IP Library Granted Patent US 12,130,587
Granted Patent B2
US 12,130,587 · App. 17/205,716 · Granted Oct 29, 2024

Toner

Inventors: Naoya Isono (Shizuoka, JP); Kenichi Nakayama (Shizuoka, JP); Hirofumi Kyuushima (Shizuoka, JP); Mai Kato (Tokyo, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/09371C08F212/08C08G63/183G03G9/09321
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Quick Facts
Patent No.
US 12,130,587
App. No.
17/205,716
Granted
Oct 29, 2024
Kind
B2
Abstract

The toner includes a toner particle that comprising a core particle containing a resin component and a shell on a surface of the core particle, wherein the resin component comprises more than 50.0 mass % of a polyester resin comprising a monomer unit that contains a heterocyclic group, and the shell comprises at least one resin selected from the group consisting of prescribed (meth)acrylic resins and melamine resins.

Claims (16)

1. A toner comprising a toner particle, the toner particle comprising:

a core particle containing a resin component, the resin component comprising a styrene-acrylic resin and more than 50.0 mass % of a polyester resin comprising an isosorbide monomer unit; and

a shell on a surface of the core particle, the shell comprising at least one resin selected from the group consisting of (i) melamine resins and (ii) (meth)acrylic resins comprising at least one monomer unit selected from the group consisting of a monomer unit represented by formula (2) and a 2-hydroxyethyl methacrylate monomer unit

 where R 2 represents a hydrogen atom or a methyl group, wherein

the shell content is 0.7 to 2.5 mass parts per 100.0 mass parts of the resin component in the core particle, and

the toner particle is a particle obtained by forming the shell on the surface of the core particle in an aqueous medium in which the core particle is dispersed.

2. The toner according to claim 1 , wherein a content of the isosorbide monomer unit in the polyester resin is 5.0 to 35.0 mass %.

3. The toner according to claim 1 , wherein the polyester resin comprises at least one member selected from the group consisting of a structure in which an aliphatic diol is condensation-polymerized with a carboxylic acid component and a structure in which an alicyclic diol is condensation-polymerized with a carboxylic acid component.

4. The toner according to claim 1 , wherein the shell comprises the (meth)acrylic resin.

5. The toner according to claim 4 , wherein a total content of the monomer unit selected from the group consisting of monomer unit represented by formula (2) and the 2-hydroxyethyl methacrylate monomer unit in the (meth)acrylic resin is 5.0 to 35.0 mass %.

6. A method for producing a toner comprising a toner particle, comprising a step of:

forming a shell on a surface of a core particle in an aqueous medium in which the core particle is dispersed, wherein

the core particle contains a resin component, the resin component comprising a styrene-acrylic resin and more than 50.0 mass % of a polyester resin comprising an isosorbide monomer unit,

the shell comprises at least one resin selected from the group consisting of (i) melamine resins and (ii) (meth)acrylic resins comprising at least one monomer unit selected from the group consisting of a monomer unit represented by formula (2) and a 2-hydroxyethyl methacrylate monomer unit

 where R 2 represents a hydrogen atom or a methyl group, and

the shell content is from 0.7 to 2.5 mass parts per 100.0 mass parts of the resin component in the core particle.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 2, 2021
From: ISONO, NAOYA; NAKAYAMA, KENICHI; KYUUSHIMA, HIROFUMI; KATO, MAI
To: CANON KABUSHIKI KAISHA
Reel/Frame 055814/0912 →
Priority Claims (1)
JP 2020-053059 · Mar 24, 2020 · national
Continuity (1)
Related Publication 20210318631A1 · Oct 14, 2021