Radiation cooling device using ceramic nanoparticle mixture
The present invention relates to a technical idea of cooling the surface of a material or the internal temperature under the material by emitting heat under an element to the outside while minimizing absorption of light in the solar spectrum, and more particularly to a technology for developing a material having a high transmittance or high reflectance with respect to incident sunlight and a high absorptivity selectively in a wavelength range of 8 μm to 13 μm corresponding to the sky window section of the atmosphere.
1. A radiative cooling device manufactured using a ceramic nanoparticle mixture, comprising:
a solar reflective layer formed of a metal material to reflect sunlight; and
an infrared radiation layer formed by mixing a plurality of ceramic nanoparticles based on any one of a size, thickness, and weight fraction determined in consideration of an absorptivity in a wavelength range corresponding to a sky window of atmosphere and configured to absorb and emit infrared rays in the wavelength range,
wherein the infrared radiation layer is formed by mixing at least two ceramic nanoparticle types of first ceramic nanoparticles having a first intrinsic emissivity in a first wavelength range, second ceramic nanoparticles having a second intrinsic emissivity in a second wavelength range, and third ceramic nanoparticles having a third intrinsic emissivity in a third wavelength range.
2. The radiative cooling device according to claim 1 , wherein the first wavelength range comprises 8 μm to 10 μm in the wavelength range,
the second wavelength range comprises 10 μm to 12.5 μm in the wavelength range, and
the third wavelength range comprises 11 μm to 13 μm in the wavelength range.
3. The radiative cooling device according to claim 1 , wherein the first ceramic nanoparticles comprise any one ceramic nanoparticle type of SiO 2 , cBN, and CaSO 4 ceramic nanoparticles,
the second ceramic nanoparticles comprise Si 3 N 4 ceramic nanoparticles, and
the third ceramic nanoparticles comprise Al 2 O 3 ceramic nanoparticles.
4. The radiative cooling device according to claim 1 , wherein the first intrinsic emissivity comprises an emissivity higher than an emissivity of the second ceramic nanoparticles and third ceramic nanoparticles in the first wavelength range,
the second intrinsic emissivity comprises an emissivity higher than an emissivity of the first ceramic nanoparticles and third ceramic nanoparticles in the second wavelength range, and
the third intrinsic emissivity comprises an emissivity higher than an emissivity of the first ceramic nanoparticles and second ceramic nanoparticles in the third wavelength range.
5. The radiative cooling device according to claim 1 , wherein in the infrared radiation layer, a particle size and composition related to a size and thickness of the plural ceramic nanoparticles are determined such that an absorptivity of the infrared rays is increased in the wavelength range.
6. The radiative cooling device according to claim 1 , wherein the plural ceramic nanoparticles comprise at least two ceramic nanoparticle types of SiO 2 , Al 2 O 3 , Si 3 N 4 , CBN, CaSO 4 , TiO 2 , ALON, BaTiO 3 , BeO, Cu 2 O, MgAl 2 O 4 , SrTiO 3 , Y 2 O 3 , Bi 12 SiO 20 , CaCO 3 , LiTaO 3 , KNbO 3 , NaNo 3 , ZrSiO 4 , and CaMg(Co 3 ) 2 .
7. The radiative cooling device according to claim 1 , wherein in the infrared radiation layer, each of the plural ceramic nanoparticles is comprised in any one structure of a single particle structure and a multiple core shell structure.
8. The radiative cooling device according to claim 1 , wherein the infrared radiation layer is formed by single coating a mixed solution, in which the plural ceramic nanoparticles are mixed, on the solar reflective layer by any one method of spin coating, drop coating, bar coating, spray coating, doctor blading, and blade coating.
9. The radiative cooling device according to claim 8 , wherein any one polymer of polydimethyl siloxane (PDMS), polyurethane acrylate (PUA), polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF), and dipentaerythritol hexaacrylate (DPHA) is added to the infrared radiation layer formed by coating with the mixed solution.
10. The radiative cooling device according to claim 1 , wherein the infrared radiation layer is formed by mixing the first ceramic nanoparticles, the second ceramic nanoparticles, and the third ceramic nanoparticles in any one weight fraction of 1:1:1, 1:4:1, and 3:6:7.
11. The radiative cooling device according to claim 1 , wherein the solar reflective layer is formed of at least one metal material selected from silver (Ag), aluminum (Al), gold (Au), copper (Cu), titanium (Ti), chromium (Cr), manganese (Mn), iron (Fe), and platinum (Pt) or any one material of alloy materials in which at least two of the metal materials are combined.