Reclaimed material for manufacturing shoes and method of producing reclaimed rubber by processing recycled shoe material waste
A method of producing a reclaimed rubber made of recycled shoe material waste includes the following steps. Step S 1 : collect a scrap rubber which is the shoe material waste. Step S 2 : grind the scrap rubber to form scrap rubber granules. Step S 3 : devulcanize the scrap rubber granules to form a reclaimed rubber. A reclaimed material for manufacturing shoes includes a reclaimed rubber formulation and a crosslinking agent, wherein the reclaimed rubber formulation is constituted by compounding a basic rubber formulation and the reclaimed rubber, wherein the reclaimed material for manufacturing shoes includes 65-94.8 wt % of the basic rubber formulation, 5-30 wt % of the reclaimed rubber, and 0.2 wt % to 5 wt % of crosslinking agent. Mechanical properties of the reclaimed material for manufacturing shoes meet required standards of shoe outsole material. A method of consuming rubber waste produced during the shoe manufacturing process is disclosed herein.
1. A method of producing a reclaimed rubber made of recycled shoe material waste, comprising:
step S 1 : obtaining a scrap rubber during a shoe manufacturing process, which is produced exclusively in the shoe manufacturing process, wherein the scrap rubber is a rubber waste produced during vulcanization of shoe outsole material;
step S 2 : shredding the scrap rubber to form scrap rubber granules; and
step S 3 : making the scrap rubber granules undergo a devulcanization reaction to form the reclaimed rubber, wherein the scrap rubber granules and N,N′-Thio-bis(phthalimide) undergo a first compounding process at 80-160 degrees Celsius to form an admixture, then the admixture undergoes a second compounding process at 80-160 degrees Celsius to form the reclaimed rubber; or wherein the scrap rubber granules and N,N′-Thio-bis(phthalimide) are mixed in a mixing process to form a mixed material, and wherein the mixed material is compounded by a twin-screw extruder running at a rotational speed in a range of 150 rpm to 350 rpm at 60-190 degrees Celsius to form the reclaimed rubber; and
wherein the reclaimed rubber is subject to a Soxhlet extractor with toluene as solvent for 24 hours to obtain a gel content of the reclaimed rubber according to ASTM D2765, and the gel content of the reclaimed rubber is in a range of 55% to 75%.
2. The method as claimed in claim 1 , wherein in the step S 2 , a particle size of the scrap rubber granules is smaller than or equal to 4 millimeters.
3. The method as claimed in claim 1 , wherein 100 parts of the scrap rubber granules and 1 to 20 part(s) of the N,N′-Thio-bis(phthalimide) by weight are compounded.
4. The method as claimed in claim 1 , wherein zinc oxide or magnesium oxide is added during the first compounding process, and stearic acid or derivatives of stearic acid added during the first compounding process.
5. The method as claimed in claim 1 , wherein zinc oxide or magnesium oxide is added during the mixing process, and stearic acid or the derivatives of stearic acid added during the mixing process.
6. A reclaimed material for manufacturing shoes, comprising:
a reclaimed rubber formulation including a basic rubber formulation and the reclaimed rubber produced by the method as claimed in claim 1 , wherein the basic rubber formulation is in a range of 65 wt % to 94.8 wt %, based on a total weight of the reclaimed material, and the reclaimed rubber is in a range of 5 wt % to 30 wt %, based on a total weight of the reclaimed material, wherein the basic rubber formulation comprises 100 parts of rubber material, 30 to 100 parts of silica (SiO2), and 5 to 60 parts of an additive by weight;
the additive is selected from the group consisting of an antioxidant, a softener, an activator, zinc oxide, a silane coupling agent, an antifogging agent, and a combination thereof; and
wherein the rubber material includes 50 to 80 parts of polybutadiene rubber, 15 to 35 parts of natural rubber, and 5-15 parts of nitrile butadiene rubber by weight; and
a crosslinking agent in a range of 0.2 wt % to 5 wt %, based on a total weight of the reclaimed material,
wherein the reclaimed rubber formulation and the crosslinking agent are compounded to vulcanize, thereby forming the reclaimed material.
7. The reclaimed material as claimed in claim 6 , wherein the crosslinking agent comprises 0.1-4.9 wt % of sulfur and 0.1-4.9 wt % of a vulcanization accelerator, based on the total weight of the reclaimed material.
8. The reclaimed material as claimed in claim 7 , wherein the vulcanization accelerator is selected from the group consisting of 2,2′-dibenzothiazyl disulfide, tetrabenzyl thiuram disulfide, zinc dialkyldithiophosphate, diisopropyl xanthogen polysulphide, isopropylxanthic disulfide, thiurams, dithiocarbamates, sulphenamides, thiazoles, guanidines, thioureas, and a combination thereof.
9. The reclaimed material as claimed in claim 6 , wherein the reclaimed material is measured by a tensile testing machine having an elongation rate of 200 mm/min according to DIN 53504; a tensile strength of the reclaimed material is greater than or equal to 14 MPa, and an elongation at break is greater than or equal to 400%.
10. The reclaimed material as claimed in claim 6 , wherein the reclaimed material has a tearing strength greater than or equal to 12 N/mm in accordance with DIN 53507-A.
11. The reclaimed material as claimed in claim 6 , wherein the reclaimed material is measured by a tensile testing machine having an elongation rate of 500 mm/min according to ASTM D412 (cutting die C); a tensile strength of the reclaimed material is greater than or equal to 100 kg/cm2; an elongation at break is greater than or equal to 550%; a tensile strength at 300% elongation is greater than or equal to 35 kg/cm 2 .
12. The reclaimed material as claimed in claim 6 , wherein the reclaimed material has a tearing strength that is greater than or equal to 35 kg/cm 2 in accordance with ASTM D624.