IP Library › Granted Patent US 12,331,414
Granted Patent B2
US 12,331,414 · App. 18/262,351 · Granted Jun 17, 2025

Methods and apparatus for performing electrolytic conversion

Inventors: Zishuai Zhang (Vancouver, CA); Curtis P. Berlinguette (Vancouver, CA)
Assignee: THE UNIVERSITY OF BRITISH COLUMBIA
C25B9/23C25B1/02C25B3/07C25B3/26C25B11/032C25B11/065C25B11/081C25B15/083
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Quick Facts
Patent No.
US 12,331,414
App. No.
18/262,351
Granted
Jun 17, 2025
Kind
B2
Abstract

Methods and apparatuses for converting carbon dioxide to useful compounds are disclosed. The method involves reducing bicarbonate solution in an electrolyzer. Bicarbonate solution is supplied to the cathode. The direct reduction of bicarbonate at the cathode may be coupled with an oxidation reaction at the anode. The oxidation reaction may provide a source of protons (H + ) to cathode for the reduction of bicarbonate. The oxidation reaction may be a hydrogen oxidation reaction (HOR). Hydrogen gas (H 2 ) may be supplied to the anode. In some embodiments, a source of gas may be supplied to the bicarbonate solution to form a pressurized solution before supplying the solution to the cathode.

Claims (24)

1. A method for performing a carbon dioxide reduction reaction in an electrolyzer, the method comprising:

applying an electrical potential between an anode and a cathode;

introducing hydrogen gas at the anode;

supplying an aqueous solution comprising bicarbonate ions at the cathode, wherein the aqueous solution is substantially free of gaseous carbon dioxide;

oxidizing, at the anode, the hydrogen gas to form hydrogen ions;

transporting the hydrogen ions from the anode through an ion exchange membrane toward the cathode; and

reacting the hydrogen ions with the bicarbonate ions at the cathode to yield one or more products.

2. The method as defined in claim 1 , comprising increasing a pressure of the aqueous solution at the cathode.

3. The method as defined in claim 2 , wherein the pressure of the aqueous solution is increased by supplying a source of gas to a reservoir containing the aqueous solution.

4. The method as defined in claim 2 comprising maintaining the pressure of the aqueous solution at the cathode within a range of from 1.1 atm to 40 atm.

5. The method as defined in claim 1 , wherein the pH of the aqueous solution is greater than about 4.

6. The method as defined in claim 1 , wherein a concentration of the biocarbonate ions in the aqueous solution is in the range of from 0.1 to 10 M.

7. The method as defined in claim 1 , wherein the one or more products comprise no more than 50% CO2.

8. The method as defined in claim 1 , wherein the one or more products comprise a gaseous product or a liquid product.

9. The method as defined in claim 1 , wherein the one or more products comprise a carbon-containing compound.

10. The method as defined in claim 9 , wherein the carbon-containing compound comprises one or more of formate, carbon monoxide, formic acid, ethylene and propanol.

11. The method as defined in claim 1 , further comprising:

discharging excess hydrogen gas out of the anode; and

delivering the excess hydrogen gas into the anode.

12. The method as defined in claim 1 , further comprising transporting the hydrogen ions through a buffer layer after being transported through the ion exchange membrane and before entering a cathode chamber comprising the cathode.

13. The method as defined in claim 1 , wherein the aqueous solution comprises potassium bicarbonate, caesium bicarbonate, and/or ammonium bicarbonate.

14. The method as defined in claim 1 , wherein the one or more products comprise hydrogen gas.

15. The method as defined in claim 14 , further comprising delivering the hydrogen gas produced at the cathode to the anode.

16. The method as defined in claim 15 , further comprising separating the hydrogen gas from the one or more products prior to delivering the hydrogen gas to the anode.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2023
From: ZHANG, ZISHUAI; BERLINGUETTE, CURTIS P.
To: THE UNIVERSITY OF BRITISH COLUMBIA
Reel/Frame 064332/0477 →
Continuity (2)
Provisional Application 63140176 · Jan 21, 2021
Related Publication 20240076785A1 · Mar 7, 2024
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Cited By (1)
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