IP Library › Granted Patent US 12,167,661
Granted Patent B2
US 12,167,661 · App. 18/400,296 · Granted Dec 10, 2024

Organic light-emitting device

Inventors: Hajin Song (Yongin-si, KR); Jihwan Yoon (Yongin-si, KR); Sangwoo Lee (Yongin-si, KR); Sangwoo Pyo (Yongin-si, KR)
Assignee: Samsung Display Co., Ltd.
H10K59/35H10K50/11H10K50/125H10K50/15H10K50/16H10K59/131H10K71/00H10K50/852H10K59/1201H10K85/655H10K85/6572H10K2101/10H10K2101/27H10K2101/30H10K2101/40H10K2101/90
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Quick Facts
Patent No.
US 12,167,661
App. No.
18/400,296
Granted
Dec 10, 2024
Kind
B2
Abstract

An organic light-emitting device and display apparatus, the device including a first electrode; a second electrode facing the first electrode; an emission layer between the first and second electrode; a hole control layer between the first electrode and the emission layer; and an electron control layer between the emission layer and the second electrode, wherein the emission layer includes a plurality of sub-emission layers to emit light having different wavelengths, at least portions of the plurality of sub-emission layers do not overlap one another, the plurality of sub-emission layers include: a first sub-emission layer including a first color light-emitting dopant, and a second sub-emission layer including a second color light-emitting dopant, the first and second sub-emission layers each include a hole-transporting and electron-transporting host which form an exciplex, and a triplet energy of the exciplex is equal to or greater than triplet energies of the first and second color light-emitting dopant.

Claims (60)

1. A light-emitting display apparatus, comprising:

a timing controller;

a scan driver;

a source driver; and

a light-emitting display panel including a light-emitting device and defining a first pixel area, a second pixel area, and a third pixel area,

wherein the light-emitting device comprises:

a first electrode;

a hole control layer on the first electrode;

an emission layer on the hole control layer;

an electron control layer on the emission layer;

a second electrode on the electron control layer; and

a capping layer on the second electrode,

the emission layer comprises a plurality of sub-emission layers comprising a first sub-emission layer corresponding to the first pixel area, a second sub-emission layer corresponding to the second pixel area, and a third sub-emission layer corresponding to the third pixel area,

the first sub-emission layer comprises a first hole-transporting host, a first electron-transporting host, and a first color light-emitting dopant,

the second sub-emission layer comprises a second hole-transporting host, a second electron-transporting host, and a second color light-emitting dopant,

the third sub-emission layer comprises a third hole-transporting host, a third electron-transporting host, and a third color light-emitting dopant, and

at least one of the first color light-emitting dopant, the second color light-emitting dopant, and the third color light-emitting dopant emits thermally activated delayed fluorescence (TADF) light.

2. The light-emitting display apparatus as claimed in claim 1 ,

wherein a difference between a lowest unoccupied molecular orbital (LUMO) energy level of the first hole-transporting host and a LUMO energy level of the first electron-transporting host is about 0.2 eV or more.

3. The light-emitting display apparatus as claimed in claim 2 ,

wherein the first hole-transporting host and the first electron-transporting host form a first exciplex,

the first color light-emitting dopant emits phosphorescent light; and

a triplet energy of the first exciplex is equal to or greater than a triplet energy of the first color light-emitting dopant.

4. The light-emitting display apparatus as claimed in claim 3 ,

wherein the triplet energy of the first exciplex is about 2.4 eV to about 3.0 eV.

5. The light-emitting display apparatus as claimed in claim 1 ,

wherein a difference between a lowest unoccupied molecular orbital (LUMO) energy level of the second hole-transporting host and a LUMO energy level of the second electron-transporting host is about 0.2 eV or more.

6. The light-emitting display apparatus as claimed in claim 5 ,

wherein the second hole-transporting host and the second electron-transporting host form a second exciplex,

the second color light-emitting dopant emits phosphorescent light; and

a triplet energy of the second exciplex is equal to or greater than a triplet energy of the second color light-emitting dopant.

7. The light-emitting display apparatus as claimed in claim 6 ,

wherein the triplet energy of the second exciplex is about 2.4 eV to about 3.0 eV.

8. The light-emitting display apparatus as claimed in claim 1 ,

wherein the third hole-transporting host and the third electron-transporting host form a third exciplex,

the third color light-emitting dopant emits thermally activated delayed fluorescence (TADF) light, and

a difference between a triplet energy level of the third exciplex and a singlet energy level of the third color light-emitting dopant is about −0.1 eV to about 0.1 eV.

9. The light-emitting display apparatus as claimed in claim 1 ,

wherein the capping layer includes at least one of an amine compound, a carbazole compound, or a naphthalene compound.

10. The light-emitting display apparatus as claimed in claim 1 ,

wherein a thickness of the first sub-emission layer is thicker than a thickness of the second sub-emission layer, and

the thickness of the second sub-emission layer is thicker than a thickness of the third sub-emission layer.

11. The light-emitting display apparatus as claimed in claim 1 ,

wherein the emission layer further includes an auxiliary layer that disposed between the hole control layer and the plurality of sub-emission layers.

12. The light-emitting display apparatus as claimed in claim 11 ,

wherein the auxiliary layer comprises:

a first auxiliary layer disposed between the hole control layer and the first sub-emission layer;

a second auxiliary layer disposed between the hole control layer and the second sub-emission layer; and

a third auxiliary layer disposed between the hole control layer and the third sub-emission layer.

13. The light-emitting display apparatus as claimed in claim 12 , wherein

the first auxiliary layer disposed on the hole control layer corresponding to the first pixel area;

the second auxiliary layer disposed on the hole control layer corresponding to the second pixel area; and

the third auxiliary layer disposed on the hole control layer corresponding to the third pixel area.

14. The light-emitting display apparatus as claimed in claim 13 ,

wherein a thickness of the first auxiliary layer is thicker than a thickness of the second auxiliary layer, and

a thickness of the second auxiliary layer is thicker than a thickness of the third auxiliary layer.

15. The light-emitting display apparatus as claimed in claim 12 , wherein

the first auxiliary layer disposed on the second auxiliary layer corresponding to the first pixel area;

the second auxiliary layer disposed on the third auxiliary layer corresponding to the first pixel area and the second pixel area; and

the third auxiliary layer disposed on the hole control layer corresponding to the first pixel area, the second pixel area and the third pixel area.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 29, 2023
From: SONG, HAJIN; YOON, JIHWAN; LEE, SANGWOO; PYO, SANGWOO
To: SAMSUNG DISPLAY CO., LTD.
Reel/Frame 065981/0726 →
Priority Claims (1)
KR 10-2015-0150453 · Oct 28, 2015 · national
Continuity (8)
Continuation 18154471 · Jan 13, 2023
Continuation 17201737 · Mar 15, 2021
Continuation 16852875 · Apr 20, 2020
Continuation 16432375 · Jun 5, 2019
Continuation 15870389 · Jan 12, 2018
Continuation 15141910 · Apr 29, 2016
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