IP Library › Granted Patent US 12,234,326
Granted Patent B2
US 12,234,326 · App. 17/440,262 · Granted Feb 25, 2025

Polyphenylene sulfide resin composition and molded article

Inventors: Keita Tokuzumi (Nagoya, JP); Kazuya Okubo (Nagoya, JP)
Assignee: Toray Industries, Inc.
C08G75/0259C08K3/26C08K7/14C08K2003/265C08K2201/019
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Quick Facts
Patent No.
US 12,234,326
App. No.
17/440,262
Granted
Feb 25, 2025
Kind
B2
Abstract

A polyphenylene sulfide resin composition includes a blend of the following: 100 parts by weight of a polyphenylene sulfide resin (A); 100 to 250 parts by weight of a modified cross-section glass fiber (B); and 25 to 150 parts by weight of a non-fibrous inorganic filler (C) satisfying the following (C-a) and (C-b): (C-a) having a Mohs hardness of more than 2 and less than 4, and (C-b) having a melting point or softening point of 380° C. or more; wherein the ratio X/Y of the mass X of the modified cross-section glass fiber (B) to the mass Y of the non-fibrous inorganic filler (C) is more than 1 and less than 7.

Claims (16)

1. A polyphenylene sulfide resin composition comprising a blend of:

100 parts by weight of a polyphenylene sulfide resin (A) having a minimum melt flow rate of 1000 g/10 min;

100 to 250 parts by weight of a modified cross-section glass fiber (B) having a flattening ratio of 1.3 to 10; and

25 to 150 parts by weight of a non-fibrous inorganic filler (C);

wherein the non-fibrous inorganic filler (C): has a Mohs hardness of more than 2 and less than 4, has a melting point or softening point of 380° C. or more, and is selected from the group consisting of mica, carbonates, and sulfates;

wherein a ratio X/Y of a blending weight X of said modified cross-section glass fiber (B) to a blending weight Y of said non-fibrous inorganic filler (C) is more than 1 and less than 7, such that the polyphenylene sulfide resin composition has low linear expansion, low anisotropy, and low swelling properties;

wherein the low linear expansion corresponds to: a maximum coefficient of linear expansion in the machine direction (MD) of 1.9×10 −5 /K and a maximum coefficient of linear expansion in the traverse direction (TD) of 1.8×10 −5 /K;

wherein the low anisotropy corresponds to: a maximum difference between the coefficient of linear expansion in the MD and the coefficient of linear expansion in the TD of 0.1 ×10 −5 K, and a maximum creep ratio of 1.5; and

wherein the low swelling properties correspond to: a maximum swelling ratio in the MD of 0.06% and a maximum swelling ratio in the TD of 0.07%.

2. The polyphenylene sulfide resin composition according to claim 1 , wherein the flattening ratio is 1.5 to 7.

3. The polyphenylene sulfide resin composition according to claim 1 , wherein the ratio X/Y is more than 1 and less than 5.

4. The polyphenylene sulfide resin composition according to claim 1 , wherein said non-fibrous inorganic filler (C) is calcium carbonate.

5. The polyphenylene sulfide resin composition according to claim 1 , wherein

the carbonates are selected from calcium carbonate, magnesium carbonate, dolomite, and the sulfates are selected from calcium sulfate and barium sulfate.

6. A molded article composed of said polyphenylene sulfide resin composition according to claim 1 .

7. A housing part comprising the molded article according to claim 6 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 17, 2021
From: TOKUZUMI, KEITA; OKUBO, KAZUYA
To: TORAY INDUSTRIES, INC.
Reel/Frame 057511/0518 →
Priority Claims (2)
JP 2019-059992 · Mar 27, 2019 · national
JP 2019-224205 · Dec 12, 2019 · national
Continuity (1)
Related Publication 20220010073A1 · Jan 13, 2022
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