Foamed isocyanate-based polymer
There is described a foamed isocyanate-based polymer derived from a reaction mixture comprising: an isocyanate; a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol; a second prescribed amount of biomass-based carbonaceous particulate material; and a blowing agent. In one embodiment, the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by omitting the biomass-based carbonaceous particulate material from the reaction mixture and increasing the amount of polymer particles in the polymer polyol composition to equal the sum of the first prescribed amount and the second prescribed amount. In another embodiment, the foamed polymer has a cellular matrix comprising a plurality of interconnected struts, the biomass-based carbonaceous particulate material conferring to the cellular matrix a load efficiency of at least about 5 Newtons/weight % of biomass-based carbonaceous particulate material. A process to produce the foamed isocyanate-based polymer is also described. A polyol-based dispersion to produce the foamed isocyanate-based polymer is also described. It has been discovered that a relatively expensive petroleum-based copolymer polyol can be fully substituted by a relative inexpensive bio-based (amorphous carbon) dispersion with no significant compromise in important physical properties in the resulting polyurethane foam.
1. A foamed isocyanate-based polymer derived from a reaction mixture comprising:
an isocyanate;
a polymer polyol composition comprising an amount in parts by weight of styrene-acrylonitrile polymer particles dispersed in a base polyol;
an amount in parts by weight of a biomass-based carbonaceous particulate material; and
a blowing agent;
the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 13% as that of a reference foam which is prepared from an identical reaction mixture to said reaction mixture used to prepare said foamed isocyanate-based polymer, except that the reaction mixture used to prepare the reference foam is free of biomass-based carbonaceous particulate material and comprises an amount in parts by weight of polymer particles which is equal to the sum of the amount in parts by weight of polymer particles and the amount in parts by weight of biomass-based carbonaceous particulate in said foamed isocyanate-based polymer;
wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.2 μm to about 6 μm;
wherein the biomass-based carbonaceous particulate material has a percentage of modern carbon (pMC) greater than about 85% when measured pursuant to ASTM D6866; and
wherein the biomass-based carbonaceous particulate material comprises an organic carbon content in the range of from about 85% to about 98% when measured by dry combustion using ASTM D4373.
2. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material is dispersed in the base polyol composition prior to formation of the reaction mixture.
3. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.3 μm to about 6 μm.
4. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.4 μm to about 6 μm.
5. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.5 μm to about 6 μm.
6. The foamed isocyanate-based polymer defined in claim 1 , wherein the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 10% as that of the reference foam.
7. The foamed isocyanate-based polymer defined in claim 1 , wherein the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 5% as that of the reference foam.
8. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material comprises a hydrogen to carbon molar ratio in the range of from about 0.35 to about 0.85 when measured by dry combustion using ASTM D4373.
9. The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a surface area of from about 50 to about 3000 m 2 /g when measured by a BET method.
10. The foamed isocyanate-based polymer defined in claim 1 , wherein the reaction mixture is substantially completely free of carbonaceous particulate material derived from petroleum sources.
11. A polyurethane foam derived from a reaction mixture comprising:
an isocyanate;
a polymer polyol composition comprising an amount in parts by weight of styrene-acrylonitrile polymer particles dispersed in a base polyol;
an amount in parts by weight of a biomass-based carbonaceous particulate material; and
a blowing agent;
the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 11% as that of a reference foam which is prepared from an identical reaction mixture to said reaction mixture used to prepare said foamed isocyanate-based polymer, except that the reaction mixture used to prepare the reference foam is free of biomass-based carbonaceous particulate material and comprises an amount in parts by weight of polymer particles which is equal to the sum of the amount in parts by weight of polymer particles and the amount in parts by weight of biomass-based carbonaceous particulate in said foamed isocyanate-based polymer;
wherein the biomass-based carbonaceous particulate material has: (i) a D50 particle size in the range of from about 0.2 μm to about 6 μm, (ii) a percentage modern carbon (pMC) of greater than 85% when determined according to ASTM D6866, and (iii) an organic carbon content in the range of from about 85% to about 98% when measured by dry combustion using ASTM D4373.
12. The polyurethane foam defined in claim 11 , wherein the biomass-based carbonaceous particulate material has a percentage modern carbon (pMC) of greater than 95% when determined according to ASTM D6866.
13. The polyurethane foam defined in claim 11 , wherein the biomass-based carbonaceous particulate material is dispersed in the base polyol composition prior to formation of the reaction mixture.
14. The polyurethane foam defined in claim 11 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.5 μm to about 6 μm.
15. The polyurethane foam defined in claim 11 , wherein the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 8% as that of the reference foam.
16. The polyurethane foam defined in claim 11 , wherein the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 5% as that of the reference foam.
17. The polyurethane foam defined in claim 11 , wherein the biomass-based carbonaceous particulate material comprises a hydrogen to carbon molar ratio in the range of from about 0.35 to about 0.85 when measured by dry combustion using ASTM D4373.
18. The polyurethane foam defined in claim 11 , wherein the biomass-based carbonaceous particulate material has a surface area of from about 50 to about 3000 m 2 /g when measured by a BET method.
19. The foamed isocyanate-based polymer foam defined in claim 1 , wherein the foam is an isocyanate-based high resilience (HR) foam.
20. The polyurethane foam defined in claim 11 , wherein the foam is a polyurethane high resilience (HR) foam.