IP Library Granted Patent US 12,140,355
Granted Patent B2
US 12,140,355 · App. 18/413,994 · Granted Nov 12, 2024

Heat exchanger integration with membrane system for evaporator pre-concentration

Inventors: Kyle Vanzandt (Watertown, MA); Marcus Lundgren (Cambridge, MA); Brent D. Keller (Somerville, MA)
Assignee: Via Separations, Inc.
F25B43/00B01D71/024B01D2311/04B01D2311/106
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Quick Facts
Patent No.
US 12,140,355
App. No.
18/413,994
Granted
Nov 12, 2024
Kind
B2
Abstract

A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.

Claims (92)

1. A system, comprising:

a membrane system configured to receive a liquid feed and produce a concentrate and a permeate, the membrane system including:

a graphene oxide membrane;

a passive cooling system; and

an active cooling system;

a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed; and

a controller configured to:

determine performance of the passive cooling system; and

adjust an operation of the active cooling system based on the determined performance of the passive cooling system, such that cooling of the membrane system is at a target cooling level.

2. The system of claim 1 , wherein the liquid feed comprises black liquor.

3. The system of claim 1 , wherein the active cooling system includes at least one of a water sprayer, a heat sink with cooling fins, or a membrane system heat exchanger.

4. The system of claim 1 , wherein the passive cooling system includes an insulated piping, a membrane housing, or a combination thereof.

5. The system of claim 1 , wherein the controller is further configured to control an operation of the heat exchanger to control a temperature of the liquid feed based on the determined performance of the passive cooling.

6. The system of claim 1 , wherein the heat exchanger is further configured to heat the concentrate by transferring heat from the liquid feed to the concentrate, and the controller is further configured to:

determine a temperature of the concentrate before the concentrate enters the heat exchanger or after the concentrate leaves the heat exchanger; and

adjust a heat transfer rate between the liquid feed and the concentrate based on the determined temperature of the concentrate.

7. The system of claim 6 , wherein adjusting the heat transfer rate includes reducing or increasing an effective heat transfer area of the heat exchanger.

8. The system of claim 6 , wherein adjusting the heat transfer rate includes:

separating a flow of the liquid feed into a first flow and a second flow, wherein:

the first flow is configured to pass through the heat exchanger;

the second flow is configured to bypass the heat exchanger; and

the controller is configured to determine a magnitude of the first flow and/or second flow; and

recombining the first and the second flow after the first flow passes through the heat exchanger.

9. The system of claim 6 , wherein the controller is further configured to determine a membrane temperature and adjust a heat transfer rate between the liquid feed and the concentrate based on the determined membrane temperature.

10. The system of claim 9 , wherein the controller is configured to:

increase a temperature of the liquid feed if the membrane temperature is below a target temperature value; and

decrease the temperature of the liquid feed if the membrane temperature is above the target temperature value.

11. A system, comprising:

a membrane system configured to receive a liquid feed and produce a concentrate and a permeate, the membrane system including:

a graphene oxide membrane;

a first heat exchanger in fluid communication with the membrane system and disposed

upstream of the membrane system;

a second heat exchanger in fluid communication with both the first heat exchanger and the membrane system and disposed between the first heat exchanger and the membrane system, such that the liquid feed enters the first heat exchanger, the second heat exchanger, and the membrane system sequentially; and

a controller configured to:

determine the membrane temperature;

adjust a heat transfer rate in the first heat exchanger based on the determined membrane temperature; and

adjust a heat transfer rate in the second heat exchanger based on the determined membrane temperature;

wherein the first heat exchanger is configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate.

12. The system of claim 11 , wherein the liquid feed includes black liquor.

13. The system of claim 11 , wherein the controller is further configured to:

determine a temperature of the concentrate before the concentrate enters the first heat exchanger or after the concentrate leaves the first heat exchanger; and

adjust the heat transfer rate in the first heat exchanger based on at least one of the determined temperature of the concentrate, or the membrane temperature.

14. The system of claim 11 , wherein the controller is further configured to:

determine a change in a flow rate of the liquid feed; and

adjust the heat transfer rate in the first heat exchanger or the second heat exchanger based on at least one of the determined change in the flow rate of the liquid feed or the membrane temperature.

15. The system of claim 11 , wherein the second heat exchanger is configured to cool the liquid feed and heat the permeate by transferring heat from the liquid feed to the permeate; and the controller is further configured to:

determine a temperature (T c ) of the concentrate;

determine a temperature (T f ) of the liquid feed;

determine a temperature (T p ) of the permeate; and

adjust a heat flow between the liquid feed and the concentrate and between the liquid feed and the permeate based on the determined T c , T f , and T p to minimize a system objective function F.

16. The system of claim 15 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 , wherein T c ref is a concentrate reference temperature, and T f ref is a feed reference temperature, and w 1 and w 2 are weights ranging between zero and one.

17. The system of claim 15 , wherein the system objective function F is F=(T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 +w 3 (T p −T p ref ), wherein T c ref is a concentrate reference temperature, T f ref is a feed reference temperature, and T p ref is a permeate reference temperature, and w 1 , w 2 , and w 3 are weights ranging between zero and one.

18. A system, comprising:

a membrane system configured to receive a liquid feed and produce a concentrate and a permeate, the membrane system including:

a graphene oxide membrane;

a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and

a controller configured to determine the membrane temperature and adjust a heat transfer rate between the liquid feed and the concentrate based on the determined membrane temperature.

19. The system of claim 18 , wherein the liquid feed includes black liquor.

20. The system of claim 18 , wherein the heat exchanger operates at about atmospheric pressure.

21. The system of claim 18 , wherein the membrane system further comprises:

a passive cooling system; and

an active cooling system including at least one of a water sprayer, a heat sink with cooling fins, or a membrane system heat exchanger.

22. The system of claim 21 , wherein the controller is further configured to:

determine performance of the passive cooling system; and

adjust an operation of the active cooling system based on the determined performance of the passive cooling system, such that cooling of the membrane system is at a target level.

23. The system of claim 18 , wherein the controller is further configured to:

increase a temperature of the liquid feed if the membrane temperature is below a target temperature value; and

decrease the temperature of the liquid feed if the membrane temperature is above the target temperature value.

24. The system of claim 18 , wherein a temperature difference between the concentrate prior to entering the heat exchanger and the liquid feed prior to entering the heat exchanger is between about 10-40 degrees Celsius.

25. A system, comprising:

a membrane system configured to receive a liquid feed and produce a concentrate and a permeate, the membrane system including:

a graphene oxide membrane;

a first heat exchanger in fluid communication with the membrane system and disposed

upstream of the membrane system;

a second heat exchanger in fluid communication with both the first heat exchanger and the membrane system and disposed between the first heat exchanger and the membrane system, such that the liquid feed enters the first heat exchanger, the second heat exchanger, and the membrane system sequentially; and

a controller configured to:

determine a change in a flow rate of the liquid feed; and

adjust a heat transfer rate in the first heat exchanger or the second heat exchanger based on the determined change in the flow rate of the liquid feed;

wherein:

the first heat exchanger is configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and

the second heat exchanger is configured to cool the liquid feed and heat the permeate by transferring heat from the liquid feed to the permeate.

26. The system of claim 25 , wherein the liquid feed includes black liquor.

27. The system of claim 25 , wherein adjusting the heat transfer rate in the first heat exchanger or the second heat exchanger includes reducing or increasing an effective heat transfer area of the first heat exchanger or the second heat exchanger.

28. The system of claim 25 , wherein the controller is further configured to:

determine a temperature of the concentrate before the concentrate enters the first heat exchanger or after the concentrate leaves the first heat exchanger; and

adjust a heat transfer rate in the first heat exchanger between the liquid feed and the concentrate based on the determined temperature of the concentrate.

29. The system of claim 25 , wherein the controller is further configured to:

determine a temperature (T c ) of the concentrate;

determine a temperature (T f ) of the liquid feed;

determine a temperature (T p ) of the permeate; and

adjust a heat flow between the liquid feed and the concentrate and between the liquid feed and the permeate based on the determined T c , T f , and T p to minimize a system objective function F.

30. The system of claim 29 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 +w 3 (T p −T p ref ), wherein T c ref is a concentrate reference temperature, T f ref is a feed reference temperature, and T p ref is a permeate reference temperature, and w 1 , w 2 , and w 3 are weights ranging between zero and one.

Assignments (2)
SECURITY INTEREST Recorded Oct 13, 2025
From: VIA SEPARATIONS, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 072547/0699 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 22, 2024
From: VANZANDT, KYLE; LUNDGREN, MARCUS; KELLER, BRENT D.
To: VIA SEPARATIONS, INC.
Reel/Frame 066871/0673 →
Continuity (4)
Continuation 18141316 · Apr 28, 2023
Continuation PCTUS2022080120 · Nov 18, 2022
Provisional Application 63283767 · Nov 29, 2021
Related Publication 20240151445A1 · May 9, 2024