Pyrazole derivative and harmful organism-controlling agent
Embodiments provide a pest control agent that is excellent in safety, controlling effect, residual activity, and so on. According to an embodiment, there is provided a pyrazole derivative represented by general formula [II] or an agriculturally acceptable salt thereof:
1. A pyrazole derivative represented by general formula [II] or an agriculturally acceptable salt thereof
wherein,
p represents an integer of 0 or 1,
R 1 , R 2 , R 3 , R 4 , and R 5 each independently represent a hydrogen atom, halogen atom, C 1 -C 6 alkyl group, hydroxy group, C 1 -C 6 haloalkyl group, C 1 -C 6 alkoxy group, C 1 -C 6 haloalkoxy group, C 3 -C 6 cycloalkyl group, C 1 -C 6 alkylthio group, C 1 -C 6 alkylsulfinyl group, C 1 -C 6 alkylsulfonyl group, amino group, mono(C 1 -C 6 alkyl)amino group, di(C 1 -C 6 alkyl)amino group, cyano group, or nitro group,
R 16 represents a hydrogen atom or C 1 -C 6 alkyl group,
Q′ represents a halogen atom, C 1 -C 6 alkylsulfonyloxy group, C 1 -C 6 haloalkylsulfonyloxy group, di(C 1 -C 6 alkyl)sulfamoyloxy group, phenylsulfonyloxy group that is unsubstituted or substituted with (R 9 ) n , C 6 -C 10 aryl group that is unsubstituted or substituted with (R 8 ) m , or heteroaryl group that is unsubstituted or substituted with (R 8 ) m ,
R 8 represents a hydrogen atom, halogen atom, hydroxy group, thiol group, C 1 -C 6 alkyl group, C 1 -C 6 haloalkyl group, C 3 -C 6 cycloalkyl group, C 3 -C 6 cycloalkyl C 1 -C 6 alkyl group, C 3 -C 6 cycloalkyl C 2 -C 6 alkynyl group, C 3 -C 6 halocycloalkyl group, C 3 -C 6 halocycloalkyl C 1 -C 6 alkyl group, C 2 -C 6 alkenyl group, C 2 -C 6 haloalkenyl group, C 2 -C 7 alkynyl group, C 2 -C 6 haloalkynyl group, C 1 -C 6 alkoxy group, C 1 -C 6 haloalkoxy group, C 3 -C 6 cycloalkoxy group, oxirane-2-yl group, mono(oxirane-2-yl)C 1 -C 3 alkyl group, C 3 -C 6 halocycloalkoxy group, C 1 -C 6 alkylthio group, C 1 -C 6 alkylsulfinyl group, C 1 -C 6 alkylsulfonyl group, C 3 -C 6 cycloalkylthio group, C 3 -C 6 cycloalkylsulfinyl group, C 3 -C 6 cycloalkylsulfonyl group, C 1 -C 6 haloalkylthio group, C 1 -C 6 haloalkylsulfinyl group, C 1 -C 6 haloalkylsulfonyl group, formyl group, C 1 -C 6 alkylcarbonyl group, C 1 -C 6 haloalkylcarbonyl group, C 1 -C 6 alkoxycarbonyl group, aminocarbonyl group, mono(C 1 -C 6 alkyl)aminocarbonyl group, di(C 1 -C 6 alkyl)aminocarbonyl group, amino C 1 -C 6 alkyl group, mono(C 1 -C 6 alkyl)amino C 1 -C 6 alkyl group, di(C 1 -C 6 alkyl)amino C 1 -C 6 alkyl group, tri(C 1 -C 6 alkyl)silyloxy C 1 -C 6 alkyl group, C 1 -C 6 alkylcarbonyl C 1 -C 6 alkyl group, C 1 -C 6 alkylcarbonyloxy C 1 -C 6 alkyl group, C 1 -C 6 haloalkylcarbonyl C 1 -C 6 alkyl group, C 1 -C 6 alkoxycarbonyl C 1 -C 6 alkyl group, hydroxy C 1 -C 6 alkyl group, C 1 -C 6 alkoxy C 1 -C 6 alkyl group, C 1 -C 6 haloalkoxy C 1 -C 6 alkyl group, C 1 -C 6 alkoxy C 1 -C 6 haloalkyl group, C 1 -C 6 haloalkoxy C 1 -C 6 haloalkyl group, formyloxy group, C 1 -C 6 alkylcarbonyloxy group, C 1 -C 6 haloalkylcarbonyloxy group, aminocarbonyloxy group, mono(C 1 -C 6 alkyl)aminocarbonyloxy group, di(C 1 -C 6 alkyl)aminocarbonyloxy group, aminocarbonyloxy C 1 -C 6 alkyl group, mono(C 1 -C 6 alkyl)aminocarbonyloxy C 1 -C 6 alkyl group, di(C 1 -C 6 alkyl)aminocarbonyloxy C 1 -C 6 alkyl group, C 1 -C 6 alkoxycarbonyloxy group, C 1 -C 6 alkoxycarbonyloxy C 1 -C 6 alkyl group, C 1 -C 6 alkylsulfonyloxy group, C 1 -C 6 haloalkylsulfonyloxy group, C 1 -C 6 alkylthio C 1 -C 6 alkyl group, C 1 -C 6 alkylsulfinyl C 1 -C 6 alkyl group, C 1 -C 6 alkylsulfonyl C 1 -C 6 alkyl group, C 1 -C 6 haloalkylthio C 1 -C 6 alkyl group, C 1 -C 6 haloalkylsulfinyl C 1 -C 6 alkyl group, C 1 -C 6 haloalkylsulfonyl C 1 -C 6 alkyl group, C 3 -C 6 cycloalkyl C 1 -C 6 alkoxy group, C 3 -C 6 halocycloalkyl C 1 -C 6 alkoxy group, C 3 -C 6 cycloalkyl C 1 -C 6 alkylthio group, C 3 -C 6 cycloalkyl C 1 -C 6 alkylsulfinyl group, C 3 -C 6 cycloalkyl C 1 -C 6 alkylsulfonyl group, C 3 -C 6 halocycloalkyl C 1 -C 6 alkylthio group, C 3 -C 6 halocycloalkyl C 1 -C 6 alkylsulfinyl group, C 3 -C 6 halocycloalkyl C 1 -C 6 alkylsulfonyl group, phenyl group that is unsubstituted or substituted with (R 9 ) n , phenoxy group that is unsubstituted or substituted with (R 9 ) n , benzyl group that is unsubstituted or substituted with (R 9 ) n , benzyloxy group that is unsubstituted or substituted with (R 9 ) n , amino group, mono(C 1 -C 6 alkyl)amino group, di(C 1 -C 6 alkyl)amino group, carboxy group, 1,3-dioxolane-2-yl group, 1,3-dioxane-2-yl group, 1H-imidazole-2-yl group, thiazole-2-yl group, oxazole-2-yl group, (hydroxyimino)methyl group, (methyloxyimino)methyl group, isoxazole-3-yl, 4,5-dihydro-3-isoxazolyl group, cyano group, or nitro group, and further, neighboring two R 8 s may form, together with a carbon atom bound to each R 8 , a 4 to 8-membered carbon ring, or a 4 to 8-membered hetero ring having 1 to 4 hetero atoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, the carbon ring or hetero ring formed at this time may be substituted with one or more chemically acceptable substituents selected from a halogen atom, cyano group, nitro group, C 1 -C 6 alkyl group, C 1 -C 6 haloalkyl group, C 1 -C 6 alkoxy group, C 1 -C 6 haloalkoxy group, or oxo group,
R 9 represents a halogen atom, C 1 -C 6 alkyl group, C 1 -C 6 haloalkyl group, C 1 -C 6 alkoxy group, C 1 -C 6 haloalkoxy group, C 1 -C 6 alkylthio group, C 1 -C 6 alkylsulfinyl group, C 1 -C 6 alkylsulfonyl group, C 1 -C 6 haloalkylthio group, C 1 -C 6 haloalkylsulfinyl group, C 1 -C 6 haloalkylsulfonyl group, amino group, mono(C 1 -C 6 alkyl)amino group, di(C 1 -C 6 alkyl)amino group, cyano group, or nitro group,
m represents a number of chemically acceptable R 8 s and is an integer of 0 to 7,
R 8 s may be the same or different from each other when m is 2 or more,
n represents a number of chemically acceptable R 9 s and is an integer of 0 to 5, and R 9 s may be the same or different from each other when n is 2 or more.