IP Library Granted Patent US 12,281,380
Granted Patent B2
US 12,281,380 · App. 18/035,779 · Granted Apr 22, 2025

CRN coating film and sliding member

Inventors: Syun Sugawara (Tokyo, JP); Takatsugu Iwashita (Tokyo, JP)
Assignee: TPR Co., Ltd.
C23C14/0641C23C14/32F16J9/26
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,281,380
App. No.
18/035,779
Granted
Apr 22, 2025
Kind
B2
Abstract

The present invention addresses the problem of providing a CrN coating film which has excellent peeling resistance such that peeling thereof starting at a crack is unlikely to occur even in a more severe lubrication environment. The problem is solved by a CrN coating film which has a preferred orientation of 200 as determined by XRD, and in which the X-ray diffraction intensity ratio of the (200) plane with respect to the (111) plane, (200)/(111), is 5.5 or higher, and the ratio of crystal grains of 1 μm or smaller is 85% or higher in a crystal grain size distribution measured by an EBSD analysis.

Claims (9)

1. A CrN coating film, having a preferred orientation of 200 as determined by XRD,

wherein

an X-ray diffraction intensity ratio of a (200) plane with respect to a (111) plane, (200)/(111), is 5.5 or higher, and

a ratio of crystal grains of 1 μm or smaller is 85% or higher in a crystal grain size distribution measured by an EBSD analysis.

2. The CrN coating film according to claim 1 , having a micro-Vickers hardness of 800 HV to 1,300 HV.

3. The CrN coating film according to claim 1 , having a plastic work rate of 61% to 69% as measured using a Vickers indenter in accordance with ISO14577-1.

4. A sliding member, comprising a sliding surface coated with the CrN coating film according to claim 1 .

5. A sliding member, comprising a sliding surface coated with the CrN coating film according to claim 2 .

6. A sliding member, comprising a sliding surface coated with the CrN coating film according to claim 3 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 25, 2023
From: SUGAWARA, SYUN; IWASHITA, TAKATSUGU
To: TPR CO., LTD.
Reel/Frame 063766/0794 →
Priority Claims (1)
JP 2020-213722 · Dec 23, 2020 · national
Continuity (1)
Related Publication 20230416903A1 · Dec 28, 2023
References Cited (22)
US 4486285A · Aubert et al. · 1984 [cited by applicant]
US 10006546B2 · Sato et al. · 2018 [cited by applicant]
US 20150093586A1 · Kawai et al. · 2015 [cited by applicant]
US 20160238132A1 · Sato · 2016 [cited by examiner]
JP S58144473A · 1983 [cited by applicant]
JP H0727228A · 1995 [cited by applicant]
JP H11335813A · 1999 [cited by applicant]
JP 2001335878A · 2001 [cited by applicant]
JP 2010168603A · 2010 [cited by applicant]
JP 2011194536A · 2011 [cited by applicant]
JP 2011218513A · 2011 [cited by applicant]
JP 201966024A · 2019 [cited by applicant]
WO WO2013136510A1 · 2013 [cited by applicant]
WO WO2015046437A1 · 2015 [cited by applicant]
Lugscheider, E., et al. “Investigation of Mechanical Properties of CrN-PVD Thin Films by Nanoindentation.” MRS Online Proceedings Library 522 (1998): 227-232. [cited by examiner]
Third Party Observation in JP Application No. 2020-213722 dated Jun. 5, 2024, 29 pages. [cited by applicant]
Search Report in International Application No. PCT/JP2021/029273 dated Sep. 21, 2021. [cited by applicant]
Schiavi et al., “Indentation Modulus, Indentation Work and Creep of Metals and Alloys at the Macro-Scale Level: Experimental Insights Into the Use of a Primary Vickers Hardness Standard Machine”, Materials, vol. 14, 291… [cited by applicant]
Herrmann et al., “CIRP Sponsored International Comparision on Nanoindentation”, Metrologia, vol. 47, 2010, pp. S50-S58. [cited by applicant]
Extended European Search Report in EP Application No. 21909791.2 dated Mar. 28, 2024, 8 pages. [cited by applicant]
Binns et al., “Preferred Orientation and its Effects on Intensity-Correlation Measurements”, IUCrJ, vol. 9, 2022, pp. 231-242. [cited by applicant]
Office Action in IN Application No. 202317030858 dated Mar. 5, 2025, 7 pages. [cited by applicant]