High temperature high salt low end rheology modifiers
View Patent ↗A low-end rheology modifier for adjusting rheological characteristics of water-based drilling fluid systems, particularly for high salt, high density drilling fluids in high temperature and high-pressure applications. The low end rheology modifier comprises a copolymer and laponite clay, the copolymer comprising tert-Butylacrylamidosulfonic acid (TBAS) and n-vinylpyrrolidone (NVP) crosslinked with N,N′-Methylenebis(acrylamide).
1. A water-based drilling fluid, comprising:
a low-end rheology modifier comprising laponite clay and a copolymer, wherein the laponite clay is present in the low-end rheology modifier in amounts of 50 mass % to 67 mass %, and wherein the copolymer comprises:
a tert-Butylacrylamidosulfonic acid (TBAS) monomer;
an n-vinylpyrrolidone (NVP) monomer; and
a cross-linking monomer, wherein the cross-linking monomer is N,N′-Methylenebis(acrylamide),
wherein the low-end rheology modifier is capable of increasing viscosity of the water-based drilling fluid at temperatures of above 450 degrees Fahrenheit.
2. The water-based drilling fluid according to claim 1 , wherein the laponite clay and the copolymer are present in the low-end rheology modifier in a mass ratio of 2:1.
3. The water-based drilling fluid according to claim 1 , wherein the TBAS monomer of the copolymer is present in the low-end rheology modifier in an amount of 60 mol % to 80 mol %.
4. The water-based drilling fluid according to claim 1 , wherein the NVP monomer of the copolymer is present in the low-end rheology modifier in an amount of 20 mol % to 40 mol %.
5. The water-based drilling fluid according to claim 1 , wherein the cross-linking monomer of the copolymer is present in the low-end rheology modifier in an amount of 1000 ppm to 3000 ppm.
6. The water-based drilling fluid according to claim 1 , wherein the copolymer is present in the low-end rheology modifier in an amount of 33 mass % to and 50 mass %.
7. The water-based drilling fluid according to claim 1 , wherein the TBAS monomer of the copolymer is present in the low-end theology modifier in an amount of 65 mol % to 97 mol %.
8. The water-based drilling fluid according to claim 1 , wherein the n-vinylpyrrolidone monomer of the copolymer is present in the low-end rheology modifier in an amount of 20 mol % to 35 mol %.
9. The water-based drilling fluid according to claim 1 , wherein the crosslinking monomer of the copolymer is present in the low-end rheology modifier in an amount of 0.01% to 0.03%.
10. The water-based drilling fluid according to claim 1 , wherein the low-end rheology modifier is present in the water-based drilling fluid in a concentration of 2 lbs/bbl to 5 lbs/bbl.
11. The water-based drilling fluid according to claim 1 , wherein the low-end theology modifier is present in the water-based drilling fluid in a concentration of 5 kg/m 3 to 15 kg/m 3 .