Hair treatment compositions
Aspects of the disclosure relate to hair treatment compositions including about 0.1 to about 10 wt. % of a cationic surfactant; about 0.1 to about 10 wt. % of a fatty acid having a carbon chain of 12 or more carbons; about 0.1 to about 20 wt. % of a fatty alcohol; and about 50 wt. % or more of water, wherein all weight percentages are based on the total weight of the hair treatment composition. Additionally, the hair treatment compositions are formulated to have a molar ratio of the total amount of cationic surfactant to the total amount of fatty acid is about 1:0.8 to about 1:3 and a pH of about 2.5 to about 5.5. The disclosure also relates to methods for applying such hair treatment compositions.
1. A hair treatment composition comprising:
(a) about 0.5 to about 8 wt. % of one or more cationic surfactants;
(b) about 0.5 to about 5 wt. % of one or more fatty acids having a carbon chain length of 12 or more carbon atoms;
wherein molar amounts of (a) and (b) are in a ratio of about 1:0.8 to about 1:2.1 ((a):(b)); and
the one or more cationic surfactants of (a) have a carbon chain length within 10 carbon atoms of the carbon chain length of the one or more fatty acids of (b);
(c) about 1 to about 10 wt. % of one or more fatty alcohols having a carbon chain length of 12 or more carbon atoms;
(d) about 50 wt. % or more of water;
(e) optionally, about 0.1 to about 10 wt. % of one or more silicones;
(f) optionally, about 0.01 to about 5 wt. % of one or more polymers;
(g) optionally, about 0.01 to about 10 wt. % of one or more fatty compounds other than the one or more fatty alcohols of (c) and the one or more fatty acids of (b); and
(h) about 0.01 to about 5 wt. % of one or more polyols;
wherein the hair treatment composition comprises a lamellar gel network,
the hair treatment composition has a pH lower than the pKa of the one or more fatty acids of (b) and is in a range of about 2.5 to about 5.5,
increasing the pH of the hair treatment composition above the pKa of the one or more fatty acids of (b) destabilizes the lamellar gel network, and
all weight percentages are based on a total weight of the hair treatment composition.
2. A method for treating hair comprising:
(I) applying a hair treatment composition of claim 1 to the hair, and
(II) rinsing the hair treatment composition from the hair.
3. A hair treatment composition comprising:
(a) about 0.5 to about 8 wt. % of one or more cationic surfactants;
(b) about 0.5 to about 5 wt. % of one or more fatty acids having a carbon chain length of 12 to 22 carbon atoms;
wherein molar amounts of (a) and (b) are in a ratio of about 1:0.5 to about 1:3 ((a):(b)), and
the one or more cationic surfactants of (a) have a carbon chain length within 10 carbon atoms of the carbon chain length of the one or more fatty acids of (b);
(c) about 1 to about 10 wt. % of one or more fatty alcohols having a carbon chain length of 12 or more carbon atoms; and
(d) about 50 wt. % or more of water,
wherein the hair treatment composition has a pH lower than the pKa of the one or more fatty acids of (b) and is in a range of about 2.5 to about 5.5,
the hair treatment composition comprises a lamellar gel network,
increasing the pH of the hair treatment composition above the pKa of the one or more fatty acids destabilizes the lamellar gel network, and
all weight percentages are based on a total weight of the hair treatment composition.
4. A hair treatment composition comprising:
(a) about 0.5 to about 8 wt. % of one or more cationic surfactants;
(b) about 0.5 to about 5 wt. % of one or more fatty acids having a carbon chain length of 12 to 22 carbon atoms;
wherein molar amounts of (a) and (b) are in a ratio of about 1:0.5 to about 1:3 ((a):(b)), and
the one or more cationic surfactants of (a) have a carbon chain length within 10 carbon atoms of the carbon chain length of the one or more fatty acids of (b);
(c) about 1 to about 10 wt. % of one or more fatty alcohols having a carbon chain length of 12 or more carbon atoms; and
(d) about 50 wt. % or more of water;
(e) less than 0.1 wt. % of a fatty amidoamine compound; and
(f) less than 0.1 wt. % of a PEGylated compound,
wherein the hair treatment composition has a pH lower than the pKa of the one or more fatty acids of (b) and is in a range of about 2.5 to about 5.5,
the hair treatment composition comprises a lamellar gel network,
increasing the pH of the hair treatment composition above the pKa of the one or more fatty acids destabilizes the lamellar gel network, and
all weight percentages are based on a total weight of the hair treatment composition.