Carbon material for use as catalyst carrier of polymer electrolyte fuel cell and method of producing the same
A carbon material for use as a catalyst carrier for a polymer electrolyte fuel cell which is a porous carbon material and satisfies at the same time (1) the content of a crystallized material is 1.6 or less, (2) the BET specific surface area obtained by a BET analysis of a nitrogen gas adsorption isotherm is from 400 to 1500 m 2 /g, (3) the cumulative pore volume V 2-10 with respect to a pore diameter of from 2 to 10 nm obtained by an analysis of a nitrogen gas adsorption isotherm using the Dollimore-Heal method is from 0.4 to 1.5 mL/g, and (4) the nitrogen gas adsorption amount V macro between a relative pressure of 0.95 and 0.99 in a nitrogen gas adsorption isotherm is from 300 to 1200 cc (STP)/g, and the method of producing the same.
1. A carbon material for use as a catalyst carrier for a polymer electrolyte fuel cell, having a three-dimensional dendritic structure in which a rod-shaped body or a ring-shaped body is branched three-dimensionally, the carbon material being a porous carbon material made from a silver acetylide and satisfying the following (1), (2), (3), and (4) at the same time:
(1) a content of a crystallized material defined below is 1.2 or more and 1.6 or less,
wherein the content of the crystallized material is determined by [(C/A)−(B/A)], when the carbon material for use as a catalyst carrier is heated at 2050° C. in an inert atmosphere for 1 hour and powder X-ray diffractometry is performed, and a height of a baseline of a diffraction peak of a (002) plane at the location of a second peak appearing near a diffraction angle of 25.5° to 26.5° is defined as the A value, a height of a baseline of the second peak near the diffraction angle of 25.5° to 26.5° at the location of the second peak appearing near the diffraction angle of 25.5° to 26.5° is defined as the B value, and an intensity of the second peak near the diffraction angle of 25.5° to 26.5° is defined as the C value;
(2) a BET specific surface area obtained by a BET analysis of a nitrogen gas adsorption isotherm is from 400 to 1500 m 2 /g;
(3) a cumulative pore volume V 2-10 with respect to a pore diameter of from 2 to 10 nm obtained by an analysis of a nitrogen gas adsorption isotherm using the Dollimore-Heal method is from 0.4 to 1.5 mL/g; and
(4) a nitrogen gas adsorption amount V macro between a relative pressure of 0.95 and 0.99 in a nitrogen gas adsorption isotherm is from 300 to 1200 cc/g in standard temperature and pressure (STP).
2. The carbon material for use as a catalyst carrier for a polymer electrolyte fuel cell according to claim 1 , wherein a half-value width ΔG of a G-band detected in a range of from 1550 to 1650 cm −1 of a Raman spectrum is from 50 to 70 cm −1 .
3. The carbon material for use as a catalyst carrier for a polymer electrolyte fuel cell according to claim 2 , wherein the V 2-10 is from 0.5 to 1.0 mL/g.
4. The carbon material for use as a catalyst carrier for a polymer electrolyte fuel cell according to claim 1 , wherein the V 2-10 is from 0.5 to 1.0 mL/g.