Granted Patent B2

US 12,325,897 · App. 16/340,744 · Granted Jun 10, 2025

Inventors: Mikko Vepsäläinen (Victoria, AU); Miao Chen (Victoria, AU); David Molenaar (Australian Capital Territory, AU); Anthony Kilpatrick (Australian Capital Territory, AU)

Assignee: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION

C22B3/04G01N7/00G01N27/028G01N27/30G01N27/333H04Q9/00C02F2201/4612H04Q2209/30H04Q2209/826

Abstract

Claims (37)

1. An apparatus for use in acquiring electrochemical data from leaching solution within a region of material in a heap leaching application, the apparatus including: one or more sensor strings provided in direct contact with a region of material to be analysed, each sensor string including a data cable and two or more commonly referenced solid-state sensors selected from a wide-band gap semiconductor positioned along the length of the data cable, the two or more commonly referenced solid-state sensors of the one or more sensor strings adapted to periodically acquire spatial and temporal sensor data relating to electrochemical properties of a leaching solution surrounding and in direct contact with the two or more commonly referenced solid-state sensors of the one or more sensor strings over a predetermined period of time and to transmit the sensor data via the data cable to one or more hubs, wherein the apparatus includes one or more solid-state reference electrodes which provide a stable reference potential, and the one or more solid-state reference electrodes are associated with the two or more commonly referenced solid-state sensors of the one or more sensor strings.

2. The apparatus of claim 1 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings are one or more of potentiometric sensors, amperometric sensors, coulometric sensors, impedimetric sensors and voltammetric sensors.

3. The apparatus of claim 2 , wherein the potentiometric sensors are ion-selective electrodes.

4. The apparatus of claim 2 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings are adapted to provide an output data or data representative of the electrochemical properties of the leaching solution surrounding the two or more commonly referenced solid-state sensors of the one or more sensor strings, the electrochemical properties including one or more of oxidation/reduction potential (ORP), dissolved metal ions, dissolved Oxygen, dissolved CO 2 , dissolved H 2 S; and/or concentrations, molarities, potentials or partial pressures of chemical species of interest, or other observable physical or chemical phenomena to transmit an output data to the one or more hubs.

5. The apparatus of claim 2 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings are adapted to further provide an output data or data representative of one or more of total pressure, flow rate, humidity, electrical resistance, electrical conductivity, permittivity, temperature, or other observable physical phenomena to transmit an output data to the one or more hubs.

6. The apparatus of claim 1 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings are adapted to provide an output data or data representative of a change over a predetermined time period in the electrochemical properties of the leaching solution surrounding the two or more commonly referenced solid-state sensors of the one or more sensor strings, the electrochemical properties including one or more of oxidation/reduction potential (ORP), dissolved metal ions, dissolved Oxygen, dissolved CO 2 , dissolved H 2 S; and/or concentrations, molarities, potentials or partial pressures of chemical species of interest, or other observable physical or chemical phenomena over a predetermined time period to transmit output data to the one or more hubs.

7. The apparatus of claim 1 , wherein one or more sensors acquire sensor data relating to electrochemical properties simultaneously.

8. The apparatus of claim 1 , wherein one or more sensors acquire sensor data relating to electrochemical properties by way of time-division multiplexing.

9. The apparatus of claim 1 , wherein one or more sensor strings are provided in a two-dimensional spatial arrangement.

10. The apparatus of claim 9 , wherein the two-dimensional spatial arrangement is an array.

11. The apparatus of claim 1 , wherein the one or more sensor strings are provided in a three-dimensional spatial arrangement.

12. The apparatus of claim 11 , wherein the three dimensional spatial arrangement is a helix.

13. The apparatus of claim 1 , wherein two or more sensor strings are provided in one or more of:

a first plane,

a second plane,

a third plane; or

both a first and second plane, a first, second and third plane or combination thereof.

14. The apparatus of claim 13 , wherein two or more sensor strings are substantially parallel to each other.

15. The apparatus of claim 1 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings include ion-selective electrodes, voltammetry electrodes, amperometric sensors, and/or spectroscopic techniques.

16. The apparatus of claim 1 , wherein the two or more commonly referenced solid-state sensors of the one or more sensor strings are adapted to provide an output data or data representative of a change in one or more of total pressure, flow rate, humidity, electrical resistance, electrical conductivity, permittivity, temperature, or other observable physical phenomena over a predetermined time period to transmit output data to the one or more hubs.

17. The apparatus of claim 16 , wherein the output data further includes sensor location ID, unique sensor ID, time stamp and date stamp and localization coordinates.

18. A method of acquiring electrochemical data from leaching solution within a region of material to be analysed, the method including: providing one or more sensor strings in direct contact with a region of material to be analysed, each sensor string including a data cable and two or more commonly referenced solid-state sensors selected from a wide-band gap semiconductor positioned along the length of the data cable, the two or more commonly referenced solid-state sensors of the one or more sensor strings adapted to periodically acquire spatial and temporal sensor data relating to electrochemical properties of leaching solution surrounding and in direct contact with the two or more commonly referenced solid-state sensors of the one or more sensor strings over a predetermined period of time and to transmit the sensor data via the data cable to one or more hubs, wherein the apparatus includes one or more solid-state reference electrodes which provide a stable reference potential, and the one or more solid-state reference electrodes are associated with the two or more commonly referenced sensors of the one or more sensor strings.

19. A method of acquiring electrochemical data from leaching solution within a region of material to be analysed, the method including: digging a trench in the material to be analysed, providing one or more sensor strings in the trench in direct contact with a region of material to be analysed, each sensor string including a data cable and two or more commonly referenced solid-state sensors selected from a wide-band gap semiconductor positioned along the length of the data cable, the two or more commonly referenced solid-state sensors of the one or more sensor strings adapted to periodically acquire spatial and temporal sensor data relating to electrochemical properties of leaching solution surrounding and in direct contact with the two or more commonly referenced solid-state sensors of the one or more sensor strings over a predetermined period of time and to transmit the sensor data via the data cable to one or more hubs, wherein the apparatus includes one or more solid-state reference electrodes which provide a stable reference potential, and the one or more solid-state reference electrodes are associated with the two or more commonly referenced solid-state sensors of the one or more sensor strings.

20. A method of controlling operation of a leach process comprising:

a) forming a leachable region having one or more layers/dumps;

b) providing one or more sensor strings within the one or more layers/dumps, and in direct contact with a region of material to be analysed each sensor string including a data cable and two or more commonly-referenced solid-state sensors selected from a wide-band semiconductor positioned along the length of the data cable, the two or more commonly referenced sensors of the one or more sensor strings adapted to periodically acquire spatial and temporal sensor data relating to electrochemical properties of leaching solution surrounding and in direct contact with the two or more commonly referenced sensors of the one or more sensor strings in the layers/dumps over a predetermined period of time and to transmit the sensor data via the data cable to one or more hubs thereby providing sensor data relating to the leach process;

c) modelling the leach process using the sensor data relating to the leach process; and

d) adjusting the leach process based on the sensor data relating to the leach process,

wherein the method includes providing one or more solid-state reference electrodes which can provide a stable reference potential, and the one or more solid-state reference electrodes are associated with the two or more commonly referenced solid state sensors of the one or more sensor strings.

21. The method of claim 20 , wherein the one or more sensor strings are provided between the one or more layers/dumps.

22. A system for controlling operation of a leach process comprising:

a) a leachable region having one or more layers/dumps;

b) one or more sensor strings provided in the one or more layers/dumps, and in direct contact with a region of material to be analysed each sensor string including a data cable and two or more commonly referenced sensors selected from a wide-band gap semiconductor positioned along the length of the data cable, the two or more sensors of the one or more sensor strings adapted to periodically acquire spatial and temporal sensor data relating to electrochemical properties of leaching solution surrounding and in direct contact with the two or more sensors of the one or more sensor strings in the layers/dumps over a predetermined period of time and to transmit the sensor data via the data cable to one or more hubs thereby providing sensor data relating to the leach process, and

one or more solid-state reference electrodes which provide a stable reference potential, and the one or more solid-state reference electrodes are associated with the two or more sensors of the one or more sensor strings, and

c) a computer processor for:

i. modelling the leach process using the sensor data relating to the leach process and

ii. adjusting the leach process based on the sensor data relating to the leach process.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (44)