Ultra-low temperature phase change gel
View Patent ↗Some embodiments of the disclosure provide an ultra-low temperature phase change gel including a phase change matrix, a temperature regulator and a nucleating agent. In some embodiments, the phase change matrix is used as a host material for phase change to store and release cooling capacity, the temperature regulator is used for regulating the phase change temperature of the phase change matrix, and the nucleating agent is used for reducing a supercooling degree of the phase change matrix. The phase change matrix includes a temperature control material and water. The temperature control material includes sodium silicate, dipotassium hydrogen phosphate and aluminum sulfate, and the temperature regulator comprises polyethylene glycol. The nucleating agent includes a composite material formed by free radical polymerization of a reaction monomer and a macroinitiator. The composite material includes polyacrylic acid grafted with silica hybrid nano particles.
1. An ultra-low temperature phase change gel comprising a phase change matrix, a temperature regulator, and a nucleating agent, wherein:
the phase change matrix is a host material for phase change to store and to release cooling capacity;
the temperature regulator regulates a phase change temperature of the phase change matrix;
the nucleating agent reduces a supercooling degree of the phase change matrix;
the phase change matrix comprises a temperature control material and water;
the temperature control material comprises sodium silicate, dipotassium hydrogen phosphate, and aluminum sulfate;
the temperature regulator comprises polyethylene glycol;
the nucleating agent comprises a composite material formed by free radical polymerization of a reaction monomer and a macroinitiator;
the composite material comprises polyacrylic acid grafted with silica hybrid nano particles; and
in the ultra-low temperature phase change gel,
a mass percentage of the phase change matrix is 95% to 97%,
a mass percentage of the temperature regulator is 2% to 4%, and
a mass percentage of the nucleating agent is 1% to 2%.
2. The ultra-low temperature phase change gel of claim 1 , wherein:
the polyethylene glycol has hydroxyl groups on both ends; and
in the ultra-low temperature phase change gel, hydrogen bonds are formed between the hydroxyl groups and the phase change matrix to adjust thermal performance parameters of the phase change matrix.
3. The ultra-low temperature phase change gel of claim 1 , wherein the nucleating agent reduces the supercooling degree of the phase change matrix by inducing crystallization behavior of the phase change matrix.
4. The ultra-low temperature phase change gel of claim 1 , wherein a particle size of the nucleating agent is 100 nm to 900 nm.
5. The ultra-low temperature phase change gel of claim 1 , wherein a molar ratio of the silica to the polyacrylic acid is 1:1 to 1:4 in the polyacrylic acid grafted with silica hybrid nano particles.
6. The ultra-low temperature phase change gel of claim 1 , wherein a preparation method of the nucleating agent comprises the steps of:
preparing the reaction monomer and the macroinitiator as prepared raw materials;
adding the prepared raw materials into an organic solvent to obtain a mixed solution;
adding a guide agent into the mixed solution to carry out reversible addition fragmentation chain transfer reaction to obtain a suspension; and
dropping the suspension into a precipitant for precipitation to obtain the nucleating agent;
wherein:
the reactive monomer comprises acrylic acid; and
the macroinitiator comprises silica-dithioester.
7. The ultra-low temperature phase change gel of claim 6 , wherein, in the prepared raw material of the nucleating agent,
a mass percentage of the reaction monomer is 87% to 93%,
a mass percentage of the macroinitiator is 6% to 12%, and
a mass percentage of the guide agent is 1%.
8. The ultra-low temperature phase change gel of claim 1 , wherein:
the temperature control material is a mixture of sodium silicate, dipotassium hydrogen phosphate, and aluminum sulfate; and
in the phase change matrix,
a mass percentage of the sodium silicate is 6.25% to 14.7%,
a mass percentage of the dipotassium hydrogen phosphate is 4.1% to 7.4%, and
a mass percentage of the aluminum sulfate is 6.25% to 10.5%.
9. The ultra-low temperature phase change gel of claim 1 , wherein a mass percentage of the temperature control material is 16.7% to 31.5% in the phase change matrix.
10. The ultra-low temperature phase change gel of claim 1 , wherein a mass percentage of water is 68.5% to 83.3% in the phase change matrix.