Double-layer three-way catalyst with further improved ageing stability
The present invention relates to a catalyst comprising two layers on an inert catalyst carrier, a layer A containing at least palladium as a platinum group metal, in addition to a cerium/zirconium/lanthanum/yttrium mixed oxide, and a layer B, which is applied to layer A, containing at least rhodium as the platinum group metal, in addition to a cerium/zirconium/lanthanum/yttrium mixed oxide.
1. Catalyst comprising two layers arranged on top of each other on an inert catalyst support, wherein
a layer A contains at least palladium as a platinum group metal and a cerium/zirconium/lanthanum/yttrium mixed oxide, and
a layer B applied to layer A contains at least rhodium as a platinum group metal, and a cerium/zirconium/lanthanum/yttrium mixed oxide,
wherein, in both layers A and B, the lanthanum oxide content is between 1% by weight and 5% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide, and the yttrium oxide content is between 10% by weight and 20% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide.
2. Catalyst according to claim 1 , wherein layer A and/or layer B, independently of one another, additionally contain platinum as a further platinum group metal.
3. Catalyst according to claim 1 , wherein layer A contains only palladium and layer B only rhodium or layer B only palladium and rhodium as platinum group metal.
4. Catalyst according to claim 1 , wherein that layer A and layer B contain active aluminum oxide.
5. Catalyst according to claim 4 , wherein the platinum group metal in layer A and/or in layer B is supported wholly or in part on active aluminum oxide.
6. Catalyst according to claim 1 , wherein the weight ratio of cerium oxide to zirconium oxide in the cerium/zirconium/lanthanum/yttrium mixed oxide in layer A and layer B is 0.1 to 1.0.
7. Catalyst according to claim 1 , wherein layer A lies directly on the inert catalyst support.
8. Catalyst according to claim 1 , wherein in both layers A and B, the lanthanum oxide content is between 1% by weight and 3.5% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide, and the yttrium oxide content is between 12% by weight and 20% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide.
9. Catalyst according to claim 1 , wherein in both layers A and B, the yttrium oxide content is between 12% by weight and 20% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide.
10. Catalyst according to claim 9 , wherein in both layers A and B, the yttrium oxide content is between 12% by weight and 15% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide.
11. Catalyst according to claim 10 , wherein in both layers A and B, the yttrium oxide content is between 12% by weight and 13% by weight, based on the cerium/zirconium/lanthanum/yttrium mixed oxide.