IP Library › Granted Patent US 12,161,537
Granted Patent B2
US 12,161,537 · App. 17/311,608 · Granted Dec 10, 2024

Water-absorbent resin particles, water-absorbent article, and method for manufacturing same

Inventor: Hiroki Yabuguchi (Himeji, JP)
Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.
A61F13/49A61F13/53A61L15/24A61F2013/530569A61F2013/530591A61F2013/530737
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Quick Facts
Patent No.
US 12,161,537
App. No.
17/311,608
Granted
Dec 10, 2024
Kind
B2
Abstract

Water-absorbing resin particles, in which a permeation and spreading index represented by Formula (1) is 10.0 or higher, and a water absorption capacity for a physiological saline solution is 50.0 g/g or more, are disclosed. Formula (1): Permeation and spreading index=value of non-pressurization DW after 1 minute (mL/g)+artificial urine permeation speed when water-absorbing resin particles are swollen 10 times (g/min)  (1).

Claims (48)

1. Water-absorbing resin particles comprising:

a polymer particle comprising a crosslinked polymer having a monomer unit derived from an ethylenically unsaturated monomer including at least one compound selected from the group consisting of (meth)acrylic acid and a salt thereof; and

a plurality of inorganic particles disposed on a surface of the polymer particle,

wherein a proportion of a (meth)acrylic acid and a salt thereof is 70 to 100 mol % with respect to a total amount of monomer units in the crosslinked polymer,

a permeation and spreading index represented by Formula (1) is 10.0 or higher, and

a water absorption capacity for a physiological saline solution is 50.0 g/g or more,

Formula (1):

permeation and spreading index=value of non-pressurization demand wettability ( DW ) after 1 minute (mL/g)+artificial urine permeation speed when water-absorbing resin particles are swollen 10 times (g/min)  (1).

2. The water-absorbing resin particles according to claim 1 ,

wherein the permeation and spreading index is 13.0 or higher.

3. The water-absorbing resin particles according to claim 1 ,

wherein the value of non-pressurization DW after 1 minute is 3.0 mL/g or more.

4. The water-absorbing resin particles according to claim 1 ,

wherein the permeation and spreading index is 14.0 or higher.

5. The water-absorbing resin particles according to claim 1 ,

wherein the permeation and spreading index is 14.0 or higher and 25.0 or lower.

6. The water-absorbing resin particles according to claim 1 ,

wherein the value of non-pressurization DW after 1 minute is 7.0 mL/g or more.

7. The water-absorbing resin particles according to claim 1 , wherein the artificial urine permeation speed when the water-absorbing resin particles are swollen 10 times is 1.0 g/min or more.

8. The water-absorbing resin particles according to claim 1 ,

the artificial urine permeation speed when water-absorbing resin particles are swollen 10 times is 1.0 g/min or more and 15.0 g/min or less.

9. The water-absorbing resin particles according to claim 1 ,

wherein a water absorption capacity of the water-absorbing resin particles for a physiological saline solution under a load is 10 to 40 mL/g.

10. The water-absorbing resin particles according to claim 1 ,

wherein a water absorption capacity of the water-absorbing resin particles for a physiological saline solution under a load is 22 to 28 mL/g.

11. The water-absorbing resin particles according to claim 1 ,

wherein a median particle size of the water-absorbing resin particles is 250 to 850 μm.

12. The water-absorbing resin particles according to claim 1 ,

wherein a median particle size of the water-absorbing resin particles is 300 to 600 μm.

13. The water-absorbing resin particles according to claim 1 ,

wherein a water absorption capacity for a physiological saline solution is 50.0 g/g or more and 70 g/g or less.

14. An absorbent article comprising:

a liquid-impermeable sheet;

an absorbent; and

a liquid-permeable sheet,

wherein the liquid-impermeable sheet, the absorbent, and the liquid-permeable sheet are disposed in this order, and

the absorbent comprises the water-absorbing resin particles according to claim 1 .

15. A method for manufacturing an absorbent article, the method comprising:

sorting out water-absorbing resin particles in which a permeation and spreading index represented by Formula (1) is 10.0 or higher, and a water absorption capacity for a physiological saline solution is 50.0 g/g or more; and

disposing an absorbent containing the sorted water-absorbing resin particles between a liquid-impermeable sheet and a liquid-permeable sheet,

wherein the water-absorbing resin particles comprise

a polymer particle containing a crosslinked polymer having a monomer unit derived from an ethylenically unsaturated monomer including at least one compound selected from the group consisting of (meth)acrylic acid and a salt thereof, and

a plurality of inorganic particles disposed on a surface of the polymer particle, and

a proportion of a (meth)acrylic acid and a salt thereof is 70 to 100 mol % with respect to a total amount of monomer units in the crosslinked polymer,

Formula (1):

permeation and spreading index=value of non-pressurization DW after 1 minute (mL/g)+artificial urine permeation speed when water-absorbing resin particles are swollen 10 times (g/min)  (1).

16. The method according to claim 15 ,

wherein the value of non-pressurization DW after 1 minute of the sorted water-absorbing resin particles is 3.0 mL/g or more.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 17, 2021
From: YABUGUCHI, HIROKI
To: SUMITOMO SEIKA CHEMICALS CO., LTD.
Reel/Frame 056578/0735 →
Priority Claims (4)
JP 2018-232851 · Dec 12, 2018 · national
JP 2019-014545 · Jan 30, 2019 · national
JP 2019-055270 · Mar 22, 2019 · national
JP 2019-055332 · Mar 22, 2019 · national
Continuity (1)
Related Publication 20220015959A1 · Jan 20, 2022