHI, TOSHIAKI; TAKEKAWA, JUN; OGA, SHINTARO; KURIMOTO, HIDENORI
To: NIPPON STEEL CORPORATION
Reel/Frame 054729/0001 →
Priority Claims (1)
JP 2018-121385 · Jun 26, 2018 · national
Continuity (1)
Related Publication 20210262049A1 · Aug 26, 2021