Bismuth oxyhalide-based quantum dots and method of synthesis thereof
A method of producing bismuth oxyhalide quantum dots without heat. The method is a one-pot method that includes synthesizing bismuth oxyhalide quantum dots at room temperature. The method results in quantum dots preferably having bismuth and halide in a molar ratio of 1:1. Further, the bismuth oxyhalide quantum dots produced demonstrate excellent photocatalytic activity in the visible light spectrum and possess improved surface characteristics.
1. A method of producing bismuth oxyhalide quantum dots without added heat, comprising:
forming a first solution by dissolving a bismuth salt in an organic solvent;
forming a second solution by dissolving an alkali metal salt in water;
combining the first solution and the second solution to obtain a dual mixture;
combining the dual mixture with an aqueous surfactant solution comprising a surfactant to obtain a final mixture comprising the bismuth oxyhalide quantum dots; and
filtering the final solution to obtain the bismuth oxyhalide quantum dots,
wherein the alkali metal salt is selected from the group consisting of LiI, NaI, KI, RbI, CsI, LiBr, NaBr, KBr, RbBr, CsBr, LiCl, NaCl, KCl, RbCl, and CsCl.
2. The method of claim 1 , wherein the bismuth salt is Bi(NO 3 ) 3 , and wherein the first solution, the second solution, the dual mixture and the final mixture are maintained at a temperature of ±5° C. during the forming and the combining.
3. The method of claim 1 , wherein the dual mixture is added to the surfactant solution such that the ratio of dual mixture to surfactant solution is 1:4 wt %.
4. The method of claim 1 , wherein the organic solvent is selected from the group consisting of polyethylene glycol, methylene glycol, tri-ethylene glycol, and ethylene glycol.
5. The method of claim 1 , wherein the surfactant is selected from the group consisting of an octyl phenol ethoxylate, a polyoxyethylene sorbitan monolaurate, and a polyoxyethylene sorbitan monooleate.
6. The method of claim 1 , wherein the dual mixture is stirred for 5 to 10 minutes at a temperature of 15 to 25° C.
7. The method of claim 1 , wherein the final mixture is stirred for 10 to 15 minutes at a temperature of 15 to 25° C.
8. The method of claim 1 , wherein the final solution is filtered by a vacuum.
9. The method of claim 1 , wherein the bismuth quantum dots are dried for 2 to 4 hours at a temperature of 100 to 115° C.
10. The method of claim 1 , wherein the surfactant in the final mixture is present in an amount between 0.5 to 2.2 wt %.
11. The method of claim 1 , wherein the alkali metal salt is KI.
12. The method of claim 1 , wherein the bismuth oxyhalide quantum dots have a surface area of 59 to 82 m 2 /g.
13. The method of claim 1 , wherein the bismuth oxyhalide quantum dots have a band gap energy (E g ) of 1.80 to 2 eV.
14. The method of claim 1 , wherein the bismuth oxyhalide quantum dots have an average crystal size of 10 nm or less.
15. The method of claim 1 , wherein the organic solvent is ethylene glycol.
16. The method of claim 1 , wherein the surfactant is an octyl phenol ethoxylate.
17. The method of claim 1 , wherein the bismuth oxyhalide quantum dots have a Bi:I ratio of 1:1.
18. The method of claim 1 , wherein the bismuth oxyhalide quantum dots are in the form of nanosheets having a thickness of 22 to 51 nm.