Doped phase change material and method of preparation thereof
A method includes mixing a dopant salt of at least one of cobalt, nickel, zinc, and scandium with a silicate, in a solvent, to form a first solution. The method includes mixing the first solution with a solvent mixture to form a second solution. The method further includes mixing the second solution with an acid to form an acid solution. The method further includes adding a catalyst and a polymer to the acid solution to form the doped PCM. The doped PCM includes the catalyst, the polymer, at least one of cobalt, nickel, zinc, and scandium, and SiO 2 .
1. A method to form a doped phase change material (PCM), comprising:
mixing a dopant salt of at least one of a zinc nitrate and a scandium nitrate with tetraethyl orthosilicate (TEOS), in an organic solvent solution, to form a first solution;
hydrolyzing and condensing the first solution, then adding an excess of water to form a second solution;
mixing the second solution with nitric acid to form an acid solution;
adding a metal catalyst and a polymer to the acid solution to form the doped PCM,
wherein the doped PCM comprises the metal catalyst, the polymer, at least one of zinc and scandium, and SiO 2 ,
wherein the polymer is polyethylene glycol (PEG).
2. The method of claim 1 , wherein the doped PCM has a phase change enthalpy of from 100 joules per gram (J/g) to 200 J/g.
3. The method of claim 1 , wherein the doped PCM has a latent heat of from 150 J/g to 170 J/g.
4. The method of claim 1 , wherein the doped PCM has a thermal conductivity of from 0.5 watts per meter per Kelvin (W/m −1 K −1 ) to 0.7 (W/m −1 K −1 ).
5. The method of claim 1 , wherein the acid solution has a pH of 1.2.
6. The method of claim 1 , wherein the acid is added over 30 minutes and the acid solution is mixed at a rate of 100 rotations per minute (rpm).
7. The method of claim 1 , wherein the polymer is a polyethylene glycol (PEG) having an average molecular weight of 6000.
8. The method of claim 1 , wherein the doped PCM has an energy storage efficiency of 79.93%.
9. The method of claim 1 , wherein the doped PCM has a thermal conductivity of 0.6532 W/m −1 K −1 .
10. The method of claim 1 , wherein the doped PCM consists of the metal catalyst, the polymer, at least one of a zinc nitrate and a scandium nitrate, and SiO 2 .
11. The method of claim 1 , wherein the doped PCM consists of the metal catalyst, the polymer, a zinc nitrate, and SiO 2 .
12. The method of claim 1 , wherein the doped PCM consists of the metal catalyst, the polymer, a scandium nitrate, and SiO 2 .
13. The method of claim 1 , wherein the doped PCM consists of the metal catalyst, the polymer, a zinc nitrate, a scandium nitrate, and SiO 2 .