Slurry composition for all-solid-state secondary battery, solid electrolyte-containing layer, all-solid-state secondary battery, and method of producing slurry composition for all-solid-state secondary battery
Provided is a slurry composition for an all-solid-state secondary battery that has excellent fluidity and preservation stability and can form a solid electrolyte-containing layer having excellent ion conductivity. The slurry composition contains a solid electrolyte, a polymer, and a solvent. The ratio of fineness of grind of the solid electrolyte, as measured by a grind gauge method based on JIS K5600-2-5:1999, relative to the average primary particle diameter of the solid electrolyte is more than 1 and less than 30.
1. A slurry composition for an all-solid-state secondary battery comprising a solid electrolyte, a polymer, and a solvent, wherein
a ratio of fineness of grind of the solid electrolyte, as measured by a grind gauge method based on JIS K5600-2-5:1999, relative to an average primary particle diameter of the solid electrolyte is more than 1 and less than 30,
the solid electrolyte is present as a plurality of solid electrolyte particles, and some of the solid electrolyte particles are aggregated and present as aggregates,
the average primary particle diameter of the solid electrolyte is determined by observing 100 primary particles, each being a solid electrolyte particle existing independently, among the plurality of solid electrolyte particles under an electron microscope, measuring a particle diameter of each of the primary particles in accordance with JIS Z8827-1:2008, and calculating the arithmetic mean of the measured values.
2. The slurry composition for an all-solid-state secondary battery according to claim 1 , wherein the fineness of grind of the solid electrolyte is less than 20 μm.
3. The slurry composition for an all-solid-state secondary battery according to claim 1 , wherein the polymer includes a vinyl cyanide monomer unit.
4. The slurry composition for an all-solid-state secondary battery according to claim 1 , wherein the polymer includes a (meth)acrylic acid ester monomer unit.
5. The slurry composition for an all-solid-state secondary battery according to claim 4 , wherein the (meth)acrylic acid ester monomer unit constitutes a proportion of not less than 25 mass % and not more than 95 mass % in the polymer.
6. The slurry composition for an all-solid-state secondary battery according to claim 1 , wherein the solvent includes an organic solvent having a solubility parameter (SP value) of not less than 6.0 (cal/cm 3 ) 1/2 and not more than 12.0 (cal/cm 3 ) 1/2 .
7. A solid electrolyte-containing layer formed using the slurry composition for an all-solid-state secondary battery according to claim 1 .
8. An all-solid-state secondary battery comprising the solid electrolyte-containing layer according to claim 7 .