Method for preparing internal laser induced carbonization layer of aramid fiber resin matrix composite
A preparation method for an internal laser-induced carbonization layer of aramid fiber resin matrix composite material is provided. The surface of sample of aramid fiber resin matrix composite material is wiped with anhydrous ethanol; the sample of aramid fiber resin matrix composite material was placed on the laser sample platform, and the defocusing amount between the laser focus and the upper surface of the sample was negative. Infrared picosecond laser was used to scan the sample of aramid fiber resin matrix composite material for several times. Since the laser absorption rate of the surface epoxy resin was very low, most of the laser energy passed through the epoxy resin layer and directly acted on the internal aramid fiber. The laser carbonized the internal aramid fiber without damaging the surface resin, and formed a carbonized line along the laser scanning path to realize the conductivity of aramid fiber resin matrix composite.
1. A method for preparing an internal laser-induced carbonization layer of an aramid fiber resin matrix composite, the aramid fiber resin matrix composite comprising a surface resin layer on the upper surface and an aramid fiber layer under the surface resin layer, comprising the following steps:
step 1: wiping a surface of an aramid fiber resin matrix composite material sample to ensure that there is no stain on the surface of the aramid fiber resin matrix composite material sample;
step 2: placing the aramid fiber resin matrix composite material sample on a laser sample platform, wherein a defocusing amount between a laser focus and the upper surface of the aramid fiber resin matrix composite material sample is negative, so that the laser focus is located in an internal horizontal plane of the aramid fiber resin matrix composite material sample; and
step 3: using low power and high speed infrared picosecond laser to scan the aramid fiber resin matrix composite material sample for several times; setting a specific scanning processing path to carbonize the aramid fiber layer without damaging the surface resin layer of the aramid fiber resin matrix composite material sample under a condition of high temperature and hypoxia, to form a specific carbonization line.
2. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein the defocusing amount between the laser focus and the upper surface of the aramid fiber resin matrix composite sample is −1 mm to −10 mm.
3. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein in step 3, laser power is 4 w to 15 w, scanning speed is 500 mm/s to 2000 mm/s, and infrared picosecond laser wavelength is 1064 nm.
4. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 3 , wherein the infrared picosecond laser with laser power of 4.5 w and scanning speed of 1000 mm/s is used to scan the aramid fiber resin matrix composite sample.
5. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 3 , wherein the infrared picosecond laser with laser power of 10 w and scanning speed of 1000 mm/s is used to scan the aramid fiber resin matrix composite sample.
6. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 3 , wherein the infrared picosecond laser with laser power of 15 w and scanning speed of 1000 mm/s is used to scan the aramid fiber resin matrix composite sample.
7. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein in step 3, infrared picosecond laser scans the aramid fiber resin matrix composite sample for 6 to 12 times, and a time interval of each scan is 1 s to 2 s.
8. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein a thickness of the surface resin layer in the aramid fiber resin matrix composites is 0.1 mm to 0.3 mm.
9. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein a thickness of the aramid fiber resin matrix composite is 1 mm, a volume number of epoxy resin is 42%, and a volume fraction of fiber is 58%.
10. The method for preparing the internal laser-induced carbonization layer of the aramid fiber resin matrix composite according to claim 1 , wherein a sample size of aramid fiber resin matrix composite is 100 mm×50 mm.