Thin glass sheet and system and method for forming the same
A method includes heating a glass preform having a plurality of glass layers and drawing the glass preform in a distal direction to form a drawn glass sheet extending distally from the glass preform and having the plurality of glass layers. The drawn glass sheet is thinner than the glass preform. The drawn glass sheet can be rolled onto a collection spool. At least a portion of a glass layer can be removed from the drawn glass sheet. An exemplary glass sheet includes a first glass layer, a second glass layer adjacent to the first glass layer, and a thickness of at most about 0.1 mm. An exemplary ion exchanged glass sheet includes a thickness of at most about 0.1 mm and a surface layer that is under a compressive stress and extends into an interior of the glass sheet to a depth of layer.
1. A laminate glass sheet, comprising:
a first glass layer having a first composition; and
a second glass layer fused to the first glass layer, the second glass layer having a second composition that is different than the first composition, wherein:
the second composition comprises:
from about 7 mol. %. to about 23 mol. % of B 2 O 3 , and
from about 3 mol. % to about 21 mol. % of Na 2 O;
a thickness of the glass sheet is at most about 100 μm, and
the glass sheet is configured to be bent to a bend radius of less than or equal to about 50 mm.
2. The laminate glass sheet of claim 1 , wherein the first glass layer comprises a core layer, the second glass layer comprises a first cladding layer and a second cladding layer, and the core layer is disposed between the first cladding layer and the second cladding layer.
3. The laminate glass sheet of claim 2 , wherein a sheet thickness ratio of each of the first and second glass layers comprises a ratio of a thickness of the respective glass layer to the thickness of the glass sheet, and wherein the sheet thickness ratio of the first glass layer is greater than the sheet thickness ratio of the second glass layer.
4. The laminate glass sheet of claim 3 , wherein the sheet thickness ratio of the first glass layer is at most 0.5.
5. The laminate glass sheet of claim 3 , wherein the sheet thickness ratio of the first glass layer is at least 0.7.
6. The laminate glass sheet of claim 5 , wherein a thickness of the first glass layer is less than about 50 μm.
7. The laminate glass sheet of claim 2 , wherein a degradation rate of the first glass layer in a reagent is greater than a degradation rate of the second glass layer in the reagent such that contacting the glass sheet with the reagent removes at least a portion of the core glass layer.
8. The laminate glass sheet of claim 2 , wherein a degradation rate of the second glass layer in a reagent is greater than a degradation rate of the first glass layer in the reagent such that contacting the glass sheet with the reagent removes at least a portion of at least one of the first and second cladding layers.
9. The laminate glass sheet of claim 2 , further comprising a portion along which the core layer is bounded on one side by only one of the first and second cladding layers.
10. The laminate glass sheet of claim 9 , wherein the core layer on an opposite side along the portion includes an exposed surface that is pristine and substantially free of defects.
11. The laminate glass sheet of claim 10 , further comprising an electronic device arranged on the exposed surface.
12. The laminate glass sheet of claim 11 , wherein the electronic device comprises a thin film transistor (TFT).
13. The laminate glass sheet of claim 2 , further comprising a portion along which the core layer is not disposed between the first and second cladding layers.
14. The laminate glass sheet of claim 13 , wherein at least one of the first and second cladding layers along the portion includes an exposed surface that is pristine and substantially free of defects.
15. The laminate glass sheet of claim 2 , wherein each of the first cladding layer and the second cladding layer comprises an average coefficient of thermal expansion (CTE) that is less than an average CTE of the core layer.
16. The laminate glass sheet of claim 1 , further comprising an electronic device formed on a surface of the glass sheet.
17. The laminate glass sheet of claim 1 , further comprising unpolished outer surfaces.
18. The laminate glass sheet of claim 1 , wherein the second composition comprises from about 9 mol. %. to about 23 mol. % of B 2 O 3 .
19. A laminate glass sheet, comprising:
a first glass layer having a first composition; and
a second glass layer fused to the first glass layer, the second glass layer having a second composition that is different than the first composition,
wherein:
a thickness of the glass sheet is at most about 100 μm,
the glass sheet is configured to be bent to a bend radius of less than or equal to about 50 mm, and
the glass sheet is a fusion drawn glass sheet that has at least one major outer surface that is unpolished and pristine.