Method for producing octahedron transition metal dichalcogenides using plasma
The present disclosure relates to a method of producing octahedral transition metal dichalcogenides, including forming a transition metal layer on a substrate and injecting a chalcogenide-containing gas onto the substrate, on which the transition metal layer has been formed, together with a plasma treatment.
1. A method of producing an octahedral transition metal dichalcogenide, comprising:
forming a transition metal layer on a substrate; and
injecting a chalcogenide-containing gas onto the substrate together with a plasma treatment,
wherein the transition metal layer comprises a member selected from the group consisting of W, Cu, Ni, Sc, Ti, V, Cr, Mn, Fe, Co, Zn, Y, Zr, Nb, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, Re, Os, Ir, Pt, Au, Hg, Rf, Db, Sg, Bh, Hs, Mt, Ds, Rg, Cn, and combinations thereof;
the chalcogenide-containing gas is supplied at 10 sccm to 30 sccm; and
the injecting of the chalcogenide-containing gas is performed at a temperature in a range of 100° C. to 200° C., and
wherein the chalcogenide-containing gas forms argon ions (Ar + ) and hydrogen sulfide ions (H 2 S + ) during the plasma treatment.
2. The method of claim 1 , wherein the forming of the transition metal layer is performed by a member selected from the group consisting of electron-beam evaporation, RF/DC sputtering, ion beam sputtering, chemical vapor deposition (CVD), low pressure chemical vapor deposition (LPCVD), plasma enhanced chemical vapor deposition (PECVD), ion plating, and combinations thereof.
3. The method of claim 1 , wherein the plasma treatment is a plasma enhanced chemical vapor deposition (PECVD) method.
4. The method of claim 1 ,
wherein the chalcogenide-containing gas is injected together with a carrier gas.
5. The method of claim 1 ,
wherein the octahedral transition metal dichalcogenide comprises nanocrystals with a diameter of 5 nm to 10 nm.
6. The method of claim 5 ,
wherein the nanocrystals include crystals with sizes regulated to nano-size by the plasma treatment.
7. The method of claim 1 ,
wherein the substrate includes a member selected from the group consisting of Si, SiO 2 , Ge, GaN, AlN, GaP, InP, GaAs, SiC, Al 2 O 3 , LiAlO 3 , MgO, glass, quartz, sapphire, graphite, graphene, metal foil, PEN (poly ethylene naphthalate), PET (poly ethylene terephthalate), and combinations thereof.
8. The method of claim 1 , wherein the forming of the transition metal layer comprises depositing a tungsten (W) metal layer on the substrate, and
the injecting of the chalcogenide-containing gas comprises introducing hydrogen sulfide (H 2 S) in argon (Ar) plasma at 10 sccm to 30 sccm.
9. The method of claim 1 , wherein the obtained octahedral transition metal dichalcogenide has a stabilized crystalline structure such that the Raman Spectroscopy remains substantially unchanged after exposure to 1,000 cycles.
10. The method of claim 1 , wherein the plasma treatment ionizes the chalcogenide-containing gas and accelerates the ionized chalcogenide-containing gas toward the substrate.
11. The method of claim 1 , wherein the plasma treatment is plasma enhanced chemical vapor deposition that applies a plasma power and a plasma duration sufficient to convert the chalcogenide-containing gas into plasma.
12. A method of producing an octahedral transition metal dichalcogenide, comprising:
depositing a tungsten (W) metal layer on a substrate; and
injecting a chalcogenide-containing gas onto the substrate with a plasma treatment to form an octahedral transition metal dichalcogenide layer on the tungsten (W) metal layer,
wherein the chalcogenide-containing gas forms argon ions (Ar + ) and hydrogen sulfide ions (H 2 S + ) during the plasma treatment; and
the injecting of the chalcogenide-containing gas is performed at a temperature in a range of 100° C. to 200° C.
13. The method of claim 12 , wherein the depositing of the tungsten (W) metal layer is performed by electron-beam evaporation.
14. The method of claim 12 , wherein the transition metal dichalcogenide layer is formed by a plasma enhanced chemical vapor deposition method while the chalcogenide-containing gas is injected at the temperature in the range of 100° C. to 200° C.
15. The method of claim 12 , wherein the injecting of the chalcogenide-containing gas comprises introducing hydrogen sulfide (H 2 S) in argon (Ar) plasma such that the hydrogen sulfide ions (H 2 S + ) bond to tungsten (W) atoms of the tungsten (W) metal layer, generating hydrogen gas as a by-product.