IP Library › Granted Patent US 12,127,479
Granted Patent B2
US 12,127,479 · App. 18/381,846 · Granted Oct 22, 2024

Light-emitting element, light-emitting device, electronic device, lighting device, and organic compound

Inventors: Satoshi Seo (Kanagawa, JP); Takao Hamada (Kanagawa, JP); Tatsuyoshi Takahashi (Kanagawa, JP); Yasushi Kitano (Kanagawa, JP); Hiroki Suzuki (Kanagawa, JP); Hideko Inoue (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H10K85/6572C07D403/14H10K85/342H10K85/633H10K85/636Y02P20/582
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Quick Facts
Patent No.
US 12,127,479
App. No.
18/381,846
Granted
Oct 22, 2024
Kind
B2
Abstract

To provide a light-emitting element with an improved reliability, a light-emitting element with a high current efficiency (or a high quantum efficiency), and a novel dibenzo[f,h]quinoxaline derivative that is favorably used in a light-emitting element which is one embodiment of the present invention. A light-emitting element includes an EL layer between an anode and a cathode. The EL layer includes a light-emitting layer; the light-emitting layer contains a first organic compound having an electron-transport property and a hole-transport property, a second organic compound having a hole-transport property, and a light-emitting substance; the combination of the first organic compound and the second organic compound forms an exciplex; the HOMO level of the first organic compound is lower than the HOMO level of the second organic compound; and a difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.4 eV.

Claims (44)

1. A light-emitting element comprising:

a light-emitting layer between an anode and a cathode,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a phosphorescent compound,

wherein an emission spectrum of a mixed film of the first organic compound and the second organic compound is located on a longer wavelength side than a fluorescence spectrum of a film of the first organic compound and a fluorescence spectrum of a film of the second organic compound,

wherein the first organic compound comprises a 6-membered nitrogen-containing heteroaromatic ring and a carbazole skeleton and does not comprise a triarylamine skeleton,

wherein the 6-membered nitrogen-containing heteroaromatic ring is pyrazine, pyridazine, triazine, or tetrazine,

wherein a HOMO level of the first organic compound is lower than a HOMO level of the second organic compound, and

wherein a difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.4 eV.

2. A light-emitting element comprising:

a light-emitting layer between an anode and a cathode,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a phosphorescent compound,

wherein the first organic compound and the second organic compound form an exciplex,

wherein the first organic compound comprises a 6-membered nitrogen-containing heteroaromatic ring and a carbazole skeleton and does not comprise a triarylamine skeleton,

wherein the 6-membered nitrogen-containing heteroaromatic ring is pyrazine, pyridazine, triazine, or tetrazine,

wherein a HOMO level of the first organic compound is lower than a HOMO level of the second organic compound, and

wherein a difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.4 eV.

3. A light-emitting element comprising:

a light-emitting layer between an anode and a cathode,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a phosphorescent compound,

wherein an emission spectrum of a mixed film of the first organic compound and the second organic compound is located on a longer wavelength side than a fluorescence spectrum of a film of the first organic compound and a fluorescence spectrum of a film of the second organic compound,

wherein the first organic compound comprises a 6-membered nitrogen-containing heteroaromatic ring and a carbazole skeleton and does not comprise a triarylamine skeleton,

wherein a HOMO level of the first organic compound is lower than a HOMO level of the second organic compound,

wherein a difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.4 eV, and wherein the 6-membered nitrogen-containing heteroaromatic ring is condensed with a benzene ring.

4. The light-emitting element according to claim 1 , wherein the phosphorescent compound comprises iridium.

5. The light-emitting element according to claim 1 , wherein the difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.3 eV.

6. The light-emitting element according to claim 2 , wherein the phosphorescent compound comprises iridium.

7. The light-emitting element according to claim 2 , wherein the difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.3 eV.

8. The light-emitting element according to claim 3 , wherein the phosphorescent compound comprises iridium.

9. The light-emitting element according to claim 3 , wherein the difference between the HOMO level of the first organic compound and the HOMO level of the second organic compound is less than or equal to 0.3 eV.

10. The light-emitting element according to claim 3 , wherein the first organic compound and the second organic compound form an exciplex.

11. The light-emitting element according to claim 3 , wherein the 6-membered nitrogen-containing heteroaromatic ring is pyridine, pyrazine, pyrimidine, pyridazine, triazine, or tetrazine.

12. The light-emitting element according to claim 3 , wherein the 6-membered nitrogen-containing heteroaromatic ring condensed with the benzene ring is quinoline, isoquinoline, dibenzo[f,h]quinoline, naphthyridine, dibenzo[f,h]quinoxaline, oρ dibenzo[f,h]quinazoline.

13. A light-emitting device comprising the light-emitting element according to claim 1 .

14. An electronic device comprising:

the light-emitting device according to claim 13 ; and

at least one of a connection terminal and an operation key.

15. A light-emitting device comprising the light-emitting element according to claim 2 .

16. An electronic device comprising:

the light-emitting device according to claim 15 ; and

at least one of a connection terminal and an operation key.

17. A light-emitting device comprising the light-emitting element according to claim 3 .

18. An electronic device comprising:

the light-emitting device according to claim 17 ; and

at least one of a connection terminal and an operation key.

Priority Claims (1)
JP 2014-151493 · Jul 25, 2014 · national
Continuity (5)
Continuation 18094154 · Jan 6, 2023
Continuation 16570062 · Sep 13, 2019
Continuation 15988152 · May 24, 2018
Continuation 14807426 · Jul 23, 2015
Related Publication 20240147852A1 · May 2, 2024
Cited By (1)
US 12,302,685