Bio-based, biodegradable compositions and articles made therefrom
Disclosed herein are compositions and articles made therefrom, the compositions and articles comprising at least one hydrocolloid, at least one plasticizer, at least one filler and/or humectant and water. Typically, the components are derived from biological sources, such as seaweed, plants, or animals. Typically, the components are made from food quality ingredients, making the compositions and articles edible and/or biodegradable. The compositions are used to form articles, such as straws, and the articles have desirable flexibility and moisture barrier properties, such as swelling resistance, as well as biodegradability and/or compostability properties.
1. A process to make a biodegradable pellet, the process comprising:
combining (i) a hydrocolloid, wherein the hydrocolloid comprises carrageenan present in an amount of 10-20% based on total weight of the mixture, and chitosan present in amount of 10-20% based on total weight of the mixture, (ii) a plasticizer, wherein the plasticizer is a glycerol present in an amount of 5-20% based on the total weight of the mixture, (iii) a filler, wherein the filler is a CaCO 3 present in an amount of 5-20% based on the total weight of the mixture, and (iv) water, so as to make a mixture; and
subjecting the mixture to a hot-melt extrusion to form the biodegradable pellet.
2. The process of claim 1 , further comprising the step of forming the pellet into a shape.
3. The method of claim 1 , wherein the carrageenan comprises kappa-carrageenan.
4. The method of claim 1 , wherein the plasticizer comprises a combination of glycerol, and esterified or alkylated glycerol, wherein the esterified or alkylated glycerol has 4 to 20 carbon atoms in the ester or alkyl group.
5. The method of claim 1 , further comprising the step of applying a coating to the biodegradable pellet.
6. The method of claim 5 , wherein the coating is a hydrophobic coating.
7. The method of claim 6 , wherein the coating ranges in thickness from 10 nm to 100 micron.
8. The method of claim 1 , wherein an article comprising the mixture exhibits a tensile strength of 10 to 50 MPa.
9. The method of claim 1 , wherein an article comprising the mixture exhibits a Young's modulus of 50 to 500 MPa.
10. The method of claim 1 , wherein an article comprising the mixture exhibits a compressive strength of 10 to 100 MPa.
11. The method of claim 1 , wherein an article comprising the mixture exhibits swelling in room temperature water of less than 50% by weight.
12. The method of claim 2 , wherein the hot-melt extrusion is performed with a screw extruder.
13. The method of claim 11 , wherein the screw extruder is a twin-screw hot-melt extruder.
14. The method of claim 12 , wherein the hot-melt extruder is operated at a temperature of 70-100° C.
15. The method of claim 13 , wherein the hot-melt extruder is operated at a temperature of 70-100° C.
16. The method of claim 12 , wherein the hot-melt extruder has a feeding weight ratio of solids to liquids of 1:6 to 1:1.
17. The method of claim 13 , wherein the hot-melt extruder has a feeding weight ratio of solids to liquids of 1:6 to 1:1.
18. The method of any one of claim 16 , wherein the solids comprise a mixture of the carrageenan, the chitosan, and the CaCO 3 .
19. The method of any one of claim 17 , wherein the solids comprise a mixture of the carrageenan, the chitosan, and the CaCO 3 .