IP Library Granted Patent US 12,252,671
Granted Patent B2
US 12,252,671 · App. 17/631,962 · Granted Mar 18, 2025

Deposition aid polymer for laundry

Inventors: Matthew E. Belowich (Midland, MI); David S. Laitar (Midland, MI); Randara Pulukkody (Landsdale, PA); Eric Wasserman (Collegeville, PA)
Assignees: Dow Global Technologies LLC; Rohm and Haas Company
C11D3/3707C11D3/3723C11D3/373C11D3/3788C11D2111/12
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Quick Facts
Patent No.
US 12,252,671
App. No.
17/631,962
Granted
Mar 18, 2025
Kind
B2
Abstract

A deposition aid polymer for laundry is provided, comprising >50 to 99 wt % of structural units of formula (I) wherein R 1 is selected from hydrogen, —C 1-4 alkyl and —CH 2 OR 3 ; wherein R 3 is selected from —C 1-12 alkyl and phenyl; and 1 to <50 wt % of structural units of formula (II) wherein R 2 is selected from a moiety of Formula (III), a moiety of Formula (IV) and a moiety of Formula (V) wherein A − is a counter anion balancing the cationic charge on the N; wherein R 4 is selected from hydrogen, —C 1-12 alkyl and phenyl; and wherein R 5 is selected from hydrogen and —C 1-8 alkyl; wherein the deposition aid polymer has a weight average molecular weight of <100,000 Daltons; and with the proviso that the deposition aid polymer has an average of at least two structural units of formula (II) per molecule.

Claims (19)

1. A deposition aid polymer for laundry, comprising:

(a) 82 to 96 wt %, based on weight of the deposition aid polymer, of structural units of formula (I)

wherein each R 1 is independently selected from the group consisting of a hydrogen and a methyl group; and

(b) 4 to 18 wt %, based on weight of the deposition aid polymer, of structural units of formula (II)

wherein each R 2 is independently selected from the group consisting of a moiety of Formula (III) and a moiety of Formula (IV)

wherein A − is a counter anion balancing the cationic charge on the N; wherein each R 4 is a methyl group;

wherein the deposition aid polymer contains no more than 0.01 wt %, based on weight of the deposition aid polymer, of azetidinium moieties, epoxide moieties, carboxylic acid moieties, carbonyl moieties and halomethyl moieties;

wherein the deposition aid polymer has a weight average molecular weight of 5,000 to 30,000 Daltons; and

with the proviso that the deposition aid polymer has an average of 2.5 to 300 structural units of formula (II) per molecule.

2. The deposition aid polymer of claim 1 ,

wherein each R 1 is a hydrogen; and

wherein each R 2 is a moiety of Formula (IV).

3. The deposition aid polymer of claim 1 , with the proviso that the deposition aid polymer has an average of 3 to 50 structural units of formula (II) per molecule.

4. The deposition aid polymer of claim 1 , with the proviso that the deposition aid polymer has an average of 3 to 20 structural units of formula (II) per molecule.

5. The deposition aid polymer of claim 1 , with the proviso that the deposition aid polymer has an average of 3.5 to 15 structural units of formula (II) per molecule.

6. The deposition aid polymer of claim 1 , wherein each R 2 is a moiety of Formula (III).

7. The deposition aid polymer of claim 6 , with the proviso that the deposition aid polymer has an average of 3 to 50 structural units of formula (II) per molecule.

8. The deposition aid polymer of claim 6 , with the proviso that the deposition aid polymer has an average of 3 to 20 structural units of formula (II) per molecule.

9. The deposition aid polymer of claim 6 , with the proviso that the deposition aid polymer has an average of 3.5 to 15 structural units of formula (II) per molecule.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2025
From: BELOWICH, MATTHEW E.; LAITAR, DAVID S.
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 070089/0053 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2025
From: WASSERMAN, ERIC
To: UNION CARBIDE CORPORATION
Reel/Frame 070095/0714 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2025
From: UNION CARBIDE CORPORATION
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 070095/0727 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2025
From: PULUKKODY, RANDARA
To: ROHM AND HAAS COMPANY
Reel/Frame 070096/0658 →
Continuity (2)
Provisional Application 62905500 · Sep 25, 2019
Related Publication 20220290076A1 · Sep 15, 2022
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