Optically clear resin composition, flexible optical film and image display device
A photocurable resin composition for forming an optically clear film. The photocurable resin composition includes a polyfunctional thiol monomer comprising 2 thiol functional groups, a polyfunctional (meth)acrylate monomer comprising 2 (meth)acryloyl functional groups, a photo-initiator present in a concentration of about 1 parts per hundred (phr) or less, a sterically hindered phenolic antioxidant present in a concentration of about 5 phr or less, and a phosphite antioxidant present in a concentration of about 5 phr or less.
1. A photocurable resin composition for forming an optically clear film, the photocurable resin composition comprising:
a polyfunctional thiol monomer comprising 2 thiol functional groups,
a polyfunctional (meth)acrylate monomer comprising 2 (meth)acryloyl functional groups,
a photo-initiator present in a concentration of about 1 parts per hundred (phr) or less,
a sterically hindered phenolic antioxidant present in a concentration of about 5 phr or less, wherein the sterically hindered phenolic antioxidant is present in an amount to stabilize the photocurable resin composition, and
a phosphite antioxidant present in a concentration of about 5 phr or less, wherein the phosphite antioxidant is present in an amount to provide thermal stability to articles formed by curing of the photocurable resin composition.
2. The optically clear resin composition of claim 1 , further comprising a solvent at a level between 10 phr and 600 phr.
3. The optically clear resin composition of claim 2 , wherein the solvent is a polar aprotic solvent, a polar protic solvent, a nonpolar solvent, or a combination thereof.
4. The optically clear resin composition of claim 1 , further comprising nanoscale fillers at a level less than 2 phr.
5. The optically clear resin composition of claim 2 , wherein the nanoscale fillers are reactive inorganic nanoparticles, inert inorganic nanoparticles, or a combination thereof.
6. The optically clear resin composition of claim 1 , further comprising a carbodiimide agent at a level less than 5 phr.
7. The optically clear resin composition of claim 6 , wherein the carbodiimide agent is a monomeric carbodiimide compound which contains one carbodiimide group per molecule, a polycarbodiimide compound which contains more than one carbodiimide group per molecule or a combination thereof.
8. The optically clear resin composition of claim 1 , further comprising a chain transfer agent at a level less than 10 phr.
9. The optically clear resin composition of claim 8 , wherein the chain transfer agent is an alkyl thiol, an allyl sulfide, an allyl sulfone, a halogen compound, or a combination thereof.
10. An optically clear article, formed by the actinic radiation curing of the photocurable resin composition as in claim 1 .
11. An optical film, formed by the actinic radiation curing of a photocurable resin comprising:
a polyfunctional thiol monomer comprising 2 thiol functional groups,
a polyfunctional (meth)acrylate monomer comprising 2 (meth)acryloyl functional groups,
a photo-initiator present in a concentration of about 1 parts per hundred (phr) or less,
a sterically hindered phenolic antioxidant present in a concentration of about 5 phr or less, wherein the sterically hindered phenolic antioxidant is present in an amount to stabilize the photocurable resin composition, and
a phosphite antioxidant present in a concentration of about 5 phr or less, wherein the phosphate antioxidant is present in an amount to provide thermal stability to articles formed by curing of the photocurable resin composition.
12. The optical film of claim 11 wherein the polyfunctional (meth)acrylate monomers yield a cured (meth)acrylic polymer with a Young's modulus greater than 1 GPa at 20° C.
13. The optical film of claim 11 ; wherein the polyfunctional (meth)acrylate monomers yield a cured (meth)acrylic with a dry glass transition temperature above 100° C.
14. The optical film or claim 11 ; wherein the mole ratio of total thiol groups from the polyfunctional thiol monomers to the total (meth)acrylate groups from the polyfunctional (meth)acrylate monomers is greater than 0.2.
15. The optical film of claim 11 ; wherein the mass fraction of conjugated segments on the polymer chain is less than 25%.
16. The optical film of claim 11 ; wherein the degree of the crystallinity of the optical film is less than 50%.
17. The optical film of claim 11 ; wherein the mass fraction of ordered polymer structures of the optical film is less than 50%.
18. A display device comprising:
an optical film formed by curing a photocurable resin, wherein the photocurable resin comprises:
a polyfunctional thiol monomer comprising 2 thiol functional groups,
a polyfunctional (meth)acrylate monomer comprising 2 (meth)acryloyl functional groups,
a photo-initiator present in a concentration of about 1 parts per hundred (phr) or less,
a sterically hindered phenolic antioxidant present in a concentration of about 5 phr or less, wherein the sterically hindered phenolic antioxidant is present in an amount to stabilize the photocurable resin composition, and
a phosphite antioxidant present in a concentration of about 5 phr or less, wherein the phosphate antioxidant is present in an amount to provide thermal stability to articles formed by curing of the photocurable resin composition.