Composite particles for electrochemical device and method of producing same, binder composition for electrochemical device functional layer and method of producing same, conductive material paste for electrode mixed material layer and method of producing same, slurry for electrode mixed material layer, electrode for electrochemical device, and electrochemical device
Provided is a novel technique relating to electrochemical devices that makes it possible to ensure a high level of safety of an electrochemical device while also causing the electrochemical device to display excellent high-temperature storage characteristics. One or more composite particles for an electrochemical device each include a core particle and a shell portion at least partially covering an outer surface of the core particle. The core particle contains a melamine compound, and the shell portion contains an inorganic material.
1. One or more composite particles for an electrochemical device each comprising: a core particle; and a shell portion at least partially covering an outer surface of the core particle, wherein
the core particle contains a melamine compound represented by the following formula (I), where each A represents, independently of one another, a hydroxyl group or —NR 1 R 2 , where R 1 and R 2 each represent, independently of each other, a hydrogen atom, a hydrocarbon group, or a hydroxyl group-containing hydrocarbon group; when more than one R 1 is present in formula (I), each R 1 may be the same or different; and when more than one R 2 is present in formula (I), each R 2 may be the same or different,
and the shell portion contains an inorganic material.
2. The composite particles for an electrochemical device according to claim 1 , wherein the shell portion further contains a shell polymer.
3. The composite particles for an electrochemical device according to claim 2 , wherein the shell polymer includes at least one selected from the group consisting of a carboxy group, a hydroxyl group, a nitrile group, an amino group, an epoxy group, an oxazoline group, an isocyanate group, a sulfo group, an ester group, an aldehyde group, and an amide group.
4. The composite particles for an electrochemical device according to claim 2 , wherein the shell polymer includes a carboxy group and an amide group.
5. The composite particles for an electrochemical device according to claim 1 , wherein the core particle has a volume-average particle diameter of not less than 0.01 μm and not more than 10.00 μm.
6. The composite particles for an electrochemical device according to claim 1 , wherein the core particle has a volume-average particle diameter of not less than 0.01 μm and less than 1.00 μm.
7. The composite particles for an electrochemical device according to claim 1 , wherein the inorganic material includes a carbon material.
8. The composite particles for an electrochemical device according to claim 7 , wherein the carbon material includes carbon nanotubes.
9. The composite particles for an electrochemical device according to claim 1 , wherein the inorganic material includes a particulate inorganic material, and the particulate inorganic material has a volume-average particle diameter of not less than 1 nm and not more than 500 nm.
10. The composite particles for an electrochemical device according to claim 1 , wherein the inorganic material includes a fibrous inorganic material, and the fibrous inorganic material has an average minor axis of not less than 1 nm and not more than 500 nm.
11. The composite particles for an electrochemical device according to claim 1 , wherein the inorganic material includes a coupling agent.
12. The composite particles for an electrochemical device according to claim 11 , wherein the coupling agent includes a silane coupling agent.
13. A binder composition for an electrochemical device functional layer comprising: the composite particles for an electrochemical device according to claim 1 ; a binder for a functional layer; and a solvent.
14. The binder composition for an electrochemical device functional layer according to claim 13 , wherein the binder for a functional layer is a polymer including at least one selected from the group consisting of a carboxy group, a hydroxyl group, a nitrile group, an amino group, an epoxy group, an oxazoline group, an isocyanate group, a sulfo group, an ester group, an aldehyde group, and an amide group.
15. A conductive material paste for an electrode mixed material layer comprising: the binder composition for an electrochemical device functional layer according to claim 13 ; and a conductive material.
16. A slurry for an electrode mixed material layer comprising: the conductive material paste for an electrode mixed material layer according to claim 15 ; and electrode active material particles.
17. The slurry for an electrode mixed material layer according to claim 16 , wherein the electrode active material particles contain nickel.
18. An electrode for an electrochemical device comprising an electrode mixed material layer formed using the slurry for an electrode mixed material layer according to claim 16 .
19. An electrochemical device comprising the electrode for an electrochemical device according to claim 18 .
20. A method of producing the composite particles for an electrochemical device according to claim 1 , comprising a step of granulating a composition for composite particles that contains a core material including the melamine compound and a shell material including the inorganic material.
21. A method of producing a binder composition for an electrochemical device functional layer comprising a step of mixing the composite particles for an electrochemical device according to claim 1 , a binder for a functional layer, and a solvent.
22. A method of producing a conductive material paste for an electrode mixed material layer comprising:
a step of mixing the composite particles for an electrochemical device according to claim 1 , a binder for a functional layer, and a solvent to obtain a binder composition for an electrochemical device functional layer; and
a step of mixing the binder composition for an electrochemical device functional layer and a conductive material.