Reinforced glass and method for producing reinforced glass
A tempered glass has a surface and a thickness, wherein a stress profile of the tempered glass includes a first peak at the surface, at which the compressive stress becomes a maximum, a first bottom at which the stress, which gradually reduces from the first peak in the depth direction, becomes a local minimum, a second peak at which the compressive stress, which gradually increases from the first bottom in the depth direction, becomes a local minimum, and a second bottom at which the tensile stress, which gradually reduces from the second peak in the depth direction, becomes a minimum. The compressive stress at the first peak is 500 MPa or more, the compressive stress at the second peak P 2 is from 15 MPa to 250 MPa, and the depth of layer of the second peak is from 4% to 20% of the thickness.
1. A tempered glass having a surface and a thickness T,
wherein a stress profile of the tempered glass, which is obtained by measuring a stress in a depth direction from the surface with a compressive stress being represented by a positive number and a tensile stress being represented by a negative number, comprises:
a first peak at the surface, at which the compressive stress takes a maximum value;
a first bottom at which the stress, which reduces from the first peak in the depth direction, takes a local minimum value;
a second peak at which the compressive stress, which increases from the first bottom in the depth direction, takes a local maximum value; and
a second bottom at which the tensile stress, which reduces from the second peak in the depth direction, takes a minimum value,
wherein the compressive stress at the first peak is 500 MPa or more,
wherein the compressive stress at the second peak is from 15 MPa to 250 MPa,
wherein the second peak is present at a depth of from 4% to 20% of the thickness T, and
wherein the stress at the first bottom is from 0 MPa or more and +65 MPa or less.
2. The tempered glass according to claim 1 ,
wherein the stress profile has a zero stress point at which the stress becomes zero between the second peak and the second bottom, and
wherein the zero stress point is present at a depth of from 10% to 35% of the thickness T from the surface.
3. The tempered glass according to claim 1 , wherein the first bottom is present at a depth of from 0.5% to 12% of the thickness T from the surface.
4. The tempered glass according to claim 1 , wherein a distance from the first bottom to the second peak in the depth direction is 3% or more of the thickness T.
5. The tempered glass according to claim 1 ,
wherein the compressive stress at the first peak is 700 MPa or more, and
wherein the second peak is present at a depth of 7.3% or more of the thickness T from the surface.
6. The tempered glass according to claim 1 ,
wherein the thickness T is from 0.3 mm to 0.9 mm, and
wherein the tempered glass has the stress profile in each of main surfaces and end surfaces thereof.
7. The tempered glass according to claim 1 ,
wherein the thickness T falls within a range of 0.45 mm or more and 0.85 mm or less,
wherein the compressive stress at the first peak falls within a range of 700 MPa or more and 850 MPa or less,
wherein the compressive stress at the second peak falls within a range of 20 MPa or more and 80 MPa or less,
wherein the second peak is present within a depth range of 7.3% or more and 20% or less of the thickness T from the surface,
wherein the stress profile has a zero stress point at which the stress becomes zero between the second peak and the second bottom,
wherein the zero stress point is present within a depth range of 17% or more and 25% or less of the thickness T from the surface, and
wherein a maximum absolute value of the tensile stress falls within a range of 40 MPa or more and 60 MPa or less.
8. The tempered glass according to claim 1 , wherein the tempered glass comprises as a glass composition, in terms of mass %, 40% to 70% of SiO 2 , 10% to 30% of Al 2 O 3 , 0% to 10% of B 2 O 3 , 2% to 11% of Li 2 O, 5% to 25% of Na 2 O, 0% to 10% of K 2 O, 0% to 6% of MgO, 0% to 10% of ZnO, and 0% to 20% of P 2 O 5 .