Method for evaluating stability of separator
A method for evaluating the stability of a separator, including the steps of: preparing a separator; determining the elongation properties of the separator by using dynamic mechanical analysis (DMA); comparing the determined value with the stability standards of the elongation properties; and classifying a separator as a stability-passing separator when the determined values satisfy the stability standards, and classifying a separator as a stability-failing separator when the determined values do not satisfy the stability standards, after the comparison.
1. A method for evaluating a stability of a separator for a secondary battery, which can predict a safety of the separator against explosion before a nail penetration test of the secondary battery, the method providing results matched with results of the nail penetration test for the secondary battery including the separator, the method comprising the steps of:
preparing the separator;
determining elongation properties of the separator by using dynamic mechanical analysis (DMA), including determining a breaking load and elongation condition by subjecting the separator to a load of 0.002N at a rate of 0.001N/min at a temperature of 200° C.;
comparing the determined elongation properties of the separator with predetermined stability standards; and
classifying the separator as a stability-passing separator when the determined elongation properties satisfy the stability standards, and classifying the separator as a stability-failing separator when the determined elongation properties do not satisfy the stability standards, after the comparison,
wherein the separator includes a porous polymer substrate separator, an organic/inorganic composite separator which has a porous coating layer disposed on at least one surface of the porous polymer substrate, or a combination of the porous polymer substrate separator and the organic/inorganic composite separator,
wherein the elongation properties are a breaking temperature and a shrinkage of the separator, and the stability standards are a breaking temperature of 200° C. or higher and a shrinkage of 59% or less, and
wherein the elongation properties are the breaking load and elongation at a break of the separator, and the stability standards are a breaking load of 0.02N or more and an elongation at break of 1% or more.
2. The method for evaluating the stability of the separator according to claim 1 , the method further comprising:
when the nail penetration test is performed by fully charging the secondary battery at 25° C. under a voltage of 4.25V, penetrating a nail having a diameter of 3 mm through the center of the battery, and
evaluating the battery as failing the nail penetration test, when it causes ignition, and the battery as passing the nail penetration test when it causes no ignition.
3. The method for evaluating the stability of the separator according to claim 1 , wherein the separator has a width of 6.1 mm and a length of 10 mm.