Rubber composition, and tire using the same
View Patent ↗Disclosed is a rubber composition and a tire using the same. The rubber composition comprises a rubber matrix and a compounding component. In parts by weight, every 100 parts by weight of said rubber matrix comprises 5-95 parts by weight of a branched polyethylene, 5-90 parts by weight of a highly unsaturated diene elastomer and 0-30 parts by weight of a low unsaturated diene elastomer; and said compounding component comprises a vulcanization system and a filler. The rubber composition has good aging resistance and mechanical properties, and can be applied for products such as tires, rubber hoses, rubber tapes and so on, in which the traditional, easily aging diene rubber was commonly used.
1. A rubber composition, comprising:
a rubber matrix comprising:
a branched polyethylene, wherein the branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 102 branches/1,000 carbons, and a Mooney viscosity ML(1+4) at 125° C. which is between 32 and 80;
a first unsaturated diene elastomer including a diene polymeric monomer with a molar content not lower than 15%; and
a second unsaturated diene elastomer including a diene polymeric monomer with a molar content lower than 15%; wherein, every 100 parts by weight of said rubber matrix comprises:
5-95 parts by weight of the branched polyethylene,
5-90 parts by weight of the first unsaturated diene elastomer, and
no more than 30 parts by weight of the second unsaturated diene elastomer; and
a compounding component, wherein the compounding component comprises a vulcanization system and a filler.
2. The rubber composition according to claim 1 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 99 branches/1,000 carbons.
3. The rubber composition according to claim 2 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 97 branches/1,000 carbons.
4. The rubber composition according to claim 2 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 90 branches/1,000 carbons.
5. The rubber composition according to claim 1 , wherein:
the branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 90 branches/1,000 carbons;
the first unsaturated diene elastomer is selected from at least one of natural rubber (NR), butadiene/styrene copolymer (SBR), polybutadiene (BR), synthetic polyisoprene (IR), isoprene/butadiene copolymer (BIR), isoprene/styrene copolymer (SIR) or isoprene/butadiene/styrene copolymer (SBIR);
the second unsaturated diene elastomer is an ethylene-propylene-diene terpolymer, in which the content of ethylene is 2 wt %-40 wt %, the content of propylene is 60 wt %-95 wt %, and the content of diene is 0.5 wt %-12 wt %;
the diene is 5-ethylidene-2-norbornene;
in every 100 parts of said rubber matrix, the content of all the ethylene-propylene-diene terpolymers is 5-30 parts;
the vulcanization system is a peroxide vulcanization system or a peroxide-sulfur mixed vulcanization system;
the filler is selected from silica, carbon black, or a blend of silica and carbon black; and
the compounding component comprises 2-80 parts of a plasticizer, 0-3 parts of a stearic acid, 0-10 parts of a metal oxide, 0-20 parts of a surface modifier, 0-8 parts of a stabilizer, 0-15 parts of a tackifier and 0-20 parts of an adhesive.
6. The rubber composition according to claim 1 , wherein, the polymeric monomers of the first unsaturated diene elastomer includes diene polymeric monomers with a molar content not lower than 50%.
7. The rubber composition according to claim 1 , wherein, the first unsaturated diene elastomer is selected from at least one of natural rubber (NR), butadiene/styrene copolymer (SBR), polybutadiene (BR), synthetic polyisoprene (IR), isoprene/butadiene copolymer (BIR), isoprene/styrene copolymer (SIR) or isoprene/butadiene/styrene copolymer (SBIR).
8. The rubber composition according to claim 1 , wherein:
the branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 90 branches/1,000 carbons;
the first unsaturated diene elastomer is selected from at least one of natural rubber (NR), butadiene/styrene copolymer (SBR), polybutadiene (BR), synthetic polyisoprene (IR), isoprene/butadiene copolymer (BIR), isoprene/styrene copolymer (SIR) or isoprene/butadiene/styrene copolymer (SBIR);
the second unsaturated diene elastomer is an ethylene-propylene-diene terpolymer, in which the content of ethylene is 2 wt %-40 wt %, the content of propylene is 60 wt %-95 wt %, and the content of diene is 0.5 wt %-12 wt %;
the diene is vinyl norbornene;
in every 100 parts of said rubber matrix, the content of all the ethylene-propylene-diene terpolymers is 5-30 parts;
the vulcanization system is a peroxide vulcanization system or a peroxide-sulfur mixed vulcanization system;
the filler is selected from silica, carbon black, or a blend of silica and carbon black; and
the compounding component comprises 2-80 parts of a plasticizer, 0-3 parts of a stearic acid, 0-10 parts of a metal oxide, 0-20 parts of a surface modifier, 0-8 parts of a stabilizer, 0-15 parts of a tackifier and 0-20 parts of an adhesive.
9. The rubber composition according to claim 1 , wherein, the second unsaturated diene elastomer is selected from at least one of ethylene-propylene-diene terpolymer and halogenated butyl rubber.
10. The rubber composition according to claim 9 , wherein, the second unsaturated diene elastomer is composed of one or more ethylene-propylene-diene terpolymers, in which the content of propylene is 15%-95%; and in every 100 parts of said rubber matrix, the content of all the ethylene-propylene-diene terpolymers is 5-30 parts.
11. The rubber composition according to claim 9 , wherein, the second unsaturated diene elastomer is an ethylene-propylene-diene terpolymer, in which the content of ethylene is 2 wt %-40 wt %, the content of propylene is 60 wt %-95 wt %, and the content of diene is 0.5 wt %-12 wt %.
12. The rubber composition according to claim 9 , wherein, the second unsaturated diene elastomer is an ethylene-propylene-diene terpolymer, in which the diene is selected from at least one of 5-ethylidene-2-norbornene and vinyl norbornene.
13. The rubber composition according to claim 1 , wherein, said vulcanization system is a peroxide vulcanization system or a peroxide-sulfur mixed vulcanization system.
14. The rubber composition according to claim 1 , wherein, said filler is selected from silica, carbon black, or a blend of silica and carbon black.
15. The rubber composition according to claim 1 , wherein, based on 100 parts by weight of said rubber matrix, said compounding component comprises 2-80 parts of a plasticizer, 0-3 parts of a stearic acid, 0-10 parts of a metal oxide, 0-20 parts of a surface modifier, 0-8 parts of a stabilizer, 0-15 parts of a tackifier and 0-20 parts of an adhesive.
16. The rubber composition according to claim 2 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 82 branches/1,000 carbons.
17. The rubber composition according to claim 2 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 72 branches/1,000 carbons.
18. The rubber composition according to claim 2 , wherein, said branched polyethylene is an ethylene homopolymer having a branching degree of from 50 branches/1,000 carbons to 60 branches/1,000 carbons.
19. The rubber composition according to claim 1 , wherein, said branched polyethylene is an ethylene homopolymer having a weight average molecular weight of 6.6×10 4 to 53.4×10 4 g/mol.
20. The rubber composition according to claim 1 , wherein, said branched polyethylene is an ethylene homopolymer having a weight average molecular weight of from 20×10 4 to 40×10 4 g/mol.