Bonded body, ceramic copper circuit board, method for manufacturing bonded body, and method for manufacturing ceramic copper circuit board
A bonded body includes a ceramic substrate and a copper plate, in which the copper plate is bonded to the ceramic substrate via a bonding layer, the copper plate includes a surface perpendicular to a direction in which the ceramic substrate and the copper plate are bonded, and a number percentage of copper crystal grains having major diameters greater than 400 μm in three 5 mm×5 mm regions included in the surface is not less than 0% and not more than 5%. The bonding temperature is favorably not more than 800° C. The number percentage of the copper crystal grains having major diameters greater than 400 μm is favorably not more than 1%.
1. A bonded body, comprising:
a ceramic substrate; and
a copper plate bonded to the ceramic substrate via a bonding layer,
the copper plate including a surface perpendicular to a direction in which the ceramic substrate and the copper plate are bonded,
a number percentage of copper crystal grains having major diameters greater than 400 μm in three 5 mm×5 mm regions included in the surface being not less than 0% and not more than 5%, and
an average value of the major diameters of the copper crystal grains in the three regions is not less than 30 μm and not more than 300 μm.
2. The body according to claim 1 , wherein
the number percentage is not more than 1%.
3. The body according to claim 1 , wherein
an average value of the major diameters of the copper crystal grains in the three regions is not less than 50 μm and not more than 150 μm.
4. The body according to claim 1 , wherein
a number percentage of the copper crystal grains having major diameters within an average range in the three regions is not less than 80%, and
the average range is not less than 0.5 times and not more than 2 times an average value of the major diameters of the copper crystal grains in the three regions.
5. The body according to claim 1 , wherein
an arithmetic average height Wa of a waviness curve of the ceramic substrate is not more than 2 μm, and
a maximum cross-sectional height Wt of the waviness curve is not more than 10 μm.
6. The body according to claim 1 , wherein
the bonding layer includes Ag, Cu, and Ti.
7. The body according to claim 1 , wherein
the ceramic substrate is one of a silicon nitride substrate or an aluminum nitride substrate.
8. The body according to claim 1 , wherein
an average value of the major diameters of the copper crystal grains in the three regions is not less than 30 μm and not more than 300 μm,
a number percentage of the copper crystal grains having major diameters within an average range in the three regions is not less than 80%, and
the average range is not less than 0.5 times and not more than 2 times an average value of the major diameters of the copper crystal grains in the three regions.
9. The body according to claim 8 , wherein
an arithmetic average height Wa of a waviness curve of the ceramic substrate is not more than 2 μm, and
a maximum cross-sectional height Wt of the waviness curve is not more than 10 μm.
10. The body according to claim 9 , wherein
the bonding layer includes Ag, Cu, and Ti.
11. The body according to claim 10 , wherein
the ceramic substrate is one of a silicon nitride substrate or an aluminum nitride substrate.
12. A ceramic copper circuit board using the bonded body according to claim 1 .
13. A method for manufacturing the bonded body according to claim 1 , the method comprising:
a process of disposing a brazing material used as the bonding layer between the ceramic substrate and the copper plate; and
a bonding process including a bonding temperature of not more than 800° C.
14. The method according to claim 13 , wherein the bonding temperature is not more than 700° C.
15. The method according to claim 13 , wherein B/A≤10 is satisfied,
A (μm) is an average value of the major diameters of the copper crystal grains of the copper plate before bonding, and
B (μm) is an average value of the major diameters of the copper crystal grains of the copper plate after bonding.
16. The method according to claim 15 , wherein 1.1<B/A<5 is satisfied.
17. The method according to claim 13 , wherein a largest endothermic peak of a DSC curve of the brazing material is at not more than 700° C.
18. A method for manufacturing a ceramic copper circuit board, the method comprising:
a method for manufacturing the bonded body according to claim 1 ; and
a process of providing a circuit structure in the bonded copper plate.