Method for producing a decorative mineral composite body
A method for producing a decorated mineral composite body, a decorated mineral composite body and the use of a multilayer film for producing a decorated mineral composite body.
1. A method for producing a decorated mineral composite body using at least one multilayer film, wherein the method comprises the following steps:
a) providing at least one forming element with at least one outer surface and at least one inner surface,
b) applying a flowable or plastically deformable, mineral construction material mixture, which comprises water and at least one mineral binding agent, to the at least one inner surface of the forming element,
c) increasing the viscosity of the mineral construction material mixture to obtain a dimensionally stable, mineral green body, and
d) increasing the hardness of the mineral construction material mixture,
wherein the multilayer film has a carrier ply and a transfer ply, which contains at least one decorative element, arranged on the carrier ply,
wherein the transfer ply has at least one anionically functionalized primer layer on the side facing away from the carrier ply, and
wherein the at least one anionically functionalized primer layer contains at least one polymer having at least one free, anionic, functional group, and
wherein I), before step b), the at least one multilayer film is arranged with the side of the carrier ply facing away from the at least one anionically functionalized primer layer on the at least one inner surface of the provided forming element, and, in step b), the at least one anionically functionalized primer layer is brought into contact with the flowable or plastically deformable, mineral construction material mixture, wherein, in step c), the decorated, dimensionally stable, mineral green body is obtained,
and/or
wherein II), in and/or after step c), the at least one multilayer film is arranged with the at least one anionically functionalized primer layer on the dimensionally stable, mineral green body, wherein the decorated, dimensionally stable, mineral green body is obtained, and
wherein, in alternatives I) and II), the decorated mineral composite body is obtained after step d).
2. The method according to claim 1 , wherein the at least one mineral binding agent is selected from the group which consists of calcium silicate hydrates, cement, lime, clay, gypsum, loam, magnesia binder and combinations thereof.
3. The method according to claim 1 , wherein the mineral construction material mixture comprises or consists of concrete, mortar, sand-lime brick, silicate ceramic or a combination thereof.
4. The method according to claim 1 , wherein the mineral construction material mixture comprises or consists of concrete or mortar, wherein the at least one mineral binding agent comprises or consists of cement, and wherein the mineral construction material mixture furthermore comprises aggregate.
5. The method according to claim 1 , wherein the mineral construction material mixture comprises or consists of sand-lime brick or autoclaved aerated concrete, wherein the at least one mineral binding agent comprises or consists of a calcium silicate hydrate,
wherein, in step d), the decorated, dimensionally stable, mineral green body is hydrothermally hardened, to obtain the decorated mineral composite body.
6. The method according to claim 1 , wherein the mineral construction material mixture comprises or consists of a silicate ceramic, wherein the at least one mineral binding agent comprises or consists of a clay mineral
wherein, in step c), the dimensionally stable, mineral green body is obtained by means of pressing, slip casting, injection molding, film casting, modeling and/or extruding, and
wherein, in step d), the decorated, dimensionally stable, mineral green body is fired to obtain the decorated mineral composite body.
7. The method according to claim 6 , wherein the at least one multilayer film comprises at least one fireproof decorative element.
8. The method according to claim 1 , wherein the carrier ply comprises at least one carrier layer made of a polyester, a polyolefin or a combination thereof.
9. The method according to claim 8 , wherein the at least one carrier layer of the carrier ply has a layer thickness between 4 μm and 100 μm.
10. The method according to claim 1 , wherein the carrier ply furthermore comprises at least one detachment layer, which is arranged on the side of the carrier ply facing the transfer ply.
11. The method according to claim 10 , wherein the at least one detachment layer comprises at least one wax at least one silicone, at least one polyurethane or a combination thereof.
12. The method according to claim 1 , wherein the at least one anionically functionalized primer layer has a residual moisture content of at most 5 wt.-%, in each case relative to the total weight of all constituents of the primer layer.
13. The method according to claim 1 , wherein the at least one polymer having at least one free, anionic, functional group is selected from the group which consists of carboxylate, sulfonate, sulfate, phosphonate, phosphate and combinations thereof.
14. The method according to claim 13 , wherein the at least one polymer which has at least one free, anionic, functional group is selected from the group which consists of anionically functionalized epoxide polymers and copolymers, anionically functionalized acrylic polymers and copolymers, anionically functionalized methacrylic polymers and copolymers, anionically functionalized polyurethane polymers and copolymers and mixtures thereof.
15. The method according to claim 1 , wherein the at least one decorative element influences the surface texture, the color of the surface, the mechanical properties and/or the chemical properties of the decorated mineral composite body.
16. The method according to claim 1 , wherein at least one functional layer is arranged between the at least one anionically functionalized primer layer and the carrier ply.
17. The method according to claim 16 , wherein the at least one functional layer arranged between the at least one anionically functionalized primer layer and the carrier ply comprises or consists of at least one metal and/or semi-metal, alloys thereof or mixture thereof, at least one polymer, selected from cellulose-based polymers, chlorinated polyolefins, chlorinated rubbers, colophony resins, epoxy resins, EVA copolymers, formaldehyde resins, hydrocarbon resins, ketone/aldehyde resins, maleinate resins, melamine resins, phenolic resins, polyacrylates, polyacrylate dispersions, polyester dispersions, polyurethane dispersions, polyether dispersions, polyamide resins, polyester resins, polyisocyanates, polyolefin resins, polystyrene resins, polyurethane resins, polyvinyl acetals, polyvinyl acetates, polyvinyl alcohols, polyvinyl butyrals, polyvinyl chlorides, polyvinyl propionates, polyvinylpyrrolidones, polyvinylidene chlorides, polyvinylidene fluorides, shellacs, silicone resins, styrene acrylate dispersions, sulfonamide resins, urea resins, acrylonitrile-1,3-butadiene-styrene (ABS) resins and mixtures thereof.
18. The method according to claim 16 , wherein the at least one functional layer arranged between the at least one anionically functionalized primer layer and the carrier ply is selected from the group which consists of transparent and/or colored varnish layers, replication layers with a molded optically active surface structure, reflective layers, optically variable layers, optically active layers, interference multilayer systems, volume hologram layers, liquid crystal layers, electrically conductive layers, antenna layers, electrode layers, magnetic layers, magnetic storage layers, barrier layers and combinations thereof.