Toner and method for producing the same
To provide a toner having both low temperature fixability and hot offset resistance and having excellent scratch resistance of a fixed image. A toner including a toner particle containing a binder resin, a crystalline polyester, and a calcium carbonate particle, in which the crystalline polyester includes a unit derived from an aliphatic diol and a unit derived from an aliphatic dicarboxylic acid, an ester group concentration Ec of the crystalline polyester is 27% by mass or more to 50% by mass or less, a content Ma of the calcium carbonate particle included in the toner particle is 3% by mass or more to 40% by mass or less, and a ratio (Ma/Mc) of the content Ma of the calcium carbonate particle included in the toner particle to a content Mc (% by mass) of the crystalline polyester included in the toner particle is 0.2 or more to 20 or less.
1. A toner, comprising:
a toner particle containing a binder resin, a crystalline polyester, and a calcium carbonate particle;
the crystalline polyester including a unit derived from an aliphatic diol and a unit derived from an aliphatic dicarboxylic acid, wherein
an ester group concentration Ec of the crystalline polyester is 27 to 50% by mass, and
Ma is 3 to 40% by mass, and Ma/Mc is 5 to 10 when Ma (% by mass) is a content of the calcium carbonate particle included in the toner particle, and Mc (% by mass) is a content of the crystalline polyester included in the toner particle.
2. The toner according to claim 1 , wherein in a cross section of the toner particle, an average value of aspect ratios (major axis/minor axis) of the calcium carbonate particles observed with a transmission electron microscope is 1.5 to 6.0.
3. The toner according to claim 1 , wherein a number average particle diameter of the calcium carbonate particle is 100 to 600 nm.
4. The toner according to claim 1 , wherein an acid value of the crystalline polyester is 0 to 10 mgKOH/g.
5. The toner according to claim 1 , wherein the content Mc is 0.1 to 5.0% by mass.
6. The toner according to claim 1 , wherein an abundance A of calcium atoms measured by X-ray photoelectron spectroscopy using the toner as a sample is 0 to 0.5 atomic %.
7. The toner according to claim 1 , wherein the ester group concentration Ec is 27 to 40% by mass.
8. The toner according to claim 1 , wherein a ratio (Ea/Ec) of an ester group concentration Ea of the binder resin to the ester group concentration Ec is 0.5 to 0.7.
9. The toner according to claim 1 , wherein the toner particle includes a graft polymer a having a polyolefin as a trunk and a styrene acrylic resin as a branch.
10. The toner according to claim 9 , wherein a ratio (Mo/Mc) of a content Mo (% by mass) of the graft polymer a included in the toner particle to the content Mc is 0.3 to 25, and a ratio (Mo/Ma) of the content Mo to the content Ma is 0.08 to 6 or less.
11. The toner according to claim 1 , wherein the toner particle is a pulverized toner particle.
12. A method for producing a toner, comprising:
selecting a toner particle containing a binder resin, a crystalline polyester, and a calcium carbonate particle, the crystalline polyester including a unit derived from an aliphatic diol and a unit derived from an aliphatic dicarboxylic acid, wherein
an ester group concentration Ec of the crystalline polyester is 27 to 50% by mass, and
Ma is 3 to 40% by mass, and Ma/Mc is 5 to 10 when Ma (% by mass) is a content of the calcium carbonate particle included in the toner particle, and Mc (% by mass) is a content of the crystalline polyester included in the toner particle; and
treating a toner particle surface with hot air.
13. The method for producing a toner according to claim 12 , wherein a temperature of the hot air is 100 to 450° C.
14. The toner according to claim 1 , wherein a content of the binder resin included in the toner particle is 40 to 90% by mass.