Phosphorous extraction and recovery system
Separation methods and systems for converting high concentrations of animal wastes and other nutrient-rich organic materials into nutrients and other useful products such as struvite and potassium struvite. Advantageously, the system and methods do not require the addition of external chemicals other than an acid and a base.
1. A phosphorus extraction and recovery system (PEARS) system comprising:
(a) a reaction vessel comprising a mixer and a gas diffuser positioned within the reaction vessel, wherein the reaction vessel and the mixer are substantially inert to both an acidic solution and a basic solution;
(b) at least one solid-liquid separation module in fluid communication with the reaction vessel, wherein the at least one solid-liquid separation module separates contents of the reaction vessel into a substantially solid fraction and a substantially liquid fraction;
(c) at least one container in communication with at least one solid-liquid separation module, wherein the substantially solid fraction from the at least one solid-liquid separation module is collected in the at least one container; and
(d) a liquid conduit connecting the reaction vessel to at least one solid-liquid separation module for directing the substantially liquid fraction from at least one solid-liquid separation module to the reaction vessel,
wherein the reaction vessel is devoid of any solid-liquid separator comprising a membrane.
2. A phosphorus extraction and recovery system (PEARS) system comprising:
(a) an extraction reaction vessel comprising a first mixer and a gas diffuser positioned within the extraction reaction vessel, wherein each of the components of the extraction reaction vessel are substantially inert to an acidic solution;
(b) at least one first solid-liquid separation module in fluid communication with, and downstream of, the extraction reaction vessel, wherein the at least one first solid-liquid separation module separates contents of the extraction reaction vessel into a first substantially solid fraction and a first substantially liquid fraction;
(c) a precipitation reaction vessel positioned to receive the substantially liquid fraction from the at least one first solid-liquid separation module, wherein the precipitation reaction vessel comprises a second mixer, wherein each of the components of the precipitation reaction vessel are substantially inert to a basic solution;
(d) at least one second solid-liquid separation module in fluid communication with, and downstream of, the precipitation reaction vessel, wherein the at least one second solid-liquid separation module separates contents of the precipitation reaction vessel into a second substantially solid fraction and a second substantially liquid fraction; and
(e) an optional liquid conduit fluidly connecting the at least one second solid-liquid separation module to the extraction reaction vessel for directing liquid from the at least one second solid-liquid separation module to the extraction reaction vessel,
wherein the extraction reaction vessel, the precipitation reaction vessel, or both, is devoid of any solid-liquid separator comprising a membrane.
3. The PEARS system of claim 2 , further comprising at least one of:
(i) a first container in liquid communication with the extraction reaction vessel, wherein the first container is fabricated of material that is inert to an acidic solution;
(ii) an air bubbler;
(iii) a second container in liquid communication with the precipitation reaction vessel, wherein the second container is fabricated of material that is inert to a basic solution;
(iv) a third container in communication with the second solid-liquid separation module, wherein solids from the at least one second solid-liquid separation module are collected in the third container;
(v) a fourth container in communication with the at least one first solid-liquid separation module, wherein solids from the first solid-liquid separation module are collected in the fourth container;
(vi) at least one pump positioned between the precipitation reaction vessel and the extraction reaction vessel;
(vii) at least one pump positioned between the precipitation reaction vessel and the third container;
(viii) a first multi-parameter meter positioned in the extraction reaction vessel;
(ix) a second multi-parameter meter positioned in the precipitation reaction vessel;
(x) an ammonia scrubbing module in gaseous communication with the precipitation reaction vessel; and/or
(xi) a manure-to-energy module positioned downstream of the fourth container.
4. The PEARS system of claim 2 , wherein the system does not require a pump positioned between the precipitation reaction vessel and the extraction reaction vessel.
5. The PEARS system of claim 2 , wherein the at least one first and the second solid-liquid separation modules comprise, independently of one another, at least one device selected from the group consisting of a gravity settler, a coagulator, a sieve, a screen, a vibratory dewatering sieve, a centrifuge, a flotation, a hydrocyclone, mesh screening, a belt press, a gravity belt thickener, a screw press, a filter press, gravity filtration device, vacuum filtration device, and any combination thereof.
6. The PEARS system of claim 2 , wherein the at least one first solid-liquid separation module comprises a vibratory dewatering sieve.
7. The PEARS system of claim 2 , comprising an air bubbler, wherein the air bubbler comprises an air diffuser positioned within the precipitation reaction vessel.
8. The PEARS system of claim 3 , further comprising a supervisory control and data acquisition (SCADA) system in communication with at least one of the first multi-parameter meter, the first mixer, the first container, the second multi-parameter meter, the second mixer, the second container, the third container, the fourth container, the gas diffuser, the air bubbler, and the pumps.
9. A process for treating manure, sewage sludge, or other nutrient-rich organic material using the PEARS system of claim 2 to isolate a target precipitate from a slurry comprising manure, sewage sludge, or other nutrient-rich material, the process comprising:
(a) introducing the slurry in the extraction reaction vessel, wherein pH of the slurry is lowered to a range of about 3.5 to about 5.5 using at least carbon dioxide gas introduced via the gas diffuser, wherein the slurry is mixed in the extraction reaction vessel to instigate nutrient release from the slurry;
(b) separating the acidified slurry into a nutrient-rich liquid and a nutrient-deficient solid using the at least one first solid-liquid separation module;
(c) directing the nutrient-rich liquid to the precipitation reaction vessel;
(d) inducing precipitation of the target precipitate in the precipitation reaction vessel by raising pH of the nutrient-rich liquid to a range of greater than 7.0 to about 10; and
(e) collecting the target precipitate from the precipitation reaction vessel.
10. The process of claim 9 , further comprising adding at least one acid to the extraction reaction vessel to assist in the achievement of the pH range of about 3.5 to about 5.5.
11. The process of claim 9 , wherein the pH of the nutrient-rich liquid is raised to about 8.0 to about 9.2.
12. The process of claim 9 , wherein no pump is positioned between the precipitation reaction vessel and the extraction reaction vessel.
13. The process of claim 9 , wherein the at least one first solid-liquid separation module comprises at least one device selected from the group consisting of a gravity settler, a coagulator, a sieve, a screen, a vibratory dewatering sieve, a centrifuge, a flotation, a hydrocyclone, mesh screening, a belt press, a gravity belt thickener, a screw press, a filter press, gravity filtration device, vacuum filtration device, and any combination thereof.
14. The process of claim 9 , wherein the at least one first solid-liquid separation module comprises a vibratory dewatering sieve.
15. The process of claim 9 , wherein the target precipitate comprises struvite and/or potassium struvite.
16. The process of claim 9 , wherein the steps (a) through (e) can be repeated more than once.
17. The process of claim 9 , wherein the pH of the nutrient-rich liquid is achieved using at least one base and/or while sparging the nutrient-rich liquid with air.
18. The process of claim 9 , wherein the target precipitate is collected using the second solid-liquid separation module.
19. A process for treating manure, sewage sludge, or other nutrient-rich organic material using the PEARS system of claim 1 to isolate a target precipitate from a slurry comprising manure, sewage sludge, or other nutrient-rich material, the process comprising:
(a) introducing the slurry in the reaction vessel, wherein pH of the slurry is lowered to a range of about 3.5 to about 5.5 using at least carbon dioxide gas introduced via the gas diffuser, wherein the slurry is mixed in the reaction vessel to instigate nutrient release from the slurry;
(b) separating the acidified slurry into a nutrient-rich liquid and a nutrient-deficient solid using the at least one solid-liquid separation module;
(c) directing the nutrient-rich liquid back to the reaction vessel;
(d) inducing precipitation of the target precipitate in the reaction vessel by raising pH of the nutrient-rich liquid to a range of greater than 7.0 to about 10; and
(e) collecting the target precipitate from the reaction vessel.
20. The process of claim 19 , wherein the at least one solid-liquid separation module comprises a vibratory dewatering sieve.