Functional polyester and method of producing the same
There is described a method for the production of a functional polyester having functional group X. The method comprises the step of melt blending a composition comprising (i) a high number average molecular weight (Mn) polyester having a Mn of ≥6,000 Da; and (ii) a functional compound comprising functional group Y which may be the same as functional group X or be different to functional group X but be operable to form functional group X in the functional polyester. The composition is melt blended such that the high Mn polyester and the functional compound react to produce the functional polyester. The high Mn polyester has a Mn that is higher than the Mn of the functional compound. The present invention extends to functional polyesters produced by the method; aqueous, solventborne and powder coating compositions containing the functional polyester, and articles coated with the said coating compositions.
1. A method for the production of a functional polyester having functional group X, comprising:
melt blending a composition comprising
i. a high number average molecular weight (Mn) polyester having a Mn of ≥6,000 Da; and
ii. a functional compound reactive with component (i) and having an Mn of 500 to 6,000 Da,
wherein the composition is melt blended such that the high Mn polyester and the functional compound react to produce the functional polyester,
and
wherein the functional polyester has an Mn that is less than the Mn of the high Mn polyester and greater than the Mn of the functional compound.
2. A method according to claim 1 , wherein the high Mn polyester is an organic solvent insoluble polyester.
3. A method according to claim 1 , wherein the high Mn polyester has a Mn of ≥8,000 Da.
4. A method according to claim 1 , wherein the melt blending temperature is ≥90° C.
5. The method according to claim 1 , wherein the functional compound comprises ethylenic unsaturation.
6. The method according to claim 1 , wherein X comprises ethylenic unsaturation, an ether group, an amide group, an amine group, a ketone group, a hydroxyl group and/or an acid group.
7. The method according to claim 1 , wherein the composition is melt blended for a residence time of 0.25 to 20 minutes.
8. The method according to claim 1 , wherein the composition is melt blended for a residence time of one to ten minutes.
9. The method according to claim 1 , wherein the composition is melt blended for a residence time of 1.5 to five minutes.
10. The method according to claim 1 , wherein the composition is melt blended for about three minutes.
11. A functional polyester having functional group X obtained by a method according to claim 7 , wherein functional group X can crosslink to form a cured film and wherein the reaction product of the method contains fewer by-products when compared to the reaction product of a batch process having the same residence time.
12. An aqueous dispersion comprising the functional polyester of claim 11 .
13. A solvent solution comprising the functional polyester of claim 11 .
14. A powder composition comprising the functional polyester of claim 11 .
15. The functionalized polyester of claim 11 , having an Mn of greater than 4,000.
16. The functionalized polyester of claim 11 , having an Mw of greater than 15,000.
17. The functionalized polyester of claim 11 , having a polydispersity index of greater than 3.
18. A method of using the functional polyester obtained by a method according to claim 7 to prepare an acrylic polyester comprising:
polymerizing acrylic monomers in the presence of the functional polyester.
19. An acrylic polyester obtained by the method of claim 18 , wherein the acrylic polyester can crosslink to form a cured film.
20. An aqueous, solvent-borne, or powder coating composition comprising a crosslinking material and the acrylic polyester of claim 19 .
21. An aqueous, solvent-borne or powder coating composition comprising crosslinking material, and further comprising the functional polyester of claim 18 .
22. A substrate at least partially coated with a coating composition according to claim 21 .
23. An article coated at least in part with a coating composition according to claim 21 , wherein the article is an automotive product, a household or office appliance, furniture item or tool, a powered industrial product, a consumer electronics article, an architectural product or a product protected by an intumescent coating.
24. A package coated at least in part with a coating composition according to claim 21 .