Method for producing a carbonate bonded, compacted article
The method for producing a carbonate bonded, compacted article, which method comprises the steps of providing a particulate, carbonatable material; compacting the particulate material to form a compact; and carbonating said compact. The carbonation of the compact is started and subsequently continued for at least 1 hour with a low partial carbon dioxide pressure in the carbonation gas which is lower than 0.5 bars, after which carbonation of the compact is continued for at least 8 hours with a high partial carbon dioxide pressure in the carbonation gas which is higher than 0.5 bars. By carbonating in two phases with a low and a high partial carbon dioxide pressure, a higher compressive strength of the carbonated compacts can be achieved within a predetermined carbonation time, in particular within a carbonation time of about 24 hours so that every day new compacts can be carbonated.
1. A method for producing a carbonate bonded, compacted article, which method comprises the steps of:
providing a particulate carbonatable material;
compacting the particulate material to form a compact; and
carbonating said compact for a predetermined period of time with a gas which contains carbon dioxide to produce carbonates thus transforming the compact into said carbonate bonded, compacted article,
wherein
carbonation of said compact is started and subsequently continued for at least 1 hour with a low partial carbon dioxide pressure in said gas, after which carbonation of said compact is continued for at least 8 hours with a high partial carbon dioxide pressure in said gas, said low partial carbon dioxide pressure being lower than 0.5 bars and said high partial carbon dioxide pressure being equal to or higher than 0.5 bars.
2. A method according to claim 1 , wherein subsequently to having started the carbonation of said compact, the carbonation thereof is continued for at least 1.5 hours with said low partial carbon dioxide pressure in said gas.
3. A method according to claim 1 , wherein subsequently to having started the carbonation of said compact, the carbonation of said compact is continued for less than 16 hours, with said low partial carbon dioxide pressure in said gas.
4. A method according to claim 1 , wherein carbonation of said compact is continued for at least 12 hours, with said high partial carbon dioxide pressure in said gas.
5. A method according to claim 1 , wherein said gas having said low partial carbon dioxide pressure is at a pressure which is lower than 5 bars, said pressure being equal to or higher than the atmospheric pressure.
6. A method according to claim 1 , wherein said gas having said high partial carbon dioxide pressure is at a pressure which is lower than 5 bars, said pressure being equal to or higher than the atmospheric pressure.
7. A method according to claim 1 , wherein said low partial carbon dioxide pressure is lower than 0.45 bars.
8. A method according to claim 1 , wherein said low partial carbon dioxide pressure is higher than 0.05 bars.
9. A method according to claim 1 , wherein said high partial carbon dioxide pressure is higher than 0.6 bars.
10. A method according to claim 1 , wherein said predetermined period of time comprises less than 32 hours.
11. A method according to claim 1 , wherein said predetermined period of time comprises more than 16 hours.
12. A method according to claim 1 , wherein carbonation of said compact is started with said gas having a temperature lower than 50° C.
13. A method according to claim 1 , wherein carbonation of said compact is started with said gas having a temperature higher than 20° C.
14. A method according to claim 1 , wherein during the carbonation of said compact the temperature of said gas is increased to a temperature higher than 50° C.
15. A method according to claim 1 , wherein said particulate material comprises carbonatable slag from a metal production process, slag from the production of phosphorus, bottom ash and/or fly ash, the particulate material comprises steel slag.